11.1. How Do We Write Structural Formulas of Alkanes?, 323
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Alkanes and Cycloalkanes The structures and conformations of alkanes and cycloalkanes and the vibrational, rotational, and translational motion of alkanes in the gas phase are demonstrated.
A Set of Hands-On Exercises on Conformational AnalysisSilvina C. Pellegrinet and Ernesto G. Mata This article describes a set of comprehensive exercises on conformational analysis that employs a hands-on approach by the use of molecular modeling kits. In addition, the exercises provide illustrations of other topics such as nomenclature, functional groups, and isomerism, and introduce some notions of chirality. Pellegrinet, Silvina C.; Mata, Ernesto G. J. Chem. Educ.2005, 82, 73.
Alkanes / Cycloalkanes |
Conformational Analysis |
Constitutional Isomers |
Molecular Properties / Structure |
Stereochemistry
Using Hydrocarbon Acidities To Demonstrate Principles of Organic Structure and BondingAndrew P. Dicks This article demonstrates the utility of hydrocarbon acidity as a teaching tool within the undergraduate classroom. Acidities of compounds containing only hydrogen and carbon vary by at least 50 orders of magnitude. Differences in acidities are rationalized by invoking principles of hybridization, resonance, induction, and aromaticity. Dicks, Andrew P. J. Chem. Educ.2003, 80, 1322.
Acids / Bases |
Aromatic Compounds |
Alkanes / Cycloalkanes
Fractional Distillation and GC Analysis of Hydrocarbon MixturesCraig J. Donahue Separating and identifying the components of a three-hydrocarbon mixture through fractional distillation and gas chromatography. Donahue, Craig J. J. Chem. Educ.2002, 79, 721.