7.2 Thermal Energy (Heat) and Mechanical Energy (Work)
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Sulfuric Acid into Water and Ice When sulfuric acid is mixed with water the temperature rises. When sulfuric acid is added to ice, the temperature rises at first, but as the ice melts, the temperature falls.
Calorimetry / Thermochemistry
Endothermic Reaction Solid barium hydroxide octahydrate (Ba(OH)2*8H2O) and ammonium thiocyanate (NH4SCN) are mixed in a beaker, which is then placed on a few drops of water on a small board. The reaction that occurs is highly endothermic.
Thermochemistry : FuelAmpWattHeat (4 Variations)
Gasoline has an enthalpy of combustion of approximately 24000 kJ/gallon. When gasoline burns in an automobile engine, approximately 30% of the energy released is used to produce mechanical work. The remainder is lost as heat transfer to the engine's cooling system and eventually the atmosphere. As a start on estimating how much heat transfer is required, calculate what mass of water could be heated from 25 to 100oC by the combustion of 1.0 gallon of gasoline in an automobile.
Calorimetry / Thermochemistry |
Chemometrics
Thermochemistry : SystemSurrExoEndo (4 Variations)
Sulfuric acid is added to water in a beaker and the resulting solution is much warmer than either the water or acid was initially.
Identify the following items as being part of the system or the surroundings, and indicate whether the process is exothermic or endothermic.
An Inexpensive Solution CalorimeterEmma Kavanagh, Sam Mindel, Giles Robertson, and D. E. Peter Hughes Describes the construction of a simple solution calorimeter, using a miniature bead thermistor as a temperature-sensing element, that has a response time of a few seconds and made it possible to carry out a thermometric reaction in under a minute. Kavanagh, Emma; Mindel, Sam; Robertson, Giles; Hughes, D. E. Peter. J. Chem. Educ.2008, 85, 1129.
Acids / Bases |
Aqueous Solution Chemistry |
Calorimetry / Thermochemistry |
Laboratory Equipment / Apparatus |
Thermal Analysis |
Thermodynamics
The Chemical Adventures of Sherlock Holmes: The Serpentine RemainsKen Shaw This story is a chemical mystery, set in the context of Sherlock Holmes and Dr. Watson, that emphasizes qualitative analysis, descriptive chemistry, and forensics. Shaw, Ken. J. Chem. Educ.2008, 85, 507.
ChemPaths 104 F Mar 25John W. Moore Today in Chem 104:
* Lecture: Thermochemistry
* Reading:
Kotz: Review Ch. 5, Sec. 1-8
Moore: Review Ch. 6, Sec. 1-10
* Homework #8 due by 11:55 PM F Apr 1
* Quiz in second discussion section next week
Calorimetry / Thermochemistry
Measuring the Enthalpy ChangeEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Calorimetry / Thermochemistry
Bond EnthalpiesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.