| Journal Articles: 59 results |
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Connecting Solubility, Equilibrium, and Periodicity in a Green, Inquiry Experiment for the General Chemistry Laboratory Kristen L. Cacciatore, Jose Amado, Jason J. Evans, and Hannah Sevian Presents a novel first-year chemistry experiment that asks students to replicate procedures described in sample lab reports that lack essential information. This structure is designed to promote students' experimental design and data analysis skills as well as their understanding of the importance and essential qualities of written and verbal communication between scientists. Cacciatore, Kristen L.; Amado, Jose; Evans, Jason J.; Sevian, Hannah. J. Chem. Educ. 2008, 85, 251.
Equilibrium |
Green Chemistry |
Periodicity / Periodic Table |
Solutions / Solvents |
Stoichiometry |
Titration / Volumetric Analysis
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(Strept)Avidin–Biotin: Two Interrelated Experiments for the Introductory Chemistry Laboratory David E. Hansen, Dengda Tang, Jon A. Sanborn, and Mark D. Marshall Describes a two-experiment sequence focusing on the noncovalent complex between the egg white protein avidin (or the similar protein streptavidin, which is expressed by the bacterium Streptomyces avidinii) and the essential cofactor biotin. The equilibrium constant for the binding of HABA to avidin is calculated from the data collected. Hansen, David E.; Tang, Dengda; Sanborn, Jon A.; Marshall, Mark D. J. Chem. Educ. 2006, 83, 777.
Bioorganic Chemistry |
Computational Chemistry |
Equilibrium |
Titration / Volumetric Analysis
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Quantitative Determination of Citric and Ascorbic Acid in Powdered Drink Mixes: A High School or General Chemistry Experiment Samuella B. Sigmann and Dale E. Wheeler This article provides a method to quantitatively determine the amount of both citric and ascorbic acid in a given sample of a powdered drink mix. The total moles of acid in the sample are determined by titration with sodium hydroxide. Moles of ascorbic acid are determined by titration with potassium iodate. Moles of citric acid are determined by difference. Sigmann, Samuella B.; Wheeler, Dale E. J. Chem. Educ. 2004, 81, 1479.
Acids / Bases |
Aqueous Solution Chemistry |
Consumer Chemistry |
Food Science |
Quantitative Analysis |
Titration / Volumetric Analysis
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Canadian Tire Money: An Analogy for Use When Discussing Weak Acid–Strong Base Titrations Arthur M. Last In this article, use is made of the practice of one well-known Canadian retail chain in returning to its customers a small percentage of an item's purchase price in the form of imitation bank notes that can subsequently be spent in the chain's stores. An analogy is drawn between this practice and the determination of the pKa of a weak acid by titrating it with a strong base, taking into account the hydrolysis of the anion produced. Last, Arthur M. J. Chem. Educ. 2003, 80, 1403.
Acids / Bases |
Titration / Volumetric Analysis
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Comparing the Titrations of Mixed-Acid Solutions Using Dropwise and Constant-Flow Techniques Paul Charlesworth, Matthew J. Seguin, and David J. Chesney Real-time titration techniques are found to result in significantly decreased analysis times while maintaining a low experimental error. Charlesworth, Paul; Seguin, Matthew J.; Chesney, David J. J. Chem. Educ. 2003, 80, 1311.
Acids / Bases |
Laboratory Computing / Interfacing |
Quantitative Analysis |
Titration / Volumetric Analysis |
Laboratory Equipment / Apparatus |
Laboratory Management
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Principal Species and pH in Acid–Base Solutions Robert M. Hanson Web page that allows one to determine the concentrations of principal species in a variety of solutions or mixtures of solutions; also allows a virtual titration. Hanson, Robert M. J. Chem. Educ. 2002, 79, 1486.
Acids / Bases |
Aqueous Solution Chemistry |
Solutions / Solvents |
Titration / Volumetric Analysis |
Enrichment / Review Materials
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Microscale pH Titrations Using an Automatic Pipet Edward B. Flint, Carrie L. Kortz, and Max A. Taylor A technique for microscale pH titrations using 1-5 mL of analyte and titrant. Flint, Edward B.; Kortz, Carrie L.; Taylor, Max A. J. Chem. Educ. 2002, 79, 705.
