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Entropy These processes are shown in reverse. The situations shown are so highly improbable that we would not expect to observe them in nature.
Thermodynamics
Endothermic Reaction Solid barium hydroxide octahydrate (Ba(OH)2*8H2O) and ammonium thiocyanate (NH4SCN) are mixed in a beaker, which is then placed on a few drops of water on a small board. The reaction that occurs is highly endothermic.
Thermodynamics : GibbsFromHSandT (5 Variations)
On the space shuttle, the carbon dioxide produced by the astronauts is handled by an environmental control system that utilizes the following reaction. H° = -138.4 kJ and S° = -139 J/K
Calculate G° at 25°C for this reaction.
Flame Emission Spectrometry in General Chemistry Labs: Solubility Product (Ksp) of Potassium Hydrogen PhthalateFrazier W. Nyasulu, William Cusworth III, David Lindquist, and John Mackin In this general chemistry laboratory, flame emission spectrometry is used to determine the potassium ion concentration in saturated solutions of potassium hydrogen phthalate. From these data the solubility products, the Gibbs free energies of solution, the standard enthalpy of solution, and the standard entropy of solution are calculated. Nyasulu, Frazier W.; Cusworth, William, III; Lindquist, David; Mackin, John. J. Chem. Educ.2007, 84, 456.
Acids / Bases |
Atomic Properties / Structure |
Spectroscopy |
Equilibrium |
Quantitative Analysis |
Thermodynamics |
Titration / Volumetric Analysis |
Solutions / Solvents |
Aqueous Solution Chemistry |
Atomic Spectroscopy
Discovering the Thermodynamics of Simultaneous Equilibria. An Entropy Analysis Activity Involving Consecutive EquilibriaThomas H. Bindel This activity explores the thermodynamics of simultaneous, consecutive equilibria and is appropriate for second-year high school or AP chemistry. Students discover that a reactant-favored (entropy-diminishing) reaction can be caused to happen if it is coupled with a product-favored reaction of sufficient entropy production. Bindel, Thomas H. J. Chem. Educ.2007, 84, 449.
The Free EnergyEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Thermodynamics
Gibbs Free Energy in BiologyJohn W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Thermodynamics |
Metabolism |
Bioenergetics
ChemPaths 104 W Mar 30John W. Moore Today in Chem 104:
* Lecture: Gibbs Free Energy
* Reading:
Kotz: Ch. 19, Sec. 5-7
Moore: Ch. 18, Sec. 5-8
* Homework #8 due by 11:55 PM F Apr 1
* Quiz in second discussion section this week.
* Lab this week is #11, Electrochemical Cells
H° = -138.4 kJ and 
2 SO3(g)
