29.5. How Does the Biosynthesis of Amino Acids Take Place?, 782
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Isolation of Betulin and Rearrangement to AllobetulinBrian Green, Michael D. Bentley, Bong Y. Chung, Nicholas G. Lynch, and Bruce L. Jensen Betulin is obtained by extraction from birch bark and converted to allobetulin. Both compounds display 1H NMR spectra that include axialequatorial coupling characteristic of a C3-alcohol, conformational analysis by the use of dihedral angles and the Karplus equation, coupling patterns caused by diastereotopic protons and long-range interactions, and chemical shift values that are influenced by electronegativity and stereochemistry. Green, Brian; Bentley, Michael D.; Chung, Bong Y.; Lynch, Nicholas G.; Jensen, Bruce L. J. Chem. Educ.2007, 84, 1985.
Biosynthesis |
IR Spectroscopy |
Microscale Lab |
NMR Spectroscopy |
Synthesis |
Natural Products
Nature's Way To Make the LantibioticsHeather A. Relyea and Wilfred A. van der Donk This article focuses on one class of antimicrobial compounds, the lantibiotics, and discusses their biosynthetic pathways as well as their molecular mode of action. In the course of the review, the meaning of the terms regio-, chemo-, and stereoselectivity are discussed. Relyea, Heather A.; van der Donk, Wilfred A. J. Chem. Educ.2006, 83, 1769.
Applications of Chemistry |
Bioorganic Chemistry |
Biotechnology |
Biosynthesis |
Catalysis |
Drugs / Pharmaceuticals |
Proteins / Peptides
Gifts from Mother Earth—The Good, the Bad, and the UglySabine Heinhorst and Gordon C. Cannon Recent articles from the journal Nature that deal with good, bad, and ugly gifts from Mother Earth are described. Heinhorst, Sabine; Cannon, Gordon C. J. Chem. Educ.2006, 83, 196.
The Building Blocks of BiochemistryEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Biosynthesis
ChemPaths 104 W Feb 2John W. Moore Today in Chem 104:
* Lecture: Biochemistry: Proteins
* Reading: Biomolecules Tutorials
o Proteins 1 (including debriefing)
o Proteins 2 (including debriefing)
o Quiz due TODAY, 11:55 PM)
* Homework #3 due by 11:55pm F Feb 4.
Proteins / Peptides |
Amino Acids
Organic Nitrogen CompoundsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
