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Alkanes and Cycloalkanes The structures and conformations of alkanes and cycloalkanes and the vibrational, rotational, and translational motion of alkanes in the gas phase are demonstrated.
Alkanes / Cycloalkanes
Combustion of Methane Methane combustion in balloons, a Bunsen burner flame, and methane combustion in chlorine are demonstrated.
Alkanes / Cycloalkanes |
Reactions
Combustion of Hexane Combustion of hexane with limited oxygen and addition of water to burning hexane are demonstrated.
Study of Molecular-Shape Selectivity of Zeolites by Gas ChromatographyPei-Yu Chao, Yao-Yuan Chuang, Grace Hsiuying Ho, Shiow-Huey Chuang, Tseng-Chang Tsai, Chi-Young Lee, Shang-Tien Tsai, and Jun-Fu Huang This analytical or physical chemistry sorption experiment uses hexane isomers as probe molecules to demonstrate the "molecular-shape selectivity" behavior of zeolites. Students can also modify the sorption protocol to build their own experiments. Chao, Pei-Yu; Chuang, Yao-Yuan; Ho, Grace Hsiuying; Chuang, Shiow-Huey; Tsai, Tseng-Chang; Lee, Chi-Young; Tsai, Shang-Tien; Huang, Jun-Fu. J. Chem. Educ.2008, 85, 1558.
Alkanes / Cycloalkanes |
Constitutional Isomers |
Gas Chromatography |
Molecular Properties / Structure |
Physical Properties |
Separation Science |
Solid State Chemistry |
Molecular Recognition
The Synthesis of N-Benzyl-2-azanorbornene via Aqueous Hetero Diels–Alder ReactionXavier Sauvage and Lionel Delaude Characterization of the product of this organic synthesis through IR and NMR data analysis provides valuable material to familiarize students with different types of protonproton coupling patterns and their typical ranges, serves to illustrate the concepts of green chemistry and atom efficiency, and can be used to exemplify structural analysis and computational studies. Sauvage, Xavier; Delaude, Lionel. J. Chem. Educ.2008, 85, 1538.
Alkenes |
Aqueous Solution Chemistry |
Conformational Analysis |
Green Chemistry |
IR Spectroscopy |
Molecular Modeling |
NMR Spectroscopy |
Stereochemistry |
Synthesis
A-DNA and B-DNA: Comparing Their Historical X-ray Fiber Diffraction ImagesAmand A. Lucas This paper provides a comparative explanation of the structural content of the diffraction diagrams of A-DNA and B-DNA that facilitated the discovery of the double-helical structure of DNA by Watson and Crick in 1953. This analysis is supported a method that simulates both A-DNA and B-DNA X-ray images optically. Lucas, Amand A. J. Chem. Educ.2008, 85, 737.
AlkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
CycloalkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
Hexane 1 (GCMP)David M. Whisnant Hexane 1: this is a resource in the collection "General Chemistry Multimedia Problems". Hexane, a liquid hydrocarbon with the formula C6H14, burns when ignited in the presence of oxygen. In this problem we will observe videos of this combustion reaction. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.