| Journal Articles: 64 results |
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Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) Complexes Richard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor
Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction.
Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ. 2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
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Reaction Order Ambiguity in Integrated Rate Plots Joe Lee
This article provides a theoretical and statistical justification for the necessity of monitoring a reaction to a substantial fraction of completion if integrated rate plots plots are to yield unambiguous orders.
Lee, Joe. J. Chem. Educ. 2008, 85, 141.
Chemometrics |
Kinetics |
Rate Law
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The Chemistry of Paper Preservation Henry A. Carter
This article examines the applications of chemistry to paper preservation. The acid-catalyzed hydrolysis of cellulose accounts for the deterioration of paper in library books and other written records. To combat this threat to our written heritage, new permanent papers have been developed that are relatively chemically stable and undergo a very slow rate of deterioration.
Carter, Henry A. J. Chem. Educ. 2007, 84, 1937.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Free Radicals |
Gas Chromatography |
HPLC |
pH |
Kinetics |
Rate Law
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Visualizing the Transition State: A Hands-on Approach to the Arrhenius Equation Thomas S. Kuntzleman, Matthew S. Swanson, and Deborah K. Sayers
Pennies and dice are used to simulate the kinetics of two irreversible "reactions" with a hands-on, Monte Carlo approach. Arrhenius plots of the data generated yield activation energies comparable to assigned values and pre-exponential factors close to what would be expected based on the probability of a "reactant" achieving the correct orientation for conversion into "product". A comparison of the values obtained for the pre-exponential factors for the different simulations allows students to semi-quantitatively discuss the orientational requirement that is contained within this factor.
Kuntzleman, Thomas S.; Swanson, Matthew S.; Sayers, Deborah K. J. Chem. Educ. 2007, 84, 1776.
Kinetics |
Rate Law
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A Student Laboratory Experiment Based on the Vitamin C Clock Reaction Ed Vitz
Describes an adaptation of the vitamin C clock reaction to a student laboratory experiment in which the orders with respect to peroxide and iodide, the rate constant, and the activation energy are determined by the method of initial rates.
Vitz, Ed. J. Chem. Educ. 2007, 84, 1156.
Consumer Chemistry |
Kinetics |
Mechanisms of Reactions |
Rate Law
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An Inexpensive Kinetic Study: The Reaction of FD&C Red #3 (Erythrosin B) with Hypochlorite Maher M. Henary and Arlene A. Russell
Students use a desktop visible spectrophotometer to quantitatively follow the rate of disappearance of FD&C Red #3 with hypochlorite. The first-order reaction in both dye and bleach yields simple data that students can easily process and graph using spreadsheet software to obtain the rate constant and the rate law.
Henary, Maher M.; Russell, Arlene A. J. Chem. Educ. 2007, 84, 480.
Dyes / Pigments |
Kinetics |
Rate Law |
UV-Vis Spectroscopy
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Applications of Reaction Rate Kevin Cunningham
This article presents an assignment in which students are to research and report on a chemical reaction whose increased or decreased rate is of practical importance. The assignment is designed to develop and assess a number of valuable skills and understandings, including the ability to write effectively.
Cunningham, Kevin. J. Chem. Educ. 2007, 84, 430.
Catalysis |
Enzymes |
Kinetics |
Rate Law |
Reactions |
Applications of Chemistry
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New Highlights on Analyzing First-Order Kinetic Data of the Peroxodisulfate–Iodide System at Different Temperatures J. Yperman and W. J. Guedens
A pseudo-first order kinetic experiment examining the peroxodisulfateiodide system is executed at different temperatures, making it possible to calculate the activation energy of this reaction.
Yperman, J.; Guedens, W. J. J. Chem. Educ. 2006, 83, 641.
Kinetics |
Laboratory Computing / Interfacing |
Oxidation / Reduction |
Rate Law |
Thermodynamics
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Promoting Graphical Thinking: Using Temperature and a Graphing Calculator To Teach Kinetics Concepts José E. Cortés-Figueroa and Deborah A. Moore-Russo
A Calculator-Based Laboratory (CBL) System, a graphing calculator, and a cooling piece of metal are used in a classroom demonstration to teach key concepts of a first-order chemical reaction. This activity promotes graphical thinking and permits student-centered instruction where the students explore concepts and discover how simple mathematical equations model observable facts (data).
Cortés-Figueroa, José E.; Moore-Russo, Deborah A. J. Chem. Educ. 2004, 81, 69.