Acids / Bases |
Instrumental Methods |
Microscale Lab |
pH |
Titration / Volumetric Analysis
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Predicting Acid-Base Titration Curves without Calculations Dennis W. Barnum In this paper a qualitative and systematic method for sketching titration curves is presented. Even the more complex cases such as salts or polyprotic acids and bases are treated just as easily as simple monoprotic acids. Having students predict the shape of titration curves from known equilibrium constants helps to focus attention on the general principles without distraction by the mathematics. Barnum, Dennis W. J. Chem. Educ. 1999, 76, 938.
Acids / Bases |
Quantitative Analysis |
Water / Water Chemistry |
Equilibrium |
Learning Theories |
Titration / Volumetric Analysis |
Chemometrics
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A Unified Titration Formula P. Glaister In a number of standard titrations, a volume of a monoprotic base MOH at a specific concentration is added to a volume of a monoprotic acid HA at a specific concentrations. Four different types of titration are possible, depending on whether the acid and base are strong or weak. A single unifying formula covering all four cases has been determined. Glaister, P. J. Chem. Educ. 1999, 76, 132.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis
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The Gelation of Poly(Vinyl Alcohol) with Na2B4O7 · 10H2O: Killing Slime K. W. McLaughlin, N. K. Wyffels, A. B. Jentz, and M. V. Keenan The titration of slime with sulfuric acid allows students to examine the relationship between cross-linking, viscosity, and the onset of gelation. This modification to a popular chemistry demonstration produces an interesting chemistry laboratory experiment designed to introduce students to the relationship between molecular structure and the bulk properties of macromolecules. McLaughlin, K. W.; Wyffels, N. K.; Jentz, A. B.; and Keenan, M. V. J. Chem. Educ. 1997, 74, 97.
Titration / Volumetric Analysis
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The Effectiveness of Computer-Assissted Learning in the Teaching of Quantitative Volumetric Analysis Skills in a First-Year University Course Carmel McNaught, Heather Grant, Paul Fritze, Janet Barton, Peter McTigue, and Robert Prosser Study of the effectiveness of a computerized tutorial involving titration-related laboratory procedures at improving the laboratory skills of first-year students with a weak chemistry background. McNaught, Carmel; Grant, Heather; Fritze, Paul; Barton, Janet; McTigue, Peter; Prosser, Robert. J. Chem. Educ. 1995, 72, 1003.
Quantitative Analysis |
Titration / Volumetric Analysis
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From Titration Data to Buffer Capacities: A Computer Experiment for the Chemistry Lab or Lecture Roy W. Clark, Gary D. White, Judith M. Bonicamp, and Exum D. Watts Provides titration curve data that students can plot and analyze using spreadsheets to develop student understanding of pH, derivatives, buffer capacity, and the behavior of dilute buffers; includes sample graphs and analysis. Clark, Roy W.; White, Gary D.; Bonicamp, Judith M.; Watts, Exum D. J. Chem. Educ. 1995, 72, 746.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Chemometrics
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Spreadsheets in General Chemistry: Their Introduction and Application to Complex Titrations Chesick, John P. 167. Time in any course program must be made for instruction in the use of the spreadsheet, and the methodology for doing this continues to be a topic of discussion. Chesick, John P. J. Chem. Educ. 1994, 71, 934.
Laboratory Computing / Interfacing |
Titration / Volumetric Analysis
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A low-cost constant-rate buret Hannum, Steven E. A simple constant-rate delivery system used as a demonstration in general chemistry lab. Hannum, Steven E. J. Chem. Educ. 1993, 70, 1037.
Titration / Volumetric Analysis
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The electrician's multimeter in the chemistry teaching laboratory: Part 2: Potentiometry and conductimetry Sevilla, Fortunato, III; Alfonso, Rafael L.; Andres, Roberto T. Further applications of the multimeter in chemistry laboratories are discussed in this paper: potentiometry, reduction potentials and cell EMF, the Nerst equations, pH measurements, titration, conductimetry, and conduction of solutions. Sevilla, Fortunato, III; Alfonso, Rafael L.; Andres, Roberto T. J. Chem. Educ. 1993, 70, 580.
