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Magnetized Water: Science or Fraud? L. Lahuerta Zamora, G. M. Antón-Fos, P. A. Alemán López, and R. V. Martin Algarra Commercial water magnetizers provide a unique opportunity to help university and secondary students develop appropriate skepticism against extraordinary claims and use testing as the basis for their scientific evaluation. Lahuerta Zamora, L.; Antón-Fos, G. M.; Alemán López, P. A.; Martin Algarra, R. V. J. Chem. Educ. 2008, 85, 1416.
Aqueous Solution Chemistry |
Magnetic Properties |
pH |
Titration / Volumetric Analysis |
Water / Water Chemistry
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Phenolphthalein—Pink Tornado Demonstration Bruce R. Prall This demonstration uses the vortex generated by a spinning magnetic stir bar to demonstrate Le Châtelier's principle as it applies to the phenolphthalein equilibrium in water and provides an excellent opportunity to discuss limiting and excess reagents. Prall, Bruce R. J. Chem. Educ. 2008, 85, 527.
Acids / Bases |
Equilibrium |
Kinetics |
pH
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Chemical Speciation and Calculation of pH of a Sport Drink José L. Guiñón Segura A recently published laboratory procedure allows students to see that the pointer function has a minimum value at the solution pH. However, the resolution of the pointer function requires the plotting the logarithmic concentration diagram, which is time-consuming and tedious. Segura, José L Guiñón. J. Chem. Educ. 2008, 85, 371.
Acids / Bases |
Aqueous Solution Chemistry |
Consumer Chemistry |
Food Science |
Mathematics / Symbolic Mathematics |
pH |
Quantitative Analysis
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Scientific–Chemical Viewpoints Regarding Smoking: A Science Laboratory for All Ron Blonder This article describes a lab that examines the acidity of cigarette smoke as well as solid particles and vapor phase substances found therein, and simulates the effects of smoking on the lungs. The aim of this activity is to expose adolescents to the scientific aspects of smoking and the relevance of chemistry in everyday life. Blonder, Ron. J. Chem. Educ. 2008, 85, 248.
Acids / Bases |
Consumer Chemistry |
Gases |
Laboratory Equipment / Apparatus |
pH |
Applications of Chemistry |
Student-Centered Learning
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The Chemistry of Paper Preservation Henry A. Carter This article examines the applications of chemistry to paper preservation. The acid-catalyzed hydrolysis of cellulose accounts for the deterioration of paper in library books and other written records. To combat this threat to our written heritage, new permanent papers have been developed that are relatively chemically stable and undergo a very slow rate of deterioration. Carter, Henry A. J. Chem. Educ. 2007, 84, 1937.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Free Radicals |
Gas Chromatography |
HPLC |
pH |
Kinetics |
Rate Law
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Imidazole as a pH Probe: An NMR Experiment for the General Chemistry Laboratory William J. Hagan, Jr., Dennis L. Edie, and Linda B. Cooley An experiment is described that employs the 1H-NMR signal of aqueous imidazole to determine the pH of an unknown solution. The procedure involves the preparation of a calibration curve, which is then used for the analysis of the unknown(s). Hagan, William J., Jr.; Edie, Dennis L.; Cooley, Linda B. J. Chem. Educ. 2007, 84, 1188.
Acids / Bases |
Aqueous Solution Chemistry |
Aromatic Compounds |
Calibration |
NMR Spectroscopy |
pH
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Defining and Teaching pH Richard F. Burton At an elementary level, pH and the algebra of equilibria can be simply and correctly taught, without logarithms, in terms of the modern, operationally-defined pH scale that underlies laboratory measurement and relates to activities. Burton, Richard F. J. Chem. Educ. 2007, 84, 1129.
Acids / Bases |
pH |
Aqueous Solution Chemistry
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The Chemistry of Swimming Pool Maintenance Carl Salter and David L. Langhus This paper examines the key ideas behind swimming pool chemistry -- the central importance of pH and its effect on chlorine sanitation and calcium carbonate solubility. The paper also reviews the analytical procedures and common practices used to monitor and control pool chemistry or correct problems. Salter, Carl; Langhus, David L. J. Chem. Educ. 2007, 84, 1124.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Dyes / Pigments |
pH |
Photochemistry |
Precipitation / Solubility |
Water / Water Chemistry
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pHantastic Fluorescence Mark Muyskens Students easily extract a fluorescent substance from shavings of a wood called narra. The fluorescence is dramatically pH dependent and can be turned on and off repeatedly using commonly available acid and base solutions. Muyskens, Mark. J. Chem. Educ. 2006, 83, 768A.
Fluorescence Spectroscopy |
Natural Products |
Nucleophilic Substitution |
pH |
Solutions / Solvents |
UV-Vis Spectroscopy
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Negative pH Does Exist Kieran F. Lim ( ) The misconception that pH lies between 0 and 14 has been perpetuated in popular-science books, textbooks, revision guides, and reference books. Lim, Kieran F. ( ). J. Chem. Educ. 2006, 83, 1465.
Acids / Bases |
Aqueous Solution Chemistry |
pH
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The Fluorescence of Lignum nephriticum: A Flash Back to the Past and a Simple Demonstration of Natural Substance Fluorescence Mark Muyskens This article describes a simple but visually striking demonstration of fluorescence from the aqueous extract of the tropical hardwood Pterocarpus indicus. Muyskens, Mark. J. Chem. Educ. 2006, 83, 765.
Acids / Bases |
Fluorescence Spectroscopy |
Natural Products |
pH |
Solutions / Solvents |
UV-Vis Spectroscopy
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pH Paradoxes: Demonstrating That It Is Not True That pH ≡ -log[H+] Christopher G. McCarty and Ed Vitz Six demonstrations highlighting paradoxes that arise if pH is incorrectly defined as -log[H+] are presented as justification for the recommendation that pH should be correctly defined as pH = -log aH+ in textbooks. McCarty, Christopher G.; Vitz, Ed. J. Chem. Educ. 2006, 83, 752.
