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5 Assessment Questions
8 Journal Articles
Assessment Questions: First 3 results
Electrophilic Substitution (3 Variations)
A collection of 3 assessment questions about Electrophilic Substitution
Carbocations |
Electrophilic Substitution
Nucleophilic Substitution (18 Variations)
A collection of 18 assessment questions about Nucleophilic Substitution
Nucleophilic Substitution |
Carbocations |
Alcohols |
Stereochemistry |
Epoxides |
Ethers
Substitution and Elimination (6 Variations)
A collection of 6 assessment questions about Substitution and Elimination
Mechanisms of Reactions |
Nucleophilic Substitution |
Elimination Reactions |
Carbocations |
Stereochemistry |
Alcohols |
Ethers
View all 5 results
Journal Articles: First 3 results.
Pedagogies:
Pyrolysis of Aryl Sulfonate Esters in the Absence of Solvent: E1 or E2? A Puzzle for the Organic Laboratory  John J. Nash, Marnie A. Leininger, and Kurt Keyes
An aryl sulfonate ester is synthesized and then pyrolyzed at reduced pressure. The volatile products are analyzed using gas chromatography to determine whether the thermal decomposition occurs via an E1 or E2 mechanism.
Nash, John J.; Leininger, Marnie A.; Keyes, Kurt . J. Chem. Educ. 2008, 85, 552.
Alkenes |
Carbocations |
Elimination Reactions |
Gas Chromatography |
Mechanisms of Reactions |
Synthesis
A Discovery-Based Experiment Involving Rearrangement in the Conversion of Alcohols to Alkyl Halides  Richard A. Kjonaas and Ryand J. F. Tucker
This article reports a discovery-based experiment in which students convert three alcohols to alkyl halides under acidic conditions and record the 13C NMR spectrum in each case. By comparing the number of resonances observed with the number of resonances predicted for each possible product, students draw several conclusions about the resulting rearrangement.
Kjonaas, Richard A.; Tucker, Ryand J. F. J. Chem. Educ. 2008, 85, 100.
Alcohols |
Carbocations |
Gas Chromatography |
NMR Spectroscopy |
Nucleophilic Substitution
Synthesis of Anomeric Methyl Fructofuranosides and Their Separation on an Ion-exchange Resin  Erkki Nurminen, Päivi Poijärvi, Katja Koskua, and Jari Hovinen
Treatment of d-fructose with methanol in the presence of acid as a catalyst gives a mixture of methyl--d-fructopyranoside, methyl-a-D-fructofuranoside, and methyl--d- fructofuranoside, which are separated on an ion exchange column and characterized polarimetrically.
Nurminen, Erkki; Poijärvi, Päivi; Koskua, Katja; Hovinen, Jari. J. Chem. Educ. 2007, 84, 1480.
Carbocations |
Chirality / Optical Activity |
Chromatography |
Ion Exchange |
NMR Spectroscopy |
Synthesis |
Thin Layer Chromatography |
Carbohydrates
View all 8 articles