Acids / Bases |
Solutions / Solvents |
Titration / Volumetric Analysis |
Electrochemistry |
Laboratory Equipment / Apparatus |
Potentiometry
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Estimation of carbonate content of base by Gran's method: A semimicroscale experiment. Vesala, Antti. Carbonate content of a base is determined by titration with HCl using small scale samples and additions. Vesala, Antti. J. Chem. Educ. 1992, 69, 577.
Quantitative Analysis |
Titration / Volumetric Analysis
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An MS-DOS microcomputer controlled titration system Stangeland, Leiv Jonn; Anjo, Dennis M. 136. In this experiment the computer is employed to control the addition rate of titrant based on the change in pH of the analyte system. Stangeland, Leiv Jonn; Anjo, Dennis M. J. Chem. Educ. 1992, 69, 296.
Titration / Volumetric Analysis |
pH |
Laboratory Computing / Interfacing
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Algorithm for plotting titration curves (author response). Rodrigues de Moura, Daniel. Our model, contrary to Jackman's statement, can be applied to redox systems that are pH-dependant. Rodrigues de Moura, Daniel. J. Chem. Educ. 1992, 69, 257.
pH |
Oxidation / Reduction |
Titration / Volumetric Analysis
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Advanced titration plots using spreadsheet scripting Currie, James O., Jr.; Whiteley, Richard V., Jr. 131. A spreadsheet aids in student understanding of acid/base titration calculations. Currie, James O., Jr.; Whiteley, Richard V., Jr. J. Chem. Educ. 1991, 68, 923.
Acids / Bases |
Titration / Volumetric Analysis |
pH |
Laboratory Computing / Interfacing |
Equilibrium
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Chemical equilibrium: III. A few math tricks Gordus, Adon A. The third article in a series on chemical equilibrium that considers a few math "tricks" useful in equilibrium calculations and approximations. Gordus, Adon A. J. Chem. Educ. 1991, 68, 291.
Acids / Bases |
Equilibrium |
Chemometrics |
Titration / Volumetric Analysis
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Titrations of monoprotic acids with sodium hydroxide contaminated by sodium carbonate (the author replies) Michalowski, Tadeusz A basic assumption made in the original article does not reflect the most common practical situation; therefore, some of the conclusions can be misleading if taken as general rules. Michalowski, Tadeusz J. Chem. Educ. 1990, 67, 1072.
Acids / Bases |
Titration / Volumetric Analysis
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Titrations of monoprotic acids with sodium hydroxide contaminated by sodium carbonate Bombi, G. Giorgio; Macca, Carlo; Michalowski, Tadeusz A basic assumption made in the original article does not reflect the most common practical situation; therefore, some of the conclusions can be misleading if taken as general rules. Bombi, G. Giorgio; Macca, Carlo; Michalowski, Tadeusz J. Chem. Educ. 1990, 67, 1072.
Acids / Bases |
Titration / Volumetric Analysis
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The pH of any mixture of monoprotic acids and bases Herman, D. P.; Booth, K. K.; Parker, O. J.; Breneman, G. L. 115. Bits and pieces, 44. The pH of any mixture of monoprotic weak and strong acids and bases can be calculated. A curve can also be plotted for the titration of the mixture by any monoportic weak or strong acid or base. Herman, D. P.; Booth, K. K.; Parker, O. J.; Breneman, G. L. J. Chem. Educ. 1990, 67, 501.
Acids / Bases |
Titration / Volumetric Analysis |
pH
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Squaric acid: A workshop for high school chemistry teachers Gesser, H. D.; Baldwin, W. G.; Hickling, G. G. The authors feel that the greatest value from a workshop is obtained when the workshop has a practical focus, with participating teachers experiencing both an experimental challenge, such as they often put to their pupils, and an opportunity to upgrade their knowledge of modern laboratory procedures. Gesser, H. D.; Baldwin, W. G.; Hickling, G. G. J. Chem. Educ. 1990, 67, 388.
