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Consider the graph above. Which of these substances has the highest specific heat capacity?
Calorimetry / Thermochemistry |
Heat Capacity
Thermochemistry : HeatCapacityLiq (4 Variations)
100 g of water (c=4.184 J/g.oC), 100 g of ethanol (c=2.46 J/g.oC), 100 g of carbon tetrachloride (c=0.861 J/g.oC), and 100 g of ethylene glycol (c=2.42 J/g.oC) at 50oC were each placed into a separate coffee cup calorimeter and the temperature recorded. The temperature of the surroundings was 20oC. After one hour the temperature of which substance would have changed by the largest amount? Assume that the rate of heat transfer from the coffee cup to the surroundings was the same in each case.
In an experiment, 50 g of a metal was heated to 100oC and placed in 200 g of a liquid at 25oC. Which of the following combinations of metal and liquid will produce the largest temperature increase in the liquid? (Assume that there is no transfer of energy to the surroundings.)
J. Chem. Educ. 1999,76, 1578–1583John Andraos Corrections to the article A Streamlined Approach to Solving Simple and Complex Kinetic Systems Analytically. Andraos, John. J. Chem. Educ.2008, 85, 1624.
Kinetics |
Mechanisms of Reactions |
Theoretical Chemistry
The Correlation of Binary Acid Strengths with Molecular Properties in First-Year ChemistryTravis D. Fridgen This article replaces contradictory explanations for the strengths of different binary acids in first-year chemistry textbooks with a single explanation that uses a BornHaber cycle involving homolyic bond dissociation energies, electron affinities, and ion solvation enthalpies to rationalize trends in the strengths of all binary acids. Fridgen, Travis D. J. Chem. Educ.2008, 85, 1220.
Acids / Bases |
Atomic Properties / Structure |
Aqueous Solution Chemistry |
Physical Properties |
Thermodynamics
Appreciating OxygenHilton M. Weiss Photosynthetic flora and microfauna utilize light from the sun to convert carbon dioxide and water into carbohydrates and oxygen. While these carbohydrates and their derivative hydrocarbons are generally considered to be fuels, it is the thermodynamically energetic oxygen molecule that traps, stores, and provides almost all of the energy that powers life on earth. Weiss, Hilton M. J. Chem. Educ.2008, 85, 1218.
Heat CapacitiesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Heat Capacity
Heat Capacity and Microscopic ChangesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Heat Capacity |
Kinetic-Molecular Theory
Energy and the Formation of IonsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.