Kinetics |
Rate Law
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Kinetics of Platinum-Catalyzed Decomposition of Hydrogen Peroxide Tiffany A. Vetter and D. Philip Colombo Jr.
Determining the order and rate constant of the catalyzed decomposition of hydrogen peroxide using AOSEPT contact lens cleaning and a platinum-coated AOSEPT disc.
Vetter, Tiffany A.; Colombo, D. Philip, Jr. J. Chem. Educ. 2003, 80, 788.
Catalysis |
Consumer Chemistry |
Kinetics |
Laboratory Computing / Interfacing |
Rate Law
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Depletion: A Game with Natural Rules for Teaching Reaction Rate Theory Donald J. Olbris and Judith Herzfeld
Game that reinforces central concepts of rate theory through simulation.
Olbris, Donald J.; Herzfeld, Judith. J. Chem. Educ. 2002, 79, 1232.
Kinetics |
Nonmajor Courses |
Rate Law |
Enrichment / Review Materials |
Catalysis
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Factors Affecting Reaction Kinetics of Glucose Oxidase Kristin A. Johnson
Demonstration based on a biochemical kinetics experiment in which the rate of reaction varies with the enzyme concentration, substrate concentration, substrate used in the reaction, and temperature.
Johnson, Kristin A. J. Chem. Educ. 2002, 79, 74.
Enzymes |
Kinetics |
Proteins / Peptides |
Carbohydrates |
Catalysis |
Rate Law
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Using CBL Technology and a Graphing Calculator To Teach the Kinetics of Consecutive First-Order Reactions José E. Cortés-Figueroa and Deborah A. Moore
This work proposes a demonstration to introduce first-order reactions using the CBL system. It then presents the analysis of two consecutive first-order reactions. The values of the rate constants that govern each reaction's rate are determined using the graphing and statistical capabilities of a TI-83 calculator.
Cortés-Figueroa, José E.; Moore, Deborah A. J. Chem. Educ. 1999, 76, 635.
Kinetics |
Laboratory Computing / Interfacing |
Rate Law
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Chemistry Time: Factors Affecting the Rate of a Chemical Reaction
This activity can be used to introduce a unit on chemical kinetics, but it is simple enough to be used in a discussion of chemical reactions or experimental methods/procedures during the first weeks of the semester. The activity involves reacting bicarbonate with acid, a reaction with practical applications in everyday life.
J. Chem. Educ. 1998, 75, 1120A.
Kinetics |
Rate Law
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The Coupling of Related Demonstrations to Illustrate Principles in Chemical Kinetics and Equilibrium Richard A. Pacer
Two very simple lecture demonstrations, both involving the reaction of magnesium with one or more dilute acids, are linked together to illustrate principles in chemical kinetics and equilibrium.
Pacer, Richard A. J. Chem. Educ. 1997, 74, 543.
Learning Theories |
Acids / Bases |
Equilibrium |
Kinetics |
Rate Law |
Reactions
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Monitoring self-association of a hydrophobic peptide with high performance liquid chromatography: An undergraduate kinetic experiment using the antibiotic gramicidin A Braco, Lorenzo; Ba, M. Carmen; Abad, Concepcin
The authors propose a kinetic experiment that uses high performance liquid chromatography to determine the rate and equilibrium constants in a very simple manner, and separate the molecular species under study.
Braco, Lorenzo; Ba, M. Carmen; Abad, Concepcin J. Chem. Educ. 1992, 69, A113.
HPLC |
Kinetics |
Proteins / Peptides |
Rate Law |
Equilibrium
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Simple and inexpensive kinetics: A student laboratory experiment and demonstration Erwin, David K.
Laboratory experimentation, as well as in-class demonstration, involving the study of chemical kinetics can be performed using this safe, simple, and inexpensive apparatus. This apparatus requires only that systems to be studied must produce a gaseous product that can displace water.
Erwin, David K. J. Chem. Educ. 1992, 69, 926.
Kinetics |
Qualitative Analysis |
Quantitative Analysis |
Rate Law |
Laboratory Equipment / Apparatus
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Three methods for studying the kinetics of the halogenation of acetone. Birk, James P.; Walters, David L.
Three methods for carrying out a kinetic study of the reaction between propanone and elemental iodine.
Birk, James P.; Walters, David L. J. Chem. Educ. 1992, 69, 585.