Acids / Bases |
Aqueous Solution Chemistry |
Ion Selective Electrodes |
pH |
Quantitative Analysis
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Linking Laboratory Experiences to the Real World: The Extraction of Octylphenoxyacetic Acid from Water Jorge E. Loyo-Rosales, Alba Torrents, Georgina C. Rosales-Rivera, and Clifford P. Rice A known quantity of the sodium salt of octylphenoxyacetic acid is dissolved in water, transformed to the acid (insoluble) form, and extracted using dichloromethane. These changes can be followed visually owing to conspicuous changes in solution turbidity. Loyo-Rosales, Jorge E.; Torrents, Alba; Rosales-Rivera, Georgina C.; Rice, Clifford P. J. Chem. Educ. 2006, 83, 248.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
pH |
Stoichiometry |
Nonmajor Courses |
Water / Water Chemistry
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Determination of Hypochlorite in Bleaching Products with Flower Extracts To Demonstrate the Principles of Flow Injection Analysis Luiz Antônio Ramos, Kátia Roberta Prieto, Éder Tadeu Gomes Cavalheiro, and Carla Cristina Schmitt Cavalheiro Proposes the use of crude flower extracts and a bleaching reaction between hypochlorite and anthocyanins to teach the principles of flow injection procedures. Ramos, Luiz Antônio; Prieto, Kátia Roberta; Cavalheiro, Éder Tadeu Gomes; Cavalheiro, Carla Cristina Schmitt. J. Chem. Educ. 2005, 82, 1815.
Dyes / Pigments |
Natural Products |
pH |
Quantitative Analysis |
UV-Vis Spectroscopy |
Aromatic Compounds
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Using Visible Spectrophotometers and pH Measurements To Study Speciation in a Guided-Inquiry Laboratory William H. Otto, Cynthia K. Larive, Susan L. Mason, Janet B. Robinson, Joseph A. Heppert, and James D. Ellis A collective-effort, guided-inquiry laboratory investigation was developed for the second-semester general chemistry laboratory for the purpose of increasing student conceptual understanding of equilibrium and speciation phenomena. This investigation required students to employ the chemical indicator phenol red in phosphate buffer solution, computer interfaced pH probes, and visible spectrophotometers. Through a combination of potentiometric and visible absorption measurements, the students determined the pH conditions that alter equilibrium concentrations of multiple species (colored and transparent) in solution. Otto, William H.; Larive, Cynthia K.; Mason, Susan L.; Robinson, Janet B.; Heppert, Joseph A.; Ellis, James D. J. Chem. Educ. 2005, 82, 1552.
Acids / Bases |
UV-Vis Spectroscopy |
Equilibrium |
pH |
Water / Water Chemistry |
Dyes / Pigments
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Teaching pH Measurements with a Student-Assembled Combination Quinhydrone Electrode Fritz Scholz, Tim Steinhardt, Heike Kahlert, Jens R. Pörksen, and Jürgen Behnert A combination pH electrode that can be assembled by the student is described. It consists of a glass holder and two sensors in the form of rubber stoppers that contain quinhydrone and graphite. The combination electrode is suitable to teach potentiometric measurements, pH measurements, and the interplay of acidbase and redox equilibria. The electrode meets highest safety standards and overcomes the troubles associated with the use of the conventional quinhydrone electrode. Scholz, Fritz; Steinhardt, Tim; Kahlert, Heike; Pörksen, Jens R.; Behnert, Jürgen. J. Chem. Educ. 2005, 82, 782.
Acids / Bases |
pH |
Laboratory Equipment / Apparatus |
Electrochemistry
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Color Changes in Indicator Solutions Addison Ault Addresses the question "Can an indicator solution change color upon dilution?" Ault, Addison. J. Chem. Educ. 2002, 79, 1070.
Acids / Bases |
pH
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Microscale pH Titrations Using an Automatic Pipet Edward B. Flint, Carrie L. Kortz, and Max A. Taylor A technique for microscale pH titrations using 1-5 mL of analyte and titrant. Flint, Edward B.; Kortz, Carrie L.; Taylor, Max A. J. Chem. Educ. 2002, 79, 705.
Acids / Bases |
Instrumental Methods |
Microscale Lab |
pH |
Titration / Volumetric Analysis
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pH of Sodium Acetate Solutions Guy Schmitz Example of buffering power in deviations of the pH of sodium acetate from calculated values. Schmitz, Guy. J. Chem. Educ. 2002, 79, 29.
Acids / Bases |
Carboxylic Acids |
pH
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Response to Potential-Energy-Only Models (re J. Chem. Educ. 2000, 77, 155-156) Frank Rioux and Roger L. DeKock Example of buffering power in deviations of the pH of sodium acetate from calculated values. Rioux, Frank; DeKock, Roger L. J. Chem. Educ. 2002, 79, 29.
Acids / Bases |
Carboxylic Acids |
pH |
Atomic Properties / Structure |
Quantum Chemistry |
Theoretical Chemistry
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A Comparative Study of Microscale and Standard Burets Mono M. Singh, Cynthia B. McGowan, Zvi Szafran, and R. M. Pike This paper describes a comparative study of the performance of microscale titrations using 2-mL microscale burets with those using Beral pipets and normal 50- and 10-mL burets. The usefulness of a microburet in general and analytical chemistry is demonstrated by presenting results from acid-base, oxidation-reduction, precipitation, complexometric, and pH titrations. Singh, Mono M.; McGowan, Cynthia B.; Szafran, Zvi; Pike, Ronald M. J. Chem. Educ. 2000, 77, 625.
Acids / Bases |
Aqueous Solution Chemistry |
Laboratory Equipment / Apparatus |
Microscale Lab |
Quantitative Analysis |
Oxidation / Reduction |
Titration / Volumetric Analysis |
pH |
Precipitation / Solubility
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Environmental Chemistry Using Ultrasound Belinda K. Wilmer, Edward Poziomek, and Grazyna E. Orzechowska In this demonstration, we describe a simple method for presenting the usefulness of sonication in environmental chemistry. When an aqueous solution of carbon tetrachloride is sonicated, it degrades to produce HCl and HOCl. These products cause a reduction of pH, which can be observed visually with a pH indicator. Wilmer, Belinda K.; Poziomek, Edward; Orzechowska, Grazyna E. J. Chem. Educ. 1999, 76, 1657.
