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Reactions: Acetylene Preparation of acetylene and the reaction of chlorine with acetylene are demonstrated. An antique carbide lamp is also demonstrated.
Hydration of Acetylene: A 125th AnniversaryDmitry A. Ponomarev and Sergey M. Shevchenko The discovery the hydration of alkynes catalyzed by mercury ions by Mikhail Kucherov made possible industrial production of acetaldehyde from acetylene and had a profound effect on the development of industrial chemistry in the 1920th centuries. Ponomarev, Dmitry A.; Shevchenko, Sergey M. J. Chem. Educ.2007, 84, 1725.
Addition Reactions |
Aldehydes / Ketones |
Alkynes |
Catalysis |
Industrial Chemistry |
Reactions
A Green Alternative to Aluminum Chloride Alkylation of XyleneGrigoriy A. Sereda and Vikul B. Rajpara Presents a simple laboratory experiment that introduces organic chemistry students to the basic principles of green technologies, such as lack of toxic or bulk byproducts, nontoxicity, and reusability of the catalyst. Sereda, Grigoriy A.; Rajpara, Vikul B. J. Chem. Educ.2007, 84, 692.
Alkylation |
Green Chemistry |
Catalysis |
NMR Spectroscopy |
Reactions |
Synthesis
Ozonolysis Problems That Promote Student ReasoningRay A. Gross Jr. The structural features inherent in acyclic monoterpenes that follow the isoprene rule often lead to unique sets of ozonolysis products from which their structures, excluding stereochemistry, can be determined from molecular formulas only. This article shows how students may elucidate the structures of these compounds by analysis of the oxidative and reductive workup products. Gross, Ray A., Jr. J. Chem. Educ.2006, 83, 604.
