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Nucleophilic Substitution Reactions Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Chart for Deciding Mechanism for Reaction of Alkyl Halide with Nucleophile/BaseMcClelland, Bruce W. The decision chart offered here is based upon the well-known and accepted characteristics of the reaction system mechanisms described in typical introductory organic chemistry textbooks. McClelland, Bruce W. J. Chem. Educ.1994, 71, 1047.
Organic lecture demonstrationsSilversmith, Ernest F. Organic chemistry may not be known for its spectacular, attention getting chemical reactions. Nevertheless, this author describes a few organic chemistry reactions that put points across and generate interest. This article provides a convenient sources of demonstrations and urges others to add to the collection. Demonstrations concerning: carbohydrates, spectroscopy, proteins, amines, carbohydrates, carboxylic acids, and much more. Silversmith, Ernest F. J. Chem. Educ.1988, 65, 70.