Acids / Bases |
Aqueous Solution Chemistry |
pH
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Using Chemistry and Color To Analyze Household Products: A 10-12 Hour Laboratory Project at the General Chemistry Level Wayne B. Bosma A sequence of experiments using a UV-Vis spectrometer to identify food colorings and to measure the pH of soft drinks allowing qualitative and quantitative measurements to be made. Bosma, Wayne B. J. Chem. Educ. 1998, 75, 214.
Consumer Chemistry |
Spectroscopy |
UV-Vis Spectroscopy |
Dyes / Pigments |
pH |
Qualitative Analysis |
Quantitative Analysis
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From Christmas Ornament to Glass Electrode Rogério T. da Rocha, Ivano G. R. Gutz, and Claudimir L. do Lago Instructions and use of a homemade glass electrode for pH measurements/titrations. Da Rocha, Rogerio T.; Gutz, Ivano G. R.; do Lago, Claudimir L. J. Chem. Educ. 1995, 72, 1135.
Laboratory Equipment / Apparatus |
Electrochemistry |
Titration / Volumetric Analysis |
Ion Selective Electrodes |
Aqueous Solution Chemistry |
Acids / Bases |
Laboratory Management |
pH
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Preparing "Chameleon Balls" from Natural Plants: Simple Handmade pH Indicator and Teaching Material for Chemical Equilibrium Naoki Kanda, Takayuki Asano, Toshiyuki Itoh, and Makoto Onoda Description of preparation and use of polysaccharide beads containing anthocyanins to teach students about chemical equilibrium under different pH conditions. Kanda, Naoki; Asano, Takayuki; Itoh, Toshiyuki; Onoda, Makota. J. Chem. Educ. 1995, 72, 1131.
Acids / Bases |
Plant Chemistry |
Equilibrium |
Dyes / Pigments |
pH
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From Titration Data to Buffer Capacities: A Computer Experiment for the Chemistry Lab or Lecture Roy W. Clark, Gary D. White, Judith M. Bonicamp, and Exum D. Watts Provides titration curve data that students can plot and analyze using spreadsheets to develop student understanding of pH, derivatives, buffer capacity, and the behavior of dilute buffers; includes sample graphs and analysis. Clark, Roy W.; White, Gary D.; Bonicamp, Judith M.; Watts, Exum D. J. Chem. Educ. 1995, 72, 746.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Chemometrics
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A Digital pH-mV Meter for Overhead Projection DuPre, Donald B.; Just, Warren E. A commercially available and relatively inexpensive pH-mV meter may be readily modified for display on an overhead projector. DuPre, Donald B.; Just, Warren E. J. Chem. Educ. 1994, 71, 1081.
pH |
Laboratory Equipment / Apparatus
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Teaching the Truth about pH Hawkes, Stephen J. -log[H+] is only an approximation to pH; how to teach pH to avoid misleading students. Hawkes, Stephen J. J. Chem. Educ. 1994, 71, 747.
pH |
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium
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Fruit Anthocyanins: Colorful Sensors of Molecular Milieu Curtright, Robert D.; Rynearson, James A .; Markwell, John Provides background and references as a starting point for the further exploration of anthocyanins. Curtright, Robert D.; Rynearson, James A .; Markwell, John J. Chem. Educ. 1994, 71, 682.
Dyes / Pigments |
Acids / Bases |
Equilibrium |
pH
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Student's Models of Matter in the Context of Acid-Base Chemistry Nakhleh, Mary B. Secondary students' understandings of acids, bases, and pH which emerged in semi-structured interviews conducted as part of a larger study of the effects of three levels of instrumentation on students' understandings of acids, bases, and pH. Nakhleh, Mary B. J. Chem. Educ. 1994, 71, 495.
Acids / Bases |
pH
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Pictorial Analogies XI: Concentrations and Acidity of Solutions Fortman, John J. Visual analogies of the concentration of a solution, strength of a solution, super saturated solution, conjugate acid-base pairs, and inverse relationship between pH and [H+] and pOH and [OH-]. Fortman, John J. J. Chem. Educ. 1994, 71, 430.
Solutions / Solvents |
Aqueous Solution Chemistry |
Acids / Bases |
pH
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LIMSport (V): pH Data Acquisition: An Inexpensive Probe and Calibration Software Vitz, Ed; Betts, Thomas A. 161. Construction and use of a "software pH meter". Vitz, Ed; Betts, Thomas A. J. Chem. Educ. 1994, 71, 412.
pH |
Instrumental Methods |
Laboratory Computing / Interfacing
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A recipe for the preparation of a pH 7.00 calibration buffer Jackman, Donald C. Simple recipe for preparation of a pH 7.00 calibration buffer based on the NIST standard. Jackman, Donald C. J. Chem. Educ. 1993, 70, 853.
Acids / Bases |
Laboratory Management |
pH
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The determination of "apparent" pKa's: An experiment for liberal arts or science students Cawley, John J. An experiment with two different "conclusions" to be reached: one for liberal arts students, one for science students. Cawley, John J. J. Chem. Educ. 1993, 70, 596.
Acids / Bases |
Nonmajor Courses |
pH
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A study of the pH of perspiration from male and female subjects exercising in the gymnasium: A practical challenge for students in the nonscience major class Doran, Daniel; Tierney, John; Varano, Mary; Ware, Susan An engaging activity is developed out of an authentic inquiry posed by students. This article presents the debate behind the title question, a procedure, sample data, results, and discussion. Doran, Daniel; Tierney, John; Varano, Mary; Ware, Susan J. Chem. Educ. 1993, 70, 412.
Acids / Bases |
Applications of Chemistry |
Nonmajor Courses |
pH
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An inexpensive parallel interface to a digital pH meter McMahon, John J.; Braca, Paul R. The authors have designed an experiment in which the students build their own parallel interface "card" from inexpensive components. McMahon, John J.; Braca, Paul R. J. Chem. Educ. 1992, 69, A156.
