TIGER

Assessment Questions: 40 results
Thermodynamics : ConservGibbsEnergy (6 Variations)
Which of the following best illustrates conservation of Gibbs free energy?
Thermodynamics
Thermodynamics : CalcDeltaG (14 Variations)
Using , calculate the Gibbs free energy change for the following reaction which produces the metal zinc from its ore zinc(II) oxide.
2 ZnO(s) 2 Zn(s) + O2(g)


Thermodynamics |
Chemometrics
Thermodynamics : ATPFromGlucose (8 Variations)
When glucose is oxidized in the human body it releases a lot of Gibbs free energy. Rather than waste this free energy, the body stores much of it in the form of ATP. The following reaction shows this process of storing some of the energy from glucose in ATP. This is an example of coupled reactions in a biological system.

The label on a can of Coke says that it contains 39 g of sugar. Assume that all of the sugar is glucose (even though it isn't), and calculate how many moles of ATP can be produced theoretically by the oxidation of 39.0 g of glucose.

Thermodynamics |
Reactions |
Chemometrics
Thermodynamics : InterpretKandDeltaG (16 Variations)
The thermodynamic equilibrium constant for the following reaction is 0.15 at 1227°C.
2 SO2(g) + O2(g) 2 SO3(g)
Check the box for each true statement.

Thermodynamics
Thermodynamics : GibbsFromHSandT (5 Variations)
On the space shuttle, the carbon dioxide produced by the astronauts is handled by an environmental control system that utilizes the following reaction.

H° = -138.4 kJ and S° = -139 J/K Calculate G° at 25°C for this reaction.

Thermodynamics |
Chemometrics
Thermodynamics : CalcMinSpontTemp (9 Variations)
Calculate the minimum temperature above which the following reaction will be product-favored (spontaneous).



Thermodynamics |
Chemometrics
Thermodynamics : DetermineRxnFavored (8 Variations)
When industrial plants burn coal, sulfur dioxide is produced. Sulfur dioxide is a primary pollutant that contributes to both industrial smog and acid rain. Is this process of producing sulfur dioxide product-favored?

Using


Thermodynamics |
Chemometrics
Thermodynamics : GeneralThermo (6 Variations)
Which of the following statements is an inaccurate statement about thermodynamics?
Thermodynamics
Thermodynamics : ThermoKinStability (4 Variations)
Compare white and grey tin, both of which exist as solid phases of tin near room temperature.

Phase Hof (kJ/mol) So (J/(K*mol))
white tin 0 51.5
grey tin -2.1 44.8

Which type of stability does each exhibit at 40 oC?

white tin {1:MULTICHOICE:kinetically stable#No, that's incorrect.~=thermodynamically stable#Correct!}

grey tin {1:MULTICHOICE:=kinetically stable#Correct!~thermodynamically stable#No, that's incorrect.}


Thermodynamics
Thermodynamics : PredictEntropyChange (10 Variations)
For each of the following processes, indicate whether you expect the entropy change of the system to be positive or negative.
Thermodynamics
Thermodynamics : EntropyPhaseChange (13 Variations)
Aluminum can be evaporated in a vacuum to form highly reflective coatings. Aluminum boils at 2792K and has a heat of vaporization of 70.0 kcal/mol. Calculate the entropy change for the vaporization of one mole of aluminum.
Thermodynamics |
Chemometrics |
Phases / Phase Transitions / Diagrams
Thermodynamics : ProbabilityEnergyDist (23 Variations)
Consider a system that has two indistinguishable molecules that can occupy three different energy levels (having energies of 1kJ, 2kJ and 3kJ, respectively). What is the probability that the molecules will have a total energy of 2 kJ?
Thermodynamics
Thermodynamics : CompareEntropyQual (16 Variations)
Indicate which substance in each of the following pairs of substances you expect to have higher entropy. Assume that you have a mole of each substance and all substances are at the same temperature.
Thermodynamics
Thermodynamics : CalcDeltaS (9 Variations)
Using , calculate the entropy change for the reaction.

Thermodynamics |
Chemometrics
Electrochemistry : CalcDeltaGfromE (20 Variations)
The following electrochemical data may be helpful in answering the question below.

Calculate the dGo for the oxidation of 2 mole of silver in the following balanced reaction.

2Ag(s) + CaI2(aq) a Ca(s) + 2AgI(s)


Electrochemistry |
Oxidation / Reduction
Matter_and_Measurement : CompareFCTemps (10 Variations)
Which is the higher temperature, 350oC or 350oF?
Chemometrics |
Nomenclature / Units / Symbols
Equilibrium : SolubilityPressTemp (16 Variations)
How does increasing the temperature change the solubility of nitrogen in water?
Equilibrium
Thermochemistry : HeatTransfers (10 Variations)
A red-hot piece of lead is dropped into water. Which of the following statements are true? (Assume that there are no energy transfers between anything except the lead and the water.)
Calorimetry / Thermochemistry
Intermolecular_Forces__Liquids_and_Solids : PhaseEnergyChanges (6 Variations)
When a liquid is transformed into its vapor at constant temperature,
Phases / Phase Transitions / Diagrams |
Calorimetry / Thermochemistry
Gases : GasGramMixPressure (5 Variations)
4.80 g of CH4 is mixed with 17.6 g of CO2 in a 9.00 L flask at a temperature of 67.2oC. What is the total pressure of the flask? (Assume there is no reaction.)
Gases |
Chemometrics
Gases : VolGasReactInTorch (10 Variations)
Oxyacetylene torches used in high-temperature welding use a combination of oxygen and acetylene. The combustion of acetylene (C2H2) occurs in these torches. What volume of oxygen is needed to react with 250 mL of acetylene?
Gases |
Stoichiometry
Thermochemistry : FlaskTemp (6 Variations)
If 200. J of thermal energy was added to both flasks, which of the following would happen?

Calorimetry / Thermochemistry
Thermochemistry : ThermalEnergy (2 Variations)
The sketch below shows two identical flasks with different volumes of water at the same temperature. Which of the following is true?

Calorimetry / Thermochemistry
Bonding : ImpossibleStructure (10 Variations)
Which of the following formulas represent substances that are likely to be stable at ordinary temperature and pressure? A good way to decide is to ask for which of the formulas is it possible to draw a reasonable Lewis structure (one that obeys the usual rules for drawing Lewis structures)?
Lewis Structures |
Covalent Bonding
Thermochemistry : HeatCapacityLiq (4 Variations)
100 g of water (c=4.184 J/g.oC), 100 g of ethanol (c=2.46 J/g.oC), 100 g of carbon tetrachloride (c=0.861 J/g.oC), and 100 g of ethylene glycol (c=2.42 J/g.oC) at 50oC were each placed into a separate coffee cup calorimeter and the temperature recorded. The temperature of the surroundings was 20oC. After one hour the temperature of which substance would have changed by the largest amount? Assume that the rate of heat transfer from the coffee cup to the surroundings was the same in each case.
Calorimetry / Thermochemistry |
Heat Capacity
Gases : GasRxnVolumes (10 Variations)
A gas phase reaction takes place in a syringe at a constant temperature and pressure. If the initial volume before reaction is 30 mL and the final volume after the reaction is complete is 15 mL, which of the following reactions took place? (Note: You can assume that you start with stoichiometric amounts of the reactants, the reaction goes to completion and that the gases behave ideally.)
Gases |
Chemometrics
Kinetics : CompareEnergyProfile (11 Variations)
Consider the following reactions that take place at the same temperature, begin with the same molar concentrations, and whose energy profiles are presented below:
Kinetics
Equilibrium : CalcRxnQuotient (13 Variations)
In an experiment, 4.44 mol of SO2, 7.93 mol of O2 and 4.03 mol of SO3 are placed in a 2.0L reaction vessel at a certain temperature. Calculate the reaction quotient, Q, for the reaction as written:

What is the calculated reaction quotient, Q? {2:NUMERICAL:=2.1e-1:1e-2#Correct! ~%50%2.1e-1:5e-2#Close but not quite right}

If Kc for this reaction at the temperature of the experiment is 3.7 x 103, will the reaction move toward the left or toward the right? {1:MULTICHOICE:left#Sorry, that's wrong.~=right#Correct!}


Equilibrium |
Chemometrics
Gases : GasLaws (2 Variations)
Note: This is a calculation type question. If you exit the quiz without submitting it and you do not save an answer before exiting the quiz, the values in the question may change when you enter the quiz again.

You purchase a propane tank that can hold gas safely up to a pressure of {x} atm. When the tank contains 100. grams of propane at {y}°C, the gas exerts a pressure of {z}atm. What is the highest temperature to which the propane can be heated safely? (Report your answer in Kelvins.)

Gases |
Chemometrics
Kinetics : ArrheniusTemp (3 Variations)
The activation energy for the isomerization of cyclopropane to propene is 274 kJ/mol. By what factor does the rate of reaction increase as the temperature rises from 500oC to 550oC assuming all else remains constant? (R = 8.314 J/mol k)

Hint: This is asking for the ratio of rates which is proportional to the ratio of the rate constants, all else being equal.


Kinetics |
Chemometrics
Thermochemistry : BombCalorimeter (4 Variations)
Stearic acid (CH3(CH2)16CO2H) is a fatty acid, the part of fat that stores most of the energy. 1.00 g of stearic acid was burned in a bomb calorimeter. The bomb had a heat capacity of 652 J/oC and a 500. g water reservoir. If the temperature rose from 25.0 to 39.3 oC, how much heat was released when the stearic acid was burned?
Calorimetry / Thermochemistry |
Chemometrics
Thermochemistry : CoffeeCupCalorimeter (2 Variations)
A block of copper is heated to {x} °C and then is dropped into a coffee cup calorimeter containing {y} g of water at 25.0 °C. The final temperature of the system is 45.1 °C. What is the mass of the copper block to the nearest gram? (Assume all heat is transferred to the water). Write your answer in the box, and do NOT include units.

Specific heat capacity of copper = 0.383 J/(g*°C)

Specific heat capacity of water = 4.18 J/(g*°C)

Calorimetry / Thermochemistry |
Chemometrics
Gases : GasRxnStoich (10 Variations)
One of the reactions in the process of obtaining very pure silicon for the microelectronics industry is shown below. If 24 g of SiO2 is reacted with an excess of carbon, what volume of gaseous carbon monoxide will be produced at a temperature of 17oC and a pressure of 735 mm Hg?

SiO2(s) + 2C(s)Si(S) + 2CO(g)


Gases |
Chemometrics
Equilibrium : LeChatPrinciple (18 Variations)
Consider the following equilibrium, established in a 2 L flask at 30oC.

CO(g) + H2O(g) CO2(g) + H2(g) H0= -41.2 kJ

What will happen to the concentration of CO2 if the temperature is increased?


Equilibrium
Equilibrium : RxnDirectAndTemp (16 Variations)
2 SO2(g) + O2(g) 2 SO3(g)
The reaction above has an equilibrium constant of 0.25 at 830oC, and Horxn = -197.78 kJ/mol under standard conditions. Under which conditions will this reaction produce the most sulfur trioxide?

Equilibrium
Equilibrium : CalcKc (4 Variations)
A container initially has {y} M ammonia at a certain temperature. When the system reaches equilibrium the concentration of ammonia is {x} M. Calculate Kc for the following reaction as written.

Note:
      Answers must be written using scientific notation with "e"
      DO NOT use spaces
      DO NOT write in the units.
      Be sure to use three significant figures.
          eg:       2.44e-5

Equilibrium |
Chemometrics
Equilibrium : ConvertKcKp (6 Variations)
Nitrosyl bromide is formed from nitrogen oxide and bromine:

Kp for this reaction is {x} at {y}°C. Calculate Kc at this temperature. (R = 0.0821 L atm/mol K)

Note:
DO NOT use scientific notation
Use integers (no decimal places) even is this is not the correct number of significant figures.
DO NOT write in the units.
eg: 18


Equilibrium |
Chemometrics
Equilibrium : MoreMolesAtEquil (19 Variations)
The following reaction has an equilibrium constant of 0.050 at a given temperature.

N2(g)+ O2(g) 2NO(g)

If you have 0.75 moles of N2(g) and 0.75 moles of O2(g) in a 2.0L container initially, how many moles of N2 will be present when the system reaches equilibrium?


Equilibrium |
Chemometrics
Thermochemistry : HeatCapacitySolLiq (4 Variations)
The Table below lists the specific heat capacities of several metals and liquids.

Substance Specific Heat Capacity
J/(g.oC)
Substance Specific Heat Capacity
J/(g.oC)
Al 0.902 H2O 4.18
Fe 0.451 C2H5OH 2.46
Cu 0.383 CCl4 0.861
Au 0.128 CCl2F2 0.598

In an experiment, 50 g of a metal was heated to 100oC and placed in 200 g of a liquid at 25oC. Which of the following combinations of metal and liquid will produce the largest temperature increase in the liquid? (Assume that there is no transfer of energy to the surroundings.)


Calorimetry / Thermochemistry |
Heat Capacity
Thermochemistry : MassFromCalorimetry (2 Variations)
The table below lists the specific heat capacities of several metals and liquids.

SubstanceSpecific Heat Capacity
J/(g.oC)
SubstanceSpecific Heat Capacity
J/(g.oC)
Al0.902H2O4.18
Fe0.451C2H5 OH2.46
Cu0.383CCl40.861
Au0.128CCl2F2 0.598

In an experiment a block of aluminum was heated to 100oC and placed in 200 g of water at 25oC. If the final temperature of the system is 43oC, and no heat transfer to the surroundings occurred, what is the mass of the aluminum block?


Calorimetry / Thermochemistry |
Chemometrics