22.5 Acidity of Alpha Hydrogen Atoms: Enolate Ion Formation
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Denaturation of Protein by Strong AcidJohn W. Moore, Jerrold J. Jacobsen, Gary Trammell, Kristin Johnson "Strong acid denatures egg white proteins.This video contains voiceover:""The tertiary structure of egg white proteins is held together by hydrogen bonding and hydrophobic interactions. Adding strong acid to the protein disrupts the intermolecular forces, and the tertiary structure is lost. The loss in protein structure is called denaturation. The proteins precipitate, forming a white solid."""
Extraction of Acid with Base Water and diethyl ether are shaken in a separatory funnel with a small amount of red indophenol. The non-ionic indophenol remains in the ether layer, coloring it red. Addition of sodium hydroxide converts the indophenol to its blue ionic acid anion which is extracted into the water layer turning it blue.
Reactions : AcidBaseRxns (20 Variations) In order to answer the following questions, write the net ionic equation for the reaction between equal volumes of 0.10 M solutions of the following acid and base:
KOH(aq) + HBr(aq)
What are the reaction products? Does the reaction yield an acidic, basic, or neutral aqueous solution?
Chemical Aspects of General Anesthesia: Part I. From Ether to HalothaneRobert Brunsvold and Daryl L. Ostercamp Summarizes general anesthesia from 1846 to 1956. Events leading up to the adoption of a "balanced" approach, where a sequence of individual compounds is used rather than a single agent, are described. Brunsvold, Robert; Ostercamp, Daryl L. J. Chem. Educ.2006, 83, 1821.
Acids / Bases |
Bioorganic Chemistry |
Chirality / Optical Activity |
Drugs / Pharmaceuticals |
Medicinal Chemistry |
Synthesis
Organic Acids without a Carboxylic Acid Functional GroupG. V. Perez and Alice L. Perez This paper presents several organic molecules that have been labeled as acids but do not contain a carboxylic acid functional group. Various chemical principles such as pKa, tautomerization, aromaticity, conformation, resonance, and induction are explored. Perez, G. V.; Perez, Alice L. J. Chem. Educ.2000, 77, 910.
Acids / Bases |
Molecular Properties / Structure |
Nomenclature / Units / Symbols |
Phenols |
Carboxylic Acids |
Aromatic Compounds
Thermodynamic and Kinetic Controlled Enolates: A Project for a Problem-Oriented Laboratory CourseAugustine Silveira Jr., Michael A. Knopp, and Jhong Kim A microscale preparation of thermodynamic and kinetic enolates is given as an undergraduate research laboratory. This experiment provides student involvement and discussion. Silveira, Augustine, Jr.; Knopp, Michael A.; Kim, Jhong. J. Chem. Educ.1998, 75, 78.
Acids (GCMP)David M. Whisnant Acids: this is a resource in the collection "General Chemistry Multimedia Problems". We will observe the reaction of sodium bicarbonate with three acid solutions. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Acids / Bases
Acids and Salts (GCMP)David M. Whisnant Acids and Salts: this is a resource in the collection "General Chemistry Multimedia Problems". This problem will explore a few properties of common acids and their salts. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Acids / Bases
Oxides (GCMP)David M. Whisnant Oxides: this is a resource in the collection "General Chemistry Multimedia Problems". In this problem we will explore the properties of the oxides of a few elements. We will add samples of the oxides to universal indicator solution and learn about the acid-base character of the oxides. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