Laboratory Equipment / Apparatus |
pH
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A 39-drop pH scale Silberman, Robert G. The author discusses a system which can be used to prepare a solution of any pH 2-12. Silberman, Robert G. J. Chem. Educ. 1992, 69, A42.
pH |
Microscale Lab |
Laboratory Management
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The acid-base package Ramette, Richard W.; Holmes, Jon L. Software that will calculate theoretical titration curve data and the pH for any mixture of acids and/or bases. Ramette, Richard W.; Holmes, Jon L. J. Chem. Educ. 1992, 69, 1010.
Acids / Bases |
pH |
Titration / Volumetric Analysis
|
Red, white, blue, and yellow chemistry Dewar, Phyllis D. Producing a colored U.S. flag using Congo red. Dewar, Phyllis D. J. Chem. Educ. 1992, 69, 572.
Acids / Bases |
pH
|
A low-cost pH meter for the classroom. Harris, David L.; Harris, Daniel C. Design of an inexpensive yet precise pH meter for classroom use. Harris, David L.; Harris, Daniel C. J. Chem. Educ. 1992, 69, 563.
Laboratory Equipment / Apparatus |
pH |
Acids / Bases
|
The pH range of the Mohr titration for chloride ion can be usefully extended to 4-10.5 Finlayson, A. C. The pH ranges found in textbooks for this titration are misleading because of inadequate explanations for their basis. Finlayson, A. C. J. Chem. Educ. 1992, 69, 559.
pH |
Titration / Volumetric Analysis |
Quantitative Analysis
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An AC-adapter for battery operated pH meters Mercer, Gary D. Directions for creating an AC adapter for pH meters that are battery operated. Mercer, Gary D. J. Chem. Educ. 1992, 69, 402.
pH |
Laboratory Equipment / Apparatus |
Laboratory Management
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An MS-DOS microcomputer controlled titration system Stangeland, Leiv Jonn; Anjo, Dennis M. 136. In this experiment the computer is employed to control the addition rate of titrant based on the change in pH of the analyte system. Stangeland, Leiv Jonn; Anjo, Dennis M. J. Chem. Educ. 1992, 69, 296.
Titration / Volumetric Analysis |
pH |
Laboratory Computing / Interfacing
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Algorithm for plotting titration curves (author response). Rodrigues de Moura, Daniel. Our model, contrary to Jackman's statement, can be applied to redox systems that are pH-dependant. Rodrigues de Moura, Daniel. J. Chem. Educ. 1992, 69, 257.
pH |
Oxidation / Reduction |
Titration / Volumetric Analysis
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Algorithm for plotting titration curves. Jackman, Donald C. de Moura's algorithm for plotting redox titration curves seems to be good for systems that are not dependent on pH or product concentration, but is not applicable to those situations that is student is more likely to encounter. Jackman, Donald C. J. Chem. Educ. 1992, 69, 257.
Oxidation / Reduction |
Titration / Volumetric Analysis |
pH
|
Demonstrations with red cabbage indicator Fortman, John J.; Stubbs, Katherine M. This paper extends the use of the red cabbage extract into demonstrations that illustrate the acidic or basic nature of solutions of gases and gives suggestions for modifications to project the beautiful range of colors and shades for better viewing in large lecture halls. Fortman, John J.; Stubbs, Katherine M. J. Chem. Educ. 1992, 69, 66.
Acids / Bases |
pH |
Gases
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Chemical equilibrium: VIII. Precipitates Gordus, Adon A. The final article in a series (see previous months this year): This article focuses on ionic precipitates in water and how buffered solutions allow easier calculation of solubilities. Gordus, Adon A. J. Chem. Educ. 1991, 68, 927.
Acids / Bases |
Equilibrium |
pH |
Precipitation / Solubility |
Aqueous Solution Chemistry |
Water / Water Chemistry
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Advanced titration plots using spreadsheet scripting Currie, James O., Jr.; Whiteley, Richard V., Jr. 131. A spreadsheet aids in student understanding of acid/base titration calculations. Currie, James O., Jr.; Whiteley, Richard V., Jr. J. Chem. Educ. 1991, 68, 923.
Acids / Bases |
Titration / Volumetric Analysis |
pH |
Laboratory Computing / Interfacing |
Equilibrium
|
Demonstration properties of sulfur dioxide Brouwer, H. Demonstrations of properties of sulfur dioxide are timely, given current debates between Canada and the United States regarding acid rain. Brouwer, H. J. Chem. Educ. 1991, 68, 417.
Acids / Bases |
Green Chemistry |
pH
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Using the Apple game port to measure pH Kelly, Edward A circuit that measures electrical potential using the pushbutton and annunciator connections at the Apple game port. Kelly, Edward J. Chem. Educ. 1990, 67, A254.
Laboratory Computing / Interfacing |
pH
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A pH-monitoring and control system for teaching laboratories Ibez, Jorge G.; Tavera, Luis; Rodriguez, Alberto; Gomez del Campo, Enrique The authors describe a simple microcomputer apparatus that can be used to monitor the pH change that occurs during the course of a chemical reaction, to maintain a constant pH in a chemical reactor, and to perform an automated titration. Ibez, Jorge G.; Tavera, Luis; Rodriguez, Alberto; Gomez del Campo, Enrique J. Chem. Educ. 1990, 67, A74.
pH |
Titration / Volumetric Analysis |
Laboratory Computing / Interfacing
|
A short program for the automatic calculation of pH in solutions having many acids or bases Campanario, Juan Miguel; Ballesteros, Reyes 121. Bits and pieces, 45. A computer program for calculating the pH of mixtures having many acids or bases. Campanario, Juan Miguel; Ballesteros, Reyes J. Chem. Educ. 1990, 67, 1036.
Acids / Bases |
pH
|
A modified graphical method for acid-base equilibria Nakagawa, Kuniaki A method based on logarithmic diagrams for finding the pH values for various systems in acid-base equilibria. Nakagawa, Kuniaki J. Chem. Educ. 1990, 67, 673.