Professional Development |
Titration / Volumetric Analysis
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Chemical principles for the introductory laboratory, CHM 384 (Johnson, James F.) Wegner, Carol A comprehensive review of the title program which overviews basic techniques and concepts presented in introductory laboratory courses. Topics include: titration, equilibrium, Ksp, solubility, Beer's law, coordination complexes and first-order rates of reaction. Wegner, Carol J. Chem. Educ. 1988, 65, A47.
Acids / Bases |
Titration / Volumetric Analysis |
UV-Vis Spectroscopy |
Equilibrium |
Solutions / Solvents |
Coordination Compounds |
Kinetics
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E.M.E. Titration lab (Shelton, Roger) Ogata, Philip H. A review of an interactive software program that executes a lab simulation allowing students to master the titration process while helping students understand symbols and empirical formulas and sharpening students' data collection skills. Ogata, Philip H. J. Chem. Educ. 1988, 65, A23.
Titration / Volumetric Analysis
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Rating antacids in Consumer Reports Martin, Geoffrey This article presents a Consumer Reports study on antacid effectiveness via titration. Martin, Geoffrey J. Chem. Educ. 1988, 65, 214.
Acids / Bases |
Titration / Volumetric Analysis |
Consumer Chemistry |
Drugs / Pharmaceuticals |
Food Science
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Potentiometric titration of acidic and basic compounds in household cleaners Lieu, Van T.; Kalbus, Gene E. The potentiometric titration of commercial household cleaners can be used in student laboratories in freshman, analytical, and physical chemistry courses. It can be used for analysis of household cleaners with either one or two component systems, or it can be used for the determination of the dissociation constant. Lieu, Van T.; Kalbus, Gene E. J. Chem. Educ. 1988, 65, 184.
Acids / Bases |
Potentiometry |
Consumer Chemistry |
Titration / Volumetric Analysis |
Equilibrium |
Quantitative Analysis
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Chem Lab Simulations 1: Titrations and Chem Lab Simulations 2: Ideal Gas Law (Gelder, John) Zemke, Warren T. Computer programs intended to serve as introductions for students before actual experimentation in the laboratory. Zemke, Warren T. J. Chem. Educ. 1987, 64, A57.
Titration / Volumetric Analysis |
Gases |
Enrichment / Review Materials
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Computer programming in general chemistry Breneman, G. L.; Parker, O. J. 84. Programming computers to solve problems as an integral part of the general chemistry course. Breneman, G. L.; Parker, O. J. J. Chem. Educ. 1987, 64, 584.
Titration / Volumetric Analysis |
Equilibrium
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Hands-on versus computer simulation methods in chemistry Bourque, Donald R.; Carlson, Gaylen R. Procedure, results, conclusions, and implications of a study that compares the effectiveness of a hands-on approach versus computer simulations in the same chemistry topics. Bourque, Donald R.; Carlson, Gaylen R. J. Chem. Educ. 1987, 64, 232.
Acids / Bases |
Titration / Volumetric Analysis |
Stoichiometry
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A different view of using titrimetric data Castillo S., Carlos Using titration data to obtain the dissociation constant of the acid under consideration. Castillo S., Carlos J. Chem. Educ. 1985, 62, 443.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
Aqueous Solution Chemistry
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Acid rain analysis by standard addition titration Ophardt, Charles E. A simple standard addition titration method for determining the acidity of a rain or snow sample. Ophardt, Charles E. J. Chem. Educ. 1985, 62, 257.
Titration / Volumetric Analysis |
Atmospheric Chemistry |
Acids / Bases |
Qualitative Analysis
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Colorblindness and titrations with visual indicators Diehl, Harvey; Johnson, Dennis C.; Markuszewski, Richard; Moore, Robert M. Discussion and investigation of the problem of colorblindness in determining the endpoints of titrations. Diehl, Harvey; Johnson, Dennis C.; Markuszewski, Richard; Moore, Robert M. J. Chem. Educ. 1985, 62, 255.
Minorities in Chemistry |
Titration / Volumetric Analysis |
Quantitative Analysis |
Acids / Bases
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Titrator, Review II (Dice, David D.) Drake, Gordon P. Program that allows the user to simulate the titration of either a strong or weak acid with a strong base. Drake, Gordon P. J. Chem. Educ. 1984, 61, A273.
