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Blue Bottle, Red and Blue Bottle Color changes are caused by reactions of oxygen in the air with chemicals in a solution. The colors fade over time, but can be regenerated by shaking the flask containing the solution.
Kinetics |
Mechanisms of Reactions |
Oxidation / Reduction
Induction by Iron(II) of the Oxidation of Iodide by Dichromate Acidic aqueous solutions containing dichromate and iodide ions are mixed with no reaction. The addition of a solution of iron(II) ion induces the rapid formation of brown triiodide ion.
the following mechanism has been proposed at high temperatures: (1) NO2 + CO O-N-O-C-O (slow) (2) O-N-O-C-O NO + CO2 (fast) Check the box for each species that is an intermediate in this mechanism.
Computational Analysis of Stereospecificity in the Cope RearrangementLaura Glish and Timothy W. Hanks Experimental product distributions from the Cope rearrangement of disubstituted 1,5-hexadienes can be readily understood by computer modeling of the various possible transitions states. Visual analysis of these geometries allow students to interpret the computational results by analogy to the familiar chair and boat conformations of substituted cyclohexanes. Glish, Laura; Hanks, Timothy W. J. Chem. Educ.2007, 84, 2001.
Alkenes |
Computational Chemistry |
Conformational Analysis |
Medicinal Chemistry |
MO Theory |
Molecular Modeling |
Mechanisms of Reactions
A More Realistic Teaching Style in Spectroscopic InstructionMar Gómez Gallego, Santiago Romano, Miguel A. Sierra, and Enrique Nieto A practical application of spectroscopic analysis in intermediate and advanced organic chemistry to determine reaction mechanisms and identify products; provides three specific problems. Gallego, Mar Gómez; Romano, Santiago; Sierra, Miguel A.; Nieto, Enrique. J. Chem. Educ.2001, 78, 765.
ChemPaths 104 W Feb 23John W. Moore Today in Chem 104:
* Lecture: Mechanisms of Reactions
* Reading:
Kotz, Ch. 15, Sec. 5-6
Moore, Ch. 13, Sec. 6-76
* Homework #5 due by 11:55 pm F Feb 25
* Excel Assignment due in first discussion section this week
* Quiz 4 in second discussion section this week
Mechanisms of Reactions
ChemPaths 104 F Feb 25John W. Moore Today in Chem 104:
* Lecture: Problem-Solving Session
* No assigned reading for today.
* Homework #5 due by 11:55 pm Today!
* Biomolecules Tutorial Enzymes (including Enzymes Quiz)
is due Wed. Mar. 2, at 11:55 pm.
Mechanisms of Reactions
Reaction MechanismsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
NO + CO2 