Acids / Bases |
Equilibrium |
pH
|
Development of a new design for multipurpose meter: "Calo-pH Meter" Paris, Michel R.; Aymes, Daniel J.; Poupon, Rene; Gavasso, Roland The purpose of this article is to describe the design of a common box that can be turned into a simple voltmeter, a pH meter, or a calorimeter. Paris, Michel R.; Aymes, Daniel J.; Poupon, Rene; Gavasso, Roland J. Chem. Educ. 1990, 67, 507.
Laboratory Equipment / Apparatus |
Electrochemistry |
pH |
Calorimetry / Thermochemistry
|
The pH of any mixture of monoprotic acids and bases Herman, D. P.; Booth, K. K.; Parker, O. J.; Breneman, G. L. 115. Bits and pieces, 44. The pH of any mixture of monoprotic weak and strong acids and bases can be calculated. A curve can also be plotted for the titration of the mixture by any monoportic weak or strong acid or base. Herman, D. P.; Booth, K. K.; Parker, O. J.; Breneman, G. L. J. Chem. Educ. 1990, 67, 501.
Acids / Bases |
Titration / Volumetric Analysis |
pH
|
Acid content of beverages: A general chemistry experiment involving the resolution of apparent anomalies Fuchsman, William H.; Garg, Sandhya The authors connect the chemistry of strong and weak acids not only to the world outside the laboratory but also to the kinds of problem solving that engages real scientists. Fuchsman, William H.; Garg, Sandhya J. Chem. Educ. 1990, 67, 67.
Acids / Bases |
Food Science |
pH
|
Colorimetric determination of pH Tucker, Sheryl; Robinson, Rebecca; Keane, Charlene; Boff, Margaret; Zenko, Michelle; Batish, Sanjay; Street, Kenneth W., Jr. Advantages and application of colorimeter to pH measurements. Tucker, Sheryl; Robinson, Rebecca; Keane, Charlene; Boff, Margaret; Zenko, Michelle; Batish, Sanjay; Street, Kenneth W., Jr. J. Chem. Educ. 1989, 66, 769.
pH |
Spectroscopy |
Dyes / Pigments
|
Digitizing circuit for measuring voltage with the Apple II game port Tang, Tong B.; Lee, Albert W. M.; Chan, Sebastian H. T. 102. Bits and pieces, 40. The authors have designed and tested a 10-bit analog-to-digital circuit that makes use of the Apple II+ game port and is very cheap. Tang, Tong B.; Lee, Albert W. M.; Chan, Sebastian H. T. J. Chem. Educ. 1989, 66, 410.
pH |
Laboratory Computing / Interfacing
|
The formaldehyde-sulfite clock reaction revisited Warneck, Peter The purpose of this present note is to discuss the mechanism and the change of pH during the reaction. Warneck, Peter J. Chem. Educ. 1989, 66, 334.
Mechanisms of Reactions |
pH |
Rate Law
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Tools of the trade Bruno, Michael J. High school teachers can never have too many visual aids when teaching chemistry. This author shares some demonstrations in equilibrium that often produce "oohs" and "aaaahs" from his students. Bruno, Michael J. J. Chem. Educ. 1988, 65, 698.
Equilibrium |
pH
|
pH measurements on the overhead projector Solomon, Sally; High, Nancy Universal indicator solution and a corresponding pH indicator chart are used to make pH measurements of an overhead projector where the results are visible to all students in a large lecture hall. Solomon, Sally; High, Nancy J. Chem. Educ. 1987, 64, 964.
pH |
Acids / Bases |
Dyes / Pigments
|
Buffer capacity: An undergraduate laboratory experiment Russo, Steven O.; Hanania, George I. H. A quantitative experiment that can demonstrate buffer action and the measurement of buffer capacity, for a given buffer system, over a range of pH. Russo, Steven O.; Hanania, George I. H. J. Chem. Educ. 1987, 64, 817.
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
The effect of pH and chloride ion concentration on the mobilities of various cations in soil Brown, Melody; Sutherland, Mary; Leharne, Stephen Measuring the mobilities of cations (particularly of toxic metals) in soils using soil thin layer chromatography. Brown, Melody; Sutherland, Mary; Leharne, Stephen J. Chem. Educ. 1987, 64, 448.
pH |
Agricultural Chemistry |
Metals |
Thin Layer Chromatography
|
Demonstration of the pH changes during the electrolysis of water Habich, A.; Hausermann, H. R. Demonstration of the pH changes around the anode and cathode during the electrolysis of water. Habich, A.; Hausermann, H. R. J. Chem. Educ. 1987, 64, 171.
Electrochemistry |
pH
|
The electrolysis of water: An improved demonstration procedure Heideman, Stephen The usual use of sulfuric acid as the electrolyte in the demonstration of the electrolysis of water does not allow students to observe the accompanying pH changes at the electrodes. Heideman, Stephen J. Chem. Educ. 1986, 63, 809.
Water / Water Chemistry |
pH |
Electrochemistry
|
Density gradient columns for chemical displays Guenther, William B. An important advantage of these demonstrations of complex chemistry is that students can observe them over a period of time as they grasp concepts of solution equilibria. Guenther, William B. J. Chem. Educ. 1986, 63, 148.
Acids / Bases |
pH |
Coordination Compounds |
Metals
|
Buffer demonstration Ophardt, Charles E. Emphasizes the difference in properties between strong and weak acids and that only a weak acid or base and its salt are a buffer. Ophardt, Charles E. J. Chem. Educ. 1985, 62, 608.
Acids / Bases |
pH |
Dyes / Pigments
|
To buffer or not to buffer, that is the question Mancott, A. Question involves the preparation of a buffer solution by a chemical reaction but does not have the resultant solution act as a buffer. Mancott, A. J. Chem. Educ. 1985, 62, 606.
Acids / Bases |
pH
|
An invitation to experiment with an experiment Phanstiel, Otto Students are asked to develop an experiment in which they isolate an acid / base indicator from a flower and determine the pH at which it changes color. Phanstiel, Otto J. Chem. Educ. 1985, 62, 522.