Acids / Bases |
Titration / Volumetric Analysis
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Titrator, Review I (Dice, David D.) Hill, Sister Mary Mechtilde, RSM Program that allows the user to simulate the titration of either a strong or weak acid with a strong base. Hill, Sister Mary Mechtilde, RSM J. Chem. Educ. 1984, 61, A273.
Acids / Bases |
Titration / Volumetric Analysis
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The preparation of acid-base titration curves McClendon, Michael A simple technique for generating mechanically plotted titration curves using an electron pH meter and a low-voltage chart recorder. McClendon, Michael J. Chem. Educ. 1984, 61, 1022.
Acids / Bases |
Titration / Volumetric Analysis |
Laboratory Equipment / Apparatus |
Quantitative Analysis
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Determination of ammonia in household cleaners: an instrumental analysis experiment Graham, Richard C.; DePew, Steven This popular experiment describes a procedure that is easily modified to determine quantitatively such analytes as ammonia in solution. Graham, Richard C.; DePew, Steven J. Chem. Educ. 1983, 60, 765.
Quantitative Analysis |
Titration / Volumetric Analysis |
Acids / Bases |
pH |
Consumer Chemistry |
Stoichiometry |
Solutions / Solvents
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A tutorial program for pH calculation Palmer, Glenn E. 37. Bits and pieces, 14. These authors describe a calculator program that can be used to help students drill pH calculations. Palmer, Glenn E. J. Chem. Educ. 1983, 60, 101.
pH |
Titration / Volumetric Analysis
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Another approach to titration curves: Which is the dependent variable? Willis, Christropher J. In this paper, an approach to titration curves is described which eliminates common stumbling blocks in achieving student understanding. Willis, Christropher J. J. Chem. Educ. 1981, 58, 659.
Quantitative Analysis |
Titration / Volumetric Analysis
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Titration curve for a programmable pocket calculator Williams, Howard P. A titration curve program written for a TI-58 or TI-59 programmable pocket calculator. Williams, Howard P. J. Chem. Educ. 1979, 56, 237.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Quantitative Analysis
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Comparison of strong acid and weak acid titration curves Schultz, C. W.; Spannuth, S. L. Allows comparison of mechanically reproduced titration curves of strong acid and one or more weak acids versus strong base on the same piece of paper. Schultz, C. W.; Spannuth, S. L. J. Chem. Educ. 1979, 56, 194.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
pH
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Determination of pKa using the half-volume method: A laboratory experiment Stephens, S. Jane; Jonich, Michael J. The equivalence point of an unknown acid is found; the value of pKa is read directly from the titration curve using the "half-volume" method. Stephens, S. Jane; Jonich, Michael J. J. Chem. Educ. 1977, 54, 711.
pH |
Titration / Volumetric Analysis |
Quantitative Analysis
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Visual aid for acid-base concepts Olson, Virgil K.; Osteryoung, Janet; Christie, Joseph H.; Turner, John A. Three plots that the authors have found particularly useful in concisely illustrating a number of acid-base concepts relating to buffer capacity and acid-base titrations. Olson, Virgil K.; Osteryoung, Janet; Christie, Joseph H.; Turner, John A. J. Chem. Educ. 1977, 54, 220.
Acids / Bases |
Titration / Volumetric Analysis
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Computer simulated titration curves Wilson, C. E. Three computer programs for generating theoretical titration curves. Wilson, C. E. J. Chem. Educ. 1975, 52, 344.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis
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A computer generated titration exercise Bishop, Craig V.; Wartell, M. A. A computer program which is designed for use as an exercise in teaching titration and use of titration curves. Bishop, Craig V.; Wartell, M. A. J. Chem. Educ. 1975, 52, 187.
Titration / Volumetric Analysis |
Quantitative Analysis
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Theoretical shape of acid-base titration curves without using logarithms Vennos, Mary S. This presentation of the acid-base titration curve relates to interests students in paramedical careers might have. Vennos, Mary S. J. Chem. Educ. 1974, 51, 631.
Acids / Bases |
Titration / Volumetric Analysis |
Nonmajor Courses
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A graphical-analytical iterative procedure for equivalence point determinations Sellers, Neal G.; Caruso, Joseph A. An iterative approach has been developed that combines graphical measurements with analytical calculations to give an exact potentiometric endpoint irrespective of the stoichiometry of the reaction and magnitude of the associated equilibrium constants. Sellers, Neal G.; Caruso, Joseph A. J. Chem. Educ. 1973, 50, 547.
