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Blue Bottle, Red and Blue Bottle Color changes are caused by reactions of oxygen in the air with chemicals in a solution. The colors fade over time, but can be regenerated by shaking the flask containing the solution.
Kinetics |
Mechanisms of Reactions |
Oxidation / Reduction
Induction by Iron(II) of the Oxidation of Iodide by Dichromate Acidic aqueous solutions containing dichromate and iodide ions are mixed with no reaction. The addition of a solution of iron(II) ion induces the rapid formation of brown triiodide ion.
the following mechanism has been proposed at high temperatures: (1) NO2 + CO O-N-O-C-O (slow) (2) O-N-O-C-O NO + CO2 (fast) Check the box for each species that is an intermediate in this mechanism.
has the following rate expression at high temperatures:
Rate=k[NO2][CO]
Is the following mechanism compatible with the experimental information? (1) NO2 + CO O-N-O-C-O (slow) (2) O-N-O-C-O NO + CO2 (fast) Choose the best answer.
Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) ComplexesRichard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction. Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ.2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
Dynamic Reaction Figures: An Integrative Vehicle for Understanding Chemical ReactionsEmeric Schultz Describes the dynamic reaction figure, a flexible learning tool that can be used to balance chemical equations, predict the results of potential reactions, present the underlying mechanism of reactions, and solve quantitative problems in a number of areas. Schultz, Emeric. J. Chem. Educ.2008, 85, 386.
Acids / Bases |
Aqueous Solution Chemistry |
Mechanisms of Reactions |
Nonmajor Courses
The Glyoxal Clock ReactionJulie B. Ealy, Alexandra Rodriguez Negron, Jessica Stephens, Rebecca Stauffer, and Stanley D. Furrow The glyoxal clock reaction has been adapted to a general chemistry kinetics lab to determine the order of the reacting species using a Calculator Based Laboratory or LabPro equipment. Ealy, Julie B.; Negron, Alexandra Rodriguez; Stephens, Jessica; Stauffer, Rebecca; Furrow, Stanley D. J. Chem. Educ.2007, 84, 1965.
Mechanism-Based Kinetics SimulatorRobert M. Hanson Simulate the kinetics of a reaction based on its mechanism using JavaScript. The idea is to write a mechanism and, based on that, follow the course of concentrations or rates of change in concentration of reactants, catalysts, intermediates, and products over time.
Kinetics |
Catalysis |
Mechanisms of Reactions
Mechanisms That Interchange Axial and Equatorial Atoms in Fluxional ProcessesMarion E. Cass, Henry S. Rzepa, King Kuok Hii The Berry pseudorotation is a classical mechanism for interchanging axial and equatorial ligands in molecules with trigonal bipyramidal geometry. Teaching this mechanism presents particular pedagogic problems due to both its dynamic and three dimensional character. The approach taken here illustrates these processes using interactive animations embedded in a Web page and overcomes many limitations of a printed page.
Computational Chemistry |
Molecular Properties / Structure |
Nonmetals |
Enantiomers |
NMR Spectroscopy |
Mechanisms of Reactions |
Molecular Mechanics / Dynamics
ChemPaths 104 W Feb 23John W. Moore Today in Chem 104:
* Lecture: Mechanisms of Reactions
* Reading:
Kotz, Ch. 15, Sec. 5-6
Moore, Ch. 13, Sec. 6-76
* Homework #5 due by 11:55 pm F Feb 25
* Excel Assignment due in first discussion section this week
* Quiz 4 in second discussion section this week
NO + CO2 