Acids / Bases |
Dyes / Pigments |
pH
|
Visualization of buffer action and the acidifying effect of CO2 Schonbeck, Niels D. Includes a discussion of the physiological buffering of CO2 in the human body. Schonbeck, Niels D. J. Chem. Educ. 1985, 62, 436.
Acids / Bases |
pH
|
A simple demonstration of buffer action Duerst, Marilyn D. A simple yet impressive visual demonstration of buffer action. Duerst, Marilyn D. J. Chem. Educ. 1985, 62, 435.
Acids / Bases |
pH
|
An alternative method for the determination of pKa Castillo S., Carlos; Micolta S., Germania; Grajales T., Mario Determining pKa from the titration curve of a weak acid or base. Castillo S., Carlos; Micolta S., Germania; Grajales T., Mario J. Chem. Educ. 1984, 61, 1067.
Acids / Bases |
pH |
Aqueous Solution Chemistry |
Solutions / Solvents
|
An inexpensive, very high impedance digital voltmeter for selective electrodes Caceci, Marco S. Design and construction of an instrument that exceeds in accuracy and input impedance most expensive commercial pH meters and potentiometers. Caceci, Marco S. J. Chem. Educ. 1984, 61, 935.
Laboratory Equipment / Apparatus |
Electrochemistry |
pH
|
Why teach solution equilibrium? Butler, James N. What are the most important aspects of solution equilibrium to teach at the elementary level? Butler, James N. J. Chem. Educ. 1984, 61, 784.
Equilibrium |
Solutions / Solvents |
Acids / Bases |
pH
|
The rainbow connection Hutton, Bill Demonstrates how the color of certain acid-base indicators can be influenced in a reversible manner by changes in pH. Hutton, Bill J. Chem. Educ. 1984, 61, 172.
Acids / Bases |
pH |
Dyes / Pigments
|
Sequential color reactions: School colors and a red-white-and-blue demonstration Lambert, Jack L.; Chejlava, Michael J.; Fina, Gary T.; Luce, Nina L. Many school colors can be generated using the directions for acid-base demonstrations in this article. Lambert, Jack L.; Chejlava, Michael J.; Fina, Gary T.; Luce, Nina L. J. Chem. Educ. 1983, 60, 141.
pH |
Acids / Bases |
Dyes / Pigments
|
A pocket calculator program for the solution of pH problems via the method of successive approximations Guida, Wayne C. 37. Bits and pieces, 14. A description of a pocket calculator program for the solution of pH problems via the method of successive approximations . Guida, Wayne C. J. Chem. Educ. 1983, 60, 101.
pH |
Acids / Bases |
Chemometrics
|
A tutorial program for pH calculation Palmer, Glenn E. 37. Bits and pieces, 14. These authors describe a calculator program that can be used to help students drill pH calculations. Palmer, Glenn E. J. Chem. Educ. 1983, 60, 101.
pH |
Titration / Volumetric Analysis
|
pH meter revisions Eisnor, Charles R. Two modifications to an earlier published design for an electronic pH meter. Eisnor, Charles R. J. Chem. Educ. 1982, 59, 240.
Laboratory Equipment / Apparatus |
pH
|
The construction of inexpensive digital pH meters Warner, Brian D.; Boehme, Gerhard; Pool, Karl L. Parts list and circuit diagram for a low-cost pH meter. Warner, Brian D.; Boehme, Gerhard; Pool, Karl L. J. Chem. Educ. 1982, 59, 65.
Laboratory Equipment / Apparatus |
pH |
Acids / Bases |
Quantitative Analysis
|
Soil analysis for high school chemistry students Eisenmann, Mary A. Students examine the solubility of nitrate ions, the insolubility of iron hydroxide and iron carbonate, and the reaction between acid and carbonates. Eisenmann, Mary A. J. Chem. Educ. 1980, 57, 897.
Agricultural Chemistry |
Plant Chemistry |
Applications of Chemistry |
Geochemistry |
Acids / Bases |
pH |
Oxidation / Reduction |
Precipitation / Solubility |
Aqueous Solution Chemistry
|
An extra function for the manual temperature compensation control on pH meters Eilbeck, W. John The manual temperature compensation control on pH meters changes the RT/F slope. Eilbeck, W. John J. Chem. Educ. 1980, 57, 834.
Laboratory Equipment / Apparatus |
pH
|
An acid or a base? Uriarte, Richard J. Does a diluted acid remain acidic? Uriarte, Richard J. J. Chem. Educ. 1980, 57, 806.
Acids / Bases |
pH |
Solutions / Solvents |
Aqueous Solution Chemistry
|
Apple dunking O'Connor, Rod Question regarding the ratio between ions of p-nitrophenylhydrazone in reducing the pH of basic effluent. O'Connor, Rod J. Chem. Educ. 1980, 57, 598.
Acids / Bases |
Aqueous Solution Chemistry |
Solutions / Solvents |
pH |
Industrial Chemistry
|
Significant digits: Numbers and their logarithms Clever, H. Lawrence The number of digits to report in a base 10 logarithm is an unresolved problem for many students. Clever, H. Lawrence J. Chem. Educ. 1979, 56, 824.
Chemometrics |
pH
|
Chemistry tutorial programs on display terminals Heit, M.; Jones, W. E.; Wasson, John
Heit, M.; Jones, W. E.; Wasson, John J. Chem. Educ. 1979, 56, 787.
Acids / Bases |
pH
|
Thermal buffers: An illustrative analogy Macomber, Roger S. An analogy between acid-base buffer behavior and the thermal behavior of a two-phase (solid and liquid) system. Macomber, Roger S. J. Chem. Educ. 1979, 56, 710.
Acids / Bases |
pH
|
Isoenzymes Daugherty, N. A. The separation, identification, and measurement of isoenzymes is an appropriate topic for a special lecture in general chemistry. Daugherty, N. A. J. Chem. Educ. 1979, 56, 442.
