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Diels-Alder Visualization Several computer animations of a Diels-Alder reaction that were created as an undergraduate student project are presented.
Addition Reactions |
Alkenes
Addition Reactions of Alkenes The Diels-Alder reaction, addition of oxygen to tetrakis(N, N-dimethylamino) ethylene, polymerization of ethylene, and addition of iodine to a-pinene are demonstrated. Molecular models of ethene are shown.
Polar Addition to C=C Group: Why Is Anti-Markovnikov Hydroboration–Oxidation of Alkenes Not "Anti-"?Predrag-Peter Ilich, Lucas S. Rickertsen, and Erienne Becker The authors redefine Markovnikov or anti-Markovnikov regioselectivity and propose that the teaching of organic chemistry should be based on robust and portable concepts such as energy difference and atomic charge rather than historical labels. Ilich, Predrag-Peter; Rickertsen, Lucas S.; Becker, Erienne. J. Chem. Educ.2006, 83, 1681.
Addition Reactions |
Alkenes |
Computational Chemistry |
Mechanisms of Reactions |
Molecular Modeling
Iodolactonization of 4-Pentenoic Acid R. David Crouch, Alexander Tucker-Schwartz, and Kathryn Barker Describes an experiment in which 4-pentenoic acid is converted into a lactone via iodolactonization. Crouch, R. David; Tucker-Schwartz, Alexander; Barker, Kathryn. J. Chem. Educ.2006, 83, 921.
Alkenes |
Carboxylic Acids |
IR Spectroscopy |
Mechanisms of Reactions |
NMR Spectroscopy |
Reactions |
Synthesis
Moving Past Markovnikov's RuleE. Eugene Gooch Extension of the Markovnikov Rule for addition reactions across a carbon-carbon double bond. Gooch, E. Eugene. J. Chem. Educ.2001, 78, 1358.
