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Alkanes and Cycloalkanes The structures and conformations of alkanes and cycloalkanes and the vibrational, rotational, and translational motion of alkanes in the gas phase are demonstrated.
Study of Molecular-Shape Selectivity of Zeolites by Gas ChromatographyPei-Yu Chao, Yao-Yuan Chuang, Grace Hsiuying Ho, Shiow-Huey Chuang, Tseng-Chang Tsai, Chi-Young Lee, Shang-Tien Tsai, and Jun-Fu Huang This analytical or physical chemistry sorption experiment uses hexane isomers as probe molecules to demonstrate the "molecular-shape selectivity" behavior of zeolites. Students can also modify the sorption protocol to build their own experiments. Chao, Pei-Yu; Chuang, Yao-Yuan; Ho, Grace Hsiuying; Chuang, Shiow-Huey; Tsai, Tseng-Chang; Lee, Chi-Young; Tsai, Shang-Tien; Huang, Jun-Fu. J. Chem. Educ.2008, 85, 1558.
Alkanes / Cycloalkanes |
Constitutional Isomers |
Gas Chromatography |
Molecular Properties / Structure |
Physical Properties |
Separation Science |
Solid State Chemistry |
Molecular Recognition
Percy Julian, Robert Robinson, and the Identity of EseretholeAddison Ault The Nova production Percy JulianForgotten Genius, which included the very public disagreement over the identity of "eserethole," the key intermediate for the synthesis of the alkaloid physostigmine, left three important chemical questions unanswered. Ault, Addison. J. Chem. Educ.2008, 85, 1524.
Constitutional Isomers |
Enantiomers |
Natural Products |
Stereochemistry |
Synthesis
A Green, Guided-Inquiry Based Electrophilic Aromatic Substitution for the Organic Chemistry LaboratoryEric Eby and S. Todd Deal This alternative, electrophilic aromatic substitutionan iodination reaction of salicylamide, a popular analgesicuses environmentally friendly reagents and serves as a guided-inquiry experiment in which students are asked to predict the orientation of the substitution reaction and determine the product's structure using FT-IR spectroscopy. Eby, Eric; Deal, S. Todd. J. Chem. Educ.2008, 85, 1426.
ChemPaths 104 F Jan 21John W. Moore Today in Chem 104:
* Lecture: Organic Structures; Isomers
* Reading:
Kotz Ch. 10, Sec. 1-2; Appendix E (pp. A-17-20)
Moore Ch. 3: Sec. 3-4; Ch. 8: Sec. 3, 5; App E (pp. A.26-A.30)
* Practice Quiz and Homework #1 are due by 11:55 pm M Jan 24.
Alkanes / Cycloalkanes |
Constitutional Isomers
AlkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
CycloalkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