Enzymes |
Proteins / Peptides |
pH |
Electrophoresis |
Separation Science |
Electrochemistry |
Applications of Chemistry
|
Titration curve for a programmable pocket calculator Williams, Howard P. A titration curve program written for a TI-58 or TI-59 programmable pocket calculator. Williams, Howard P. J. Chem. Educ. 1979, 56, 237.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Quantitative Analysis
|
Comparison of strong acid and weak acid titration curves Schultz, C. W.; Spannuth, S. L. Allows comparison of mechanically reproduced titration curves of strong acid and one or more weak acids versus strong base on the same piece of paper. Schultz, C. W.; Spannuth, S. L. J. Chem. Educ. 1979, 56, 194.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
pH
|
The standardization of pH meters: A comparison of procedures for different types of instruments Lund, Walter Discusses the various approaches to the standardization of pH meters and the limitations of the various procedures. Lund, Walter J. Chem. Educ. 1979, 56, 129.
Instrumental Methods |
pH |
Laboratory Equipment / Apparatus |
Laboratory Management |
Calibration |
Acids / Bases
|
The pH concept Kolb, Doris Reviews pH, the pH scale, pH calculations, buffered solutions, and measuring pH. Kolb, Doris J. Chem. Educ. 1979, 56, 49.
pH |
Aqueous Solution Chemistry |
Acids / Bases
|
Buffer effect demonstration on the overhead projector Hobe, Paul G., Jr. Illustrates that one drop of dilute acid or base will change the pH of water by a large amount while larger amounts can be added to a buffer solution before any change is noted. Hobe, Paul G., Jr. J. Chem. Educ. 1979, 56, 47.
Acids / Bases |
pH
|
Conjugate acid-base mixtures in the general chemistry laboratory. A comprehensive buffer experiment Wiger, George R.; de la Camp, Ulrich A very exact and detailed procedure for a comprehensive buffer experiment is presented in this paper. Wiger, George R.; de la Camp, Ulrich J. Chem. Educ. 1978, 55, 401.
Acids / Bases |
pH
|
Determination of the percent Na4EDTA in bathroom cleaners Kump, K. I.; Palocsay, F. A.; Gallaher, T. N. There has been much publicity recently about the importance and virtues of relevant experiments in chemistry lab courses. This experiment is for the general chemistry student involving the analysis of bathroom cleaners and determining the concentration of active ingredients. Kump, K. I.; Palocsay, F. A.; Gallaher, T. N. J. Chem. Educ. 1978, 55, 265.
Titration / Volumetric Analysis |
pH |
Consumer Chemistry |
Quantitative Analysis
|
Determination of pKa using the half-volume method: A laboratory experiment Stephens, S. Jane; Jonich, Michael J. The equivalence point of an unknown acid is found; the value of pKa is read directly from the titration curve using the "half-volume" method. Stephens, S. Jane; Jonich, Michael J. J. Chem. Educ. 1977, 54, 711.
pH |
Titration / Volumetric Analysis |
Quantitative Analysis
|
Questions [and] Answers Campbell, J. A. 330-333. Four questions and their answers; includes comments made by readers on earlier questions 130, 153, 154, 171, 172, 181. Campbell, J. A. J. Chem. Educ. 1977, 54, 678.
Enrichment / Review Materials |
Atmospheric Chemistry |
Applications of Chemistry |
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials |
Metals |
pH
|
Emphasis on acids and bases J. Chem. Educ. Staff Considers the acidity or basicity in soils and natural waters; the acid-base balance in body chemistry; acidic and basic foods; the approximate pH values of common fluids; examples of acidic, basic, and neutral drugs; and the commercial preparation of nitric acid. J. Chem. Educ. Staff J. Chem. Educ. 1977, 54, 626.
Acids / Bases |
Water / Water Chemistry |
Food Science |
Applications of Chemistry |
pH |
Drugs / Pharmaceuticals
|
pH of hair shampoos. A topical high school experiment Griffin, John J.; Corcoran, Robert F.; Akana, Kenn K. Investigates the pH of hair shampoos and the effect of pH on cleansing hair. Griffin, John J.; Corcoran, Robert F.; Akana, Kenn K. J. Chem. Educ. 1977, 54, 553.
pH |
Consumer Chemistry
|
Lecture demonstration digital multimeter Myers, Gardiner H.; Dugan, Robert J. Plans for a Lecture Demonstration Digital Multimeter used to measure and display electric potential, current, temperature, pressure, and pH. Myers, Gardiner H.; Dugan, Robert J. J. Chem. Educ. 1977, 54, 495.
Laboratory Equipment / Apparatus |
pH |
Electrochemistry
|
Adapting a pH meter for lecture demonstrations: Construction of an auxiliary scale for overhead projectors Stanko, Joseph A.; Haas, Charles G.; Lotz, John R. A pH meter adopted for display on an overhead. Stanko, Joseph A.; Haas, Charles G.; Lotz, John R. J. Chem. Educ. 1977, 54, 365.
Acids / Bases |
pH
|
The effects of HCl and aspirin on the stomach: An equilibrium review DeLorenzo, Ronald The chemical effect and medical implications of taking aspirin. DeLorenzo, Ronald J. Chem. Educ. 1977, 54, 306.
Equilibrium |
Acids / Bases |
pH |
Drugs / Pharmaceuticals |
Medicinal Chemistry |
Applications of Chemistry
|
Effect of Ionic Strength on Equilibrium Constants Seymour, M. D.; Fernando, Quintus Involves the determination of the acid dissociation constant of bromcresol green by a spectrophotometric method; using a graphing calculator, each student can perform the laboratory work and obtain his own data set. Seymour, M. D.; Fernando, Quintus J. Chem. Educ. 1977, 54, 225.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
pH
|
Separation of an APC mixture. A quantitative analysis experiment Haddad, Paul; Rasmussen, Malcolm In this paper the well known technique of pH, controlled extractive separation of a mixture of an acidic, basic, and neutral organic substance has been applied to separation and analysis of a mixture of the drugs aspirin, caffeine, and phenacetin. Haddad, Paul; Rasmussen, Malcolm J. Chem. Educ. 1976, 53, 731.
