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Solutions Reactions and demonstrations exploring the concepts of solutions.
Noncovalent Interactions |
Physical Properties |
Precipitation / Solubility |
Solutions / Solvents |
Calorimetry / Thermochemistry |
Applications of Chemistry |
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Conductivity |
Reactions |
Titration / Volumetric Analysis |
Liquids |
Solids |
Equilibrium |
Transport Properties
Denaturation of Protein by Strong AcidJohn W. Moore, Jerrold J. Jacobsen, Gary Trammell, Kristin Johnson "Strong acid denatures egg white proteins.This video contains voiceover:""The tertiary structure of egg white proteins is held together by hydrogen bonding and hydrophobic interactions. Adding strong acid to the protein disrupts the intermolecular forces, and the tertiary structure is lost. The loss in protein structure is called denaturation. The proteins precipitate, forming a white solid."""
Acids_and_Bases : BufferingCapacity (20 Variations) If a buffer is prepared using 0.75 mol CH3COOH and 0.45 mol CH3COO- in 1 liter of aqueous solution, is the buffering capacity of the solution great enough to maintain its pH if 10 g NaOH is added?
The Correlation of Binary Acid Strengths with Molecular Properties in First-Year ChemistryTravis D. Fridgen This article replaces contradictory explanations for the strengths of different binary acids in first-year chemistry textbooks with a single explanation that uses a BornHaber cycle involving homolyic bond dissociation energies, electron affinities, and ion solvation enthalpies to rationalize trends in the strengths of all binary acids. Fridgen, Travis D. J. Chem. Educ.2008, 85, 1220.
Acids / Bases |
Atomic Properties / Structure |
Aqueous Solution Chemistry |
Physical Properties |
Thermodynamics
Equilibrium Constants and Water Activity RevisitedDavid Keeports Subtle arguments based upon the use of chemical potentials show that numerical values of solute molar concentrations can be used as good approximate activities in equilibrium calculations for reactions involving dilute solutions. Keeports, David. J. Chem. Educ.2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
Equilibrium Constants and Water Activity RevisitedE. J. Behrman In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols. Behrman, E. J. J. Chem. Educ.2006, 83, 1290.