Acids / Bases |
Titration / Volumetric Analysis
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Programmable calculators. Simulated experiments Runquist, O.; Olsen, Rodney; Snadden, Bruce Describes how titration and reaction rate experiments can be simulated on a programmable calculator. Runquist, O.; Olsen, Rodney; Snadden, Bruce J. Chem. Educ. 1972, 49, 265.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
Rate Law |
Kinetics |
pH
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Determination of successive ionization constants: A computer assisted laboratory experiment Jensen, R. E.; Garvey, R. G.; Paulson, B. A. The computer programs described here plot students' titration data, locate equivalence points of the titration, calculate the apparent equivalent mass of the acid, and determine the successive ionization constants of the acid. Jensen, R. E.; Garvey, R. G.; Paulson, B. A. J. Chem. Educ. 1970, 47, 147.
Acids / Bases |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis
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Corrections for simple equations for titration curves of monoprotic acids Cortelyou, W. P. Presents corrections for simple equations for titration curves of monoprotic acids and their derivations. Cortelyou, W. P. J. Chem. Educ. 1968, 45, 677.
Acids / Bases |
Titration / Volumetric Analysis |
pH |
Aqueous Solution Chemistry
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Is a weak acid monoprotic? A new look at titration curves Sturrock, Peter E. It is suggested that experimental values of ?pH may be employed as a simple, yet sensitive, criterion to determine whether an unknown acid is monoprotic. Sturrock, Peter E. J. Chem. Educ. 1968, 45, 258.
Acids / Bases |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis |
pH
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Syntheses and titrations of unknown acids: A general chemistry laboratory experiment Kauffman, George B.; Houghten, Richard A., Jr. Students prepare a solid unknown acid from an unknown starting material and then determine its equivalent weight by titration with a standard base. Kauffman, George B.; Houghten, Richard A., Jr. J. Chem. Educ. 1967, 44, 408.
Acids / Bases |
Synthesis |
Titration / Volumetric Analysis
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Acid-base titration and distribution curves Waser, Jurg Presents an alternative method for the calculation of acid-base titration curves. Waser, Jurg J. Chem. Educ. 1967, 44, 274.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
Aqueous Solution Chemistry
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Theoretical error in acid-base titrations Butcher, John; Quintus, Fernanado The purpose of this report is to describe simple derivations of equations for titration error calculations for a number of acid-base titrations, and to show error curves for some typical cases. Butcher, John; Quintus, Fernanado J. Chem. Educ. 1966, 43, 546.
Titration / Volumetric Analysis |
Quantitative Analysis |
Acids / Bases
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The non-aqueous titration of the salts of weak acids Latimer, George W., Jr. A method for the HClO4 titration of the salts of carboxylic acid in glacial acetic acid. Latimer, George W., Jr. J. Chem. Educ. 1966, 43, 215.
Titration / Volumetric Analysis |
Quantitative Analysis
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Computer program for the calculation of acid-base titration curves Emery, Allan R. Describes the development of a computer program for the calculation of acid-base titration curves. Emery, Allan R. J. Chem. Educ. 1965, 42, 131.
Titration / Volumetric Analysis |
Acids / Bases |
Aqueous Solution Chemistry |
Chemometrics
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Automatic titrimetry in introductory college chemistry Zajicek, O. T. The experiment described here employs an automatic pH titrator as a tool for the teaching of a detailed treatment of simultaneous equilibria. Zajicek, O. T. J. Chem. Educ. 1964, 41, 554.
Titration / Volumetric Analysis |
pH |
Aqueous Solution Chemistry |
Acids / Bases |
Equilibrium
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Indicators and the basis for their use Gorin, George Describes the method for selecting appropriate indicators and the teaching of this subject. Gorin, George J. Chem. Educ. 1956, 33, 318.
Dyes / Pigments |
Titration / Volumetric Analysis |
Acids / Bases |
Aqueous Solution Chemistry |
Quantitative Analysis |
pH
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