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Entropy These processes are shown in reverse. The situations shown are so highly improbable that we would not expect to observe them in nature.
Thermodynamics
Endothermic Reaction Solid barium hydroxide octahydrate (Ba(OH)2*8H2O) and ammonium thiocyanate (NH4SCN) are mixed in a beaker, which is then placed on a few drops of water on a small board. The reaction that occurs is highly endothermic.
Thermodynamics : CompareEntropyQual (16 Variations) Indicate which substance in each of the following pairs of substances you expect to have higher entropy. Assume that you have a mole of each substance and all substances are at the same temperature.
"Mysteries" of the First and Second Laws of ThermodynamicsRubin Battino Over the years the subject of thermodynamics has taken on an aura of difficulty, subtlety, and mystery. This article discusses common misconceptions and how to introduce the topic to students. Battino, Rubin. J. Chem. Educ.2007, 84, 753.
Calorimetry / Thermochemistry |
Thermodynamics
E = mc2 for the Chemist: When Is Mass Conserved?Richard S. Treptow Einstein's famous equation is frequently misunderstood in textbooks and popular science literature. Its correct interpretation is that mass and energy are different measures of a single quantity known as massenergy, which is conserved in all processes. Treptow, Richard S. J. Chem. Educ.2005, 82, 1636.
Atomic Properties / Structure |
Nuclear / Radiochemistry |
Theoretical Chemistry |
Thermodynamics
Entropy and Constraint of MotionFrank L. Lambert William Jensen's presentation of entropy increase as solely due to kinetic energy dispersion is stimulating. Lambert, Frank L. J. Chem. Educ.2004, 81, 640.
Standard Enthalpies of FormationEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Thermodynamics
Disorder (GCMP)David M. Whisnant Disorder: this is a resource in the collection "General Chemistry Multimedia Problems". A spontaneous change is one that has a natural tendency to occur without needing to be driven by an external influence. This problem will explore the influence of entropy, a measure of disorder, on the spontaneity of a few processes. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Thermodynamics
Two Solids (GCMP)David M. Whisnant Two Solids: this is a resource in the collection "General Chemistry Multimedia Problems". When two solids barium hydroxide octahydrate, Ba(OH)2. 8H2O and ammonium thiocyanate, NH4SCN are mixed, they react. We will explore the thermodynamics of the reaction. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