Drugs / Pharmaceuticals |
pH |
Acids / Bases |
Separation Science
|
An Effective demonstration of the behavior of indicators and biochemicals in buffers Lerman, Charles L. The author has found this demonstration of buffers useful for both freshman level courses and as a refresher in biochemistry. Lerman, Charles L. J. Chem. Educ. 1976, 53, 634.
Acids / Bases |
pH
|
A new buffer demonstration Friedman, Norman An Alka-Seltzer tablet in water is used as a buffer system and its resistance to changes in pH are compared to solutions of buffered aspirin and aspirin. Friedman, Norman J. Chem. Educ. 1975, 52, 605.
Acids / Bases |
pH |
Consumer Chemistry
|
Protective cover for glass electrodes DeWitt, H. D. Slipping a piece of perforated vinyl tubing over the end of a glass electrode. DeWitt, H. D. J. Chem. Educ. 1975, 52, 498.
Laboratory Equipment / Apparatus |
pH |
Acids / Bases
|
Questions [and] Answers Campbell, J. A. 193-197. Five biochemical questions and their answers. Campbell, J. A. J. Chem. Educ. 1975, 52, 457.
Enrichment / Review Materials |
pH |
Isotopes |
Water / Water Chemistry
|
Questions [and] Answers Campbell, J. A. 180-183. Four biochemistry questions and their answers. Campbell, J. A. J. Chem. Educ. 1975, 52, 241.
Enrichment / Review Materials |
Photochemistry |
Photosynthesis |
Acids / Bases |
pH
|
A new chemistry program for nursing and allied health students Stanitski, Conrad L.; Sears, Curtis T., Jr. Outlines and discusses the topics considered in a chemistry program for nursing and allied health students. Stanitski, Conrad L.; Sears, Curtis T., Jr. J. Chem. Educ. 1975, 52, 226.
Nonmajor Courses |
Applications of Chemistry |
Medicinal Chemistry |
Oxidation / Reduction |
Catalysis |
Acids / Bases |
pH |
Metabolism |
Drugs / Pharmaceuticals
|
An easily fabricated pH cell Hendrixson, R. R. A pH cell for use in titration experiments where the solution should be protected from the air. Hendrixson, R. R. J. Chem. Educ. 1975, 52, 109.
Laboratory Equipment / Apparatus |
pH |
Quantitative Analysis |
Acids / Bases |
Titration / Volumetric Analysis
|
A computer program for the analysis of titration data Scholler, D. M.; Lyndrup, M. L. A computer program to analyze titration data for monoprotic and diprotic acids. Scholler, D. M.; Lyndrup, M. L. J. Chem. Educ. 1975, 52, 106.
Titration / Volumetric Analysis |
Quantitative Analysis |
Acids / Bases |
pH
|
A simple, effective demonstration of titration curves and indicator selection Nathan, Lawrence C. The concepts of acid-base titration curves and selection of the appropriate indicator for an acid-base titration can be easily and effectively demonstrated by use of a potentiometric titration. Nathan, Lawrence C. J. Chem. Educ. 1973, 50, 262.
Acids / Bases |
Dyes / Pigments |
Titration / Volumetric Analysis |
pH |
Quantitative Analysis
|
Questions [and] Answers Campbell, J. A. Five questions requiring an application of chemical principles and their solutions. Campbell, J. A. J. Chem. Educ. 1973, 50, 128.
Enrichment / Review Materials |
Proteins / Peptides |
pH |
Carbohydrates |
Molecular Properties / Structure
|
pH range -47 to +47? Pilar, Frank L. The author of the cited article corrects a mistake in his original manuscript. Pilar, Frank L. J. Chem. Educ. 1972, 49, 851.
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Preparation of solutions in the pH range of approximately -47 to +47 Pilar, Frank L. By adding more and more water to an acidic solution, one can produce as high a pH as desired. Pilar, Frank L. J. Chem. Educ. 1972, 49, 776.
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
An interactive program for teaching pH and logarithms Eskinazi, Jak; Macero, Daniel J. A computer program written in APL for teaching students logarithms and pH calculations. Eskinazi, Jak; Macero, Daniel J. J. Chem. Educ. 1972, 49, 571.
pH |
Acids / Bases |
Chemometrics
|
Measurement of pH of distilled water Youmans, Hubert L. Resolving the problem of pH meters giving readings for the pH of distilled water that differ significantly from 7. Youmans, Hubert L. J. Chem. Educ. 1972, 49, 429.
Water / Water Chemistry |
pH |
Quantitative Analysis
|
Programmable calculators. Simulated experiments Runquist, O.; Olsen, Rodney; Snadden, Bruce Describes how titration and reaction rate experiments can be simulated on a programmable calculator. Runquist, O.; Olsen, Rodney; Snadden, Bruce J. Chem. Educ. 1972, 49, 265.
Acids / Bases |
Titration / Volumetric Analysis |
Quantitative Analysis |
Rate Law |
Kinetics |
pH
|
Pain: A chemical explanation Plumb, Robert C.; Lindahl, Olov In sensing pain the nervous system acts like a pH meter. Plumb, Robert C.; Lindahl, Olov J. Chem. Educ. 1972, 49, 179.
pH |
Acids / Bases |
Applications of Chemistry |
Medicinal Chemistry
|
The hydrolysis of 4-nitrophenol phosphate. A freshman class investigation Hopkins, Harry P., Jr.; Mather, Jane H. A study of the hydrolysis of 4-nitrophenol phosphate is made the basis of a biochemistry-oriented quarter in freshman chemistry; after completing the simple hydrolysis studies, the student proceeds to investigate the enzymatic hydrolysis of 4-nitrophenol phosphate. Hopkins, Harry P., Jr.; Mather, Jane H. J. Chem. Educ. 1972, 49, 126.
Reactions |
pH |
Esters |
Enzymes |
Catalysis
|
Acid-base reaction parameters Freiser, Henry The author demonstrates how the combined algebraic graphical approach can be extended to acid-base titration curve calculations as well as to buffer and sharpness index formulation. