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Sulfuric Acid into Water and Ice When sulfuric acid is mixed with water the temperature rises. When sulfuric acid is added to ice, the temperature rises at first, but as the ice melts, the temperature falls.
Calorimetry / Thermochemistry
Endothermic Reaction Solid barium hydroxide octahydrate (Ba(OH)2*8H2O) and ammonium thiocyanate (NH4SCN) are mixed in a beaker, which is then placed on a few drops of water on a small board. The reaction that occurs is highly endothermic.
Thermochemistry : SystemSurrExoEndo (4 Variations)
Sulfuric acid is added to water in a beaker and the resulting solution is much warmer than either the water or acid was initially.
Identify the following items as being part of the system or the surroundings, and indicate whether the process is exothermic or endothermic.
Gas Clathrate Hydrates Experiment for High School Projects and Undergraduate LaboratoriesMelissa P. Prado, Annie Pham, Robert E. Ferazzi, Kimberly Edwards, and Kenneth C. Janda Presents a procedure for preparing and studying propane clathrate hydrate. This experiment introduces students to this unusual solid while stimulating a discussion of the interplay of intermolecular forces, thermodynamics, and solid structure. Prado, Melissa P.; Pham, Annie; Ferazzi, Robert E.; Edwards, Kimberly; Janda, Kenneth C. J. Chem. Educ.2007, 84, 1790.
Alkanes / Cycloalkanes |
Applications of Chemistry |
Calorimetry / Thermochemistry |
Gases |
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Water / Water Chemistry |
Hydrogen Bonding
Mass-Elastic Band Thermodynamics: A Visual Teaching Aid at the Introductory LevelWilliam C. Galley Demonstrations of five spontaneous isothermal processes involving the coupling of a mass and elastic band and arising from combinations of enthalpy and entropy changes are presented and then dissected. Analogies are drawn between these processes and common spontaneous molecular events such as chemical reactions and phase transitions. Galley, William C. J. Chem. Educ.2007, 84, 1147.
Calorimetry / Thermochemistry |
Thermodynamics
Predicting the Stability of Hypervalent MoleculesTracy A. Mitchell, Debbie Finocchio, and Jeremy Kua In this exercise, students use concepts in thermochemistry such as bond energy, ionization potentials, and electron affinities to predict the relative stability of two hypervalent molecules (PF5 and PH5) relative to their respective non-hypervalent counterparts. Mitchell, Tracy A.; Finocchio, Debbie; Kua, Jeremy. J. Chem. Educ.2007, 84, 629.
ChemPaths 104 F Mar 25John W. Moore Today in Chem 104:
* Lecture: Thermochemistry
* Reading:
Kotz: Review Ch. 5, Sec. 1-8
Moore: Review Ch. 6, Sec. 1-10
* Homework #8 due by 11:55 PM F Apr 1
* Quiz in second discussion section next week
Calorimetry / Thermochemistry
Measuring the Enthalpy ChangeEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Calorimetry / Thermochemistry
Bond EnthalpiesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