Aldehydes / Ketones |
Kinetics |
Spectroscopy |
Rate Law
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A study of some 2-chloro-2-methylpropane kinetics using a computer interface Allen, Anthony; Haughey, Adam J.; Hernandez, Yolanda; Ireton, Scot
Examining the effects of a few variables on the rate of a chemical reaction using specialized software.
Allen, Anthony; Haughey, Adam J.; Hernandez, Yolanda; Ireton, Scot J. Chem. Educ. 1991, 68, 609.
Kinetics |
Rate Law |
Acids / Bases |
Laboratory Computing / Interfacing
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A demonstration illustrating the factors determining rates of chemical reactions Holmes, L. H., Jr.
This demonstration qualitatively illustrates factors determining reaction rates for first-year chemistry students.
Holmes, L. H., Jr. J. Chem. Educ. 1991, 68, 501.
Rate Law |
Kinetics
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Ants and chemical kinetics Myers, R. Thomas
Data regarding the speed of ants at various temperatures are amenable to standards treatment on chemical kinetics.
Myers, R. Thomas J. Chem. Educ. 1990, 67, 761.
Kinetics |
Rate Law
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Reduction of permanganate: A kinetics demonstration for general chemistry Steffel, Margaret J.
Using the reduction of MnO4- to Mn2+ in aqueous solution to demonstrate the four factors that control reaction rates in solution: the natures of the reactants, concentrations of the reactants, temperature, and the presence of a catalyst.
Steffel, Margaret J. J. Chem. Educ. 1990, 67, 598.
Kinetics |
Rate Law |
Catalysis |
Oxidation / Reduction
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Polarized light and rates of chemical reactions Weir, John J.
This experiment provides the opportunity to introduce the principles of reaction kinetics, polarized light, and the chemistry of optically active compounds; the rate of the acid-catalyzed hydrolysis of sucrose to glucose and fructose is determined.
Weir, John J. J. Chem. Educ. 1989, 66, 1035.
Rate Law |
Kinetics |
Chirality / Optical Activity |
Carboxylic Acids
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The study of a simple redox reaction as an experimental approach to chemical kinetics Elias, Horst; Zipp, Arden P.
The authors present a kinetics experiment based on the oxidation of iodide ions that, like the iodine clock, is quick and easy to perform but has the advantage of being followed directly rather than indirectly.
Elias, Horst; Zipp, Arden P. J. Chem. Educ. 1988, 65, 737.
Kinetics |
Reactions |
Rate Law
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Kinetics and mechanism of the iodine azide reaction: A videotaped experiment Haight, Gilbert P.; Jones, Loretta L.
A clock reaction suitable for videotaping and presenting to a large lecture class of general chemistry for analysis.
Haight, Gilbert P.; Jones, Loretta L. J. Chem. Educ. 1987, 64, 271.
Kinetics |
Mechanisms of Reactions |
Rate Law
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A comment on "The order of CH3CHO decomposition" Liu, Michael T. H.
The order of the decomposition of acetaldehyde is 3/2 or 1.5.
Liu, Michael T. H. J. Chem. Educ. 1985, 62, 399.
Aldehydes / Ketones |
Rate Law |
Kinetics
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Change in concentration with time Umland, Jean B.
Shows how the rate of a reaction is fast at first and then gradually decreases to zero when one reactant has been used up.
Umland, Jean B. J. Chem. Educ. 1985, 62, 153.
Solutions / Solvents |
Kinetics |
Rate Law
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A demonstration of the effect of temperature on reaction rate (the authors reply) Boring, Wayne C.; McMillan, Ernest
Addresses problems identified with their demonstration / experiment.
Boring, Wayne C.; McMillan, Ernest J. Chem. Educ. 1984, 61, 744.
Kinetics |
Rate Law
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A demonstration of the effect of temperature on reaction rate Gupta, Y. K.; Mishra, S. K.
Problems with the experiment cited.
Gupta, Y. K.; Mishra, S. K. J. Chem. Educ. 1984, 61, 744.
Kinetics |
Rate Law
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Computer simulation of elementary chemical kinetics Nase, Martha L.; Seidman, Kurt
44. Bits and pieces, 16. The authors have developed several computer programs that simulate chemical kinetics for elementary first and second order processes. These programs can be used to generate kinetic data that can then be analyzed by the student in a variety of ways.
Nase, Martha L.; Seidman, Kurt J. Chem. Educ. 1983, 60, 734.
Kinetics |
Rate Law
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Influence of temperature and catalyst on the decomposition of potassium chlorate in a simple DTA apparatus Wiederholt, Erwin
The authors describe the use of a simple DTA-apparatus in demonstrating the catalytic effects of MnO2 and Al2O3 on the decomposition temperature of KClO3.
Wiederholt, Erwin J. Chem. Educ. 1983, 60, 431.
Kinetics |
Instrumental Methods |
Catalysis |
Reactions |
Rate Law
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The kinetics of photographic development: A general chemistry experiment Byrd, J. E.; Perona, M. J.
An experiment that uses black and white photographic equipment to illustrate the determination of reaction rate, kinetic order of reactant, and activation energy.
Byrd, J. E.; Perona, M. J. J. Chem. Educ. 1982, 59, 335.
Kinetics |
Applications of Chemistry |
Photochemistry |
Rate Law
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Let's get the heck out of here! White, Alvan D.
A football stadium is used to explain rate-determining steps.
White, Alvan D. J. Chem. Educ. 1981, 58, 645.
Rate Law |
Kinetics
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Chemical Kinetics: Reaction Rates Mickey, Charles D.
Reviews the chemistry behind factors that influence the rates of chemical reactions.
Mickey, Charles D. J. Chem. Educ. 1980, 57, 659.
Rate Law |
Kinetics |
Reactions |
Catalysis
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An introductory level kinetics investigation McGarvey, J. E. B.; Knipe, A. C.
A kinetic study of the hydrolysis of 3-bromo-3-phenylpropanoic acid.
McGarvey, J. E. B.; Knipe, A. C. J. Chem. Educ. 1980, 57, 155.
Kinetics |
Rate Law |
Mechanisms of Reactions
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Rossini, William Tell and the iodine clock reaction: A lecture demonstration Brice, L. K.
The iodine clock reaction is timed to coincide with three portions of the William Tell Overture.
Brice, L. K. J. Chem. Educ. 1980, 57, 152.
Reactions |
Kinetics |
Rate Law
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The hydrolysis of p-nitrophenyl beta-gIucoside: An undergraduate experiment on the effect of temperature on reaction rate Schram, Alfred. C.
The intensely colored p-nitrophenolate ion formed during basic hydrolysis allows a quick and convenient determination of the amount of product formed.
Schram, Alfred. C. J. Chem. Educ. 1979, 56, 351.
Kinetics |
Rate Law
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Rates of reaction - Analogies Smith, Douglas D.
Demonstrations of / analogies for zero- and first-order reactions.
Smith, Douglas D. J. Chem. Educ. 1979, 56, 47.
Rate Law |
Kinetics
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A simple general chemistry kinetics experiment Gellender, Martin
The oxidation of iodide ion by persulfate provides a gradual and clearly distinguishable appearance of color as the reaction proceeds.
Gellender, Martin J. Chem. Educ. 1975, 52, 806.
Kinetics |
Rate Law |
Reactions |
Oxidation / Reduction
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Kinetics program for iron(III) catalyzed decomposition of hydrogen peroxide Merrer, Robert J.
A computer program for use in general chemistry has been written in Basic that calculates rate constants and activation energy for the iron(III) catalyzed decomposition of hydrogen peroxide.
Merrer, Robert J. J. Chem. Educ. 1973, 50, 514.
Kinetics |
Rate Law |
Catalysis
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Cooking Succulent Roasts Plumb, Robert C.; Davis, Adelle
Allowing a roast to gradually warm to the desired internal temperature produces superior results.
Plumb, Robert C.; Davis, Adelle J. Chem. Educ. 1973, 50, 425.
Consumer Chemistry |
Food Science |
Kinetics |
Equilibrium |
Rate Law |
Applications of Chemistry
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Cooking Succulent Roasts Plumb, Robert C.; Davis, Adelle
Allowing a roast to gradually warm to the desired internal temperature produces superior results.
Plumb, Robert C.; Davis, Adelle J. Chem. Educ. 1973, 50, 425.
Consumer Chemistry |
Food Science |
Kinetics |
Equilibrium |
Rate Law |
Applications of Chemistry
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The hydroxylaminolysis of penicillin G. A kinetic experiment Stuckwisch, C. G.
Penicillin reacts with hydroxylamine to yield a hydroxamic acid, which gives a colored complex with iron (III).
Stuckwisch, C. G. J. Chem. Educ. 1972, 49, 539.
Kinetics |
Rate Law |
Titration / Volumetric Analysis
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Passage of fruit flies through a hole. A model for a reversible chemical reaction Runquist, Elizabeth A.; Runquist, Olaf
The passage of fruit flies through a single orifice provides an excellent model for illustrating the principles of equilibrium and chemical dynamics; the results are found to be temperature dependent and reproducible.
Runquist, Elizabeth A.; Runquist, Olaf J. Chem. Educ. 1972, 49, 534.
Reactions |
Equilibrium |
Kinetics |
Rate Law
|
Aquation of tris-(1,10-phenanthroline) iron(II) in acid solution. A kinetics experiment Twigg, Martyn V.
The aquation of tris-(1,10-phenanthroline) iron(II) in acid solution is a reaction for which reliable kinetic data are available and it has an easily measured rate at accessible temperatures.
Twigg, Martyn V. J. Chem. Educ. 1972, 49, 371.
Kinetics |
Rate Law
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The color blind traffic light. An undergraduate kinetics experiment using an oscillating reaction Lefelhocz, John F.
This kinetics experiment involves the student with a qualitative study of the influence of chemical and physical variables on the rate of a specific reaction.
Lefelhocz, John F. J. Chem. Educ. 1972, 49, 312.
Kinetics |
Reactions |
Rate Law
|
Programmable calculators. Simulated experiments Runquist, O.; Olsen, Rodney; Snadden, Bruce
Describes how titration and reaction rate experiments can be simulated on a programmable calculator.
Runquist, O.; Olsen, Rodney; Snadden, Bruce J. Chem. Educ. 1972, 49, 265.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
Rate Law |
Kinetics |
pH
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Computer program for the treatment of data for a kinetic study of the persulfate-iodide clock reaction Lyndrup, Mark L.
Notes the availability of a BASIC program designed to aid students in the treatment of data collected for a kinetic study of the clock reaction between the persulfate and iodide ions.
Lyndrup, Mark L. J. Chem. Educ. 1972, 49, 30.
Kinetics |
Reactions |
Rate Law
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A study of the physical and chemical rates of CaCO3 dissolution in HCl Bassow, Herbert; Hamilton, Doug; Schneeberg, Ben; Stad, Ben
The authors describe the experimental procedure and a discussion of results for a study of the physical and chemical rates of CaCO3 dissolution in HCl.
Bassow, Herbert; Hamilton, Doug; Schneeberg, Ben; Stad, Ben J. Chem. Educ. 1971, 48, 327.
Acids / Bases |
Kinetics |
Reactions |
Rate Law
|
Miscellaneous Alyea, Hubert N.
These twelve overhead projection demonstrations include rates of reactions, clock reactions, the effect of temperature and the presence of a catalyst on the decomposition of hydrogen peroxide, the relationship between viscosity and temperature, equilibria, solubility product, and the common ion effect.
Alyea, Hubert N. J. Chem. Educ. 1970, 47, A437.
Oxidation / Reduction |
Kinetics |
Rate Law |
Reactions |
Acids / Bases |
Catalysis |
Equilibrium |
Precipitation / Solubility
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Chemical queries. Especially for introductory chemistry teachers Young, J. A.; Malik, J. G.; House, J. E., Jr.; Campbell, J. A.
(1) When is the rule valid that the rate of reaction approximately doubles with a ten-degree temperature rise? - answer by House. (2) On the colors of transition metal complexes. (3) On an electrolysis experiment in which an acid solution is used to minimize the hydrolysis of Cu 2+. - answer by Campbell.
Young, J. A.; Malik, J. G.; House, J. E., Jr.; Campbell, J. A. J. Chem. Educ. 1969, 46, 674.
Rate Law |
Kinetics |
Transition Elements |
Coordination Compounds |
Atomic Properties / Structure |
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials |
Acids / Bases
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The law of mass action Berline, Steven; Bricker, Clark
It is the purpose of this paper to present a derivation of the Law of Mass Action that should have meaning and could be used at an elementary level.
Berline, Steven; Bricker, Clark J. Chem. Educ. 1969, 46, 499.
Equilibrium |
Rate Law |
Kinetics
|
From stoichiometry and rate law to mechanism Edwards, John O.; Greene, Edward F.; Ross, John
Examines the rules used by chemists as guidelines in developing mechanisms from stoichiometric and rate law observations.
Edwards, John O.; Greene, Edward F.; Ross, John J. Chem. Educ. 1968, 45, 381.
Stoichiometry |
Rate Law |
Kinetics |
Mechanisms of Reactions |
Equilibrium |
Reactive Intermediates
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The revolution in elementary kinetics and freshman chemistry Wolfgang, Richard
New developments in kinetics so fundamentally affect our most elementary conception of chemical change that they must inevitably be reflected in beginning courses in chemistry; includes an outline for freshmen on elementary chemical dynamics.
Wolfgang, Richard J. Chem. Educ. 1968, 45, 359.
Kinetics |
Rate Law |
Mechanisms of Reactions
|
Alcohols to alkyl halides: A kinetics experiment for elementary chemistry courses Cooley, J. H.; McCown, J. D.; Shill, R. M.
The rate measurement in this procedure is accomplished by direct observation of the change in length or volume of the insoluble layer of an alkyl bromide that is formed from a mixture of alcohol, hydrobromic acid, and sulfuric acid.
Cooley, J. H.; McCown, J. D.; Shill, R. M. J. Chem. Educ. 1967, 44, 280.
Alcohols |
Synthesis |
Kinetics |
Rate Law
|
A new clock reaction preparation of dicinnamalacetone King, L. Carroll; Ostrum, G. Kenneth
Presents a new clock reaction preparation of dicinnamalacetone.
King, L. Carroll; Ostrum, G. Kenneth J. Chem. Educ. 1964, 41, A139.
Reactions |
Kinetics |
Rate Law
|
The hydration of carbon dioxide: A double clock experiment Jones, P.; Haggett, Max L.; Longridge, Jethro L.
This extension of the "Soda Water Clock" experiment provides a quantitative kinetics investigation.
Jones, P.; Haggett, Max L.; Longridge, Jethro L. J. Chem. Educ. 1964, 41, 610.
Reactions |
Rate Law |
Kinetics |
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
A kinetics experiment for first year chemistry Shaefer, William P.
The exchange of iodine atoms between organic and inorganic iodides serves as a kinetics experiment for first year chemistry.
Shaefer, William P. J. Chem. Educ. 1964, 41, 558.
Kinetics |
Isotopes |
Rate Law
|
The oxidation of iodide ion by persulfate ion Moews, P. C., Jr.; Petrucci, R. H.
Presents the oxidation of iodide ion by persulfate ion as an ideal reaction to study as part of an experiment on kinetics.
Moews, P. C., Jr.; Petrucci, R. H. J. Chem. Educ. 1964, 41, 549.
Oxidation / Reduction |
Reactions |
Kinetics |
Rate Law
|
Colorimetric chemical kinetics experiment Corsaro, Gerald
This article describes an experiment in which a photocolorimetric technique is employed to follow a bimolecular reaction rate; the reactants are crystal violet and the hydroxide ion.
Corsaro, Gerald J. Chem. Educ. 1964, 41, 48.
Kinetics |
Rate Law |
Reactions
|
A simple kinetics experiment for general chemistry laboratory Cone, W. H.; Hermens, R. A.
This simple kinetics experiment examines the oxidation of benzoic acid by potassium peroxodisulfate in the presence of catalytic amounts of silver ion.
Cone, W. H.; Hermens, R. A. J. Chem. Educ. 1963, 40, 421.
Kinetics |
Rate Law |
Oxidation / Reduction |
Catalysis
|
A constant temperature reaction vessel for the thermal decomposition of solids Prout, E. G.; Herley, P. J.
Describes an apparatus suitable for studying the thermal decomposition of potassium permanganate in high vacuum.
Prout, E. G.; Herley, P. J. J. Chem. Educ. 1960, 37, 643.
Laboratory Equipment / Apparatus |
Solids |
Rate Law |
Kinetics
|
Determination of reaction rates with an A.C. conductivity bridge: A student experiment Chesick, J. P.; Patterson, A., Jr.
Describes a quantitative experiment in chemical kinetics suitable for advanced freshmen or physical chemistry; it involves a study of the solvolysis of tertiary butyl chloride by means of conductance measurements.
Chesick, J. P.; Patterson, A., Jr. J. Chem. Educ. 1960, 37, 242.
Conductivity |
Kinetics |
Rate Law
|
The formaldehyde clock reaction Barrett, Richard L.
The formaldehyde clock reaction has some advantages over the familiar iodine clock and deserves to be better known.
Barrett, Richard L. J. Chem. Educ. 1955, 32, 78.
Reactions |
Kinetics |
Rate Law |
Aldehydes / Ketones
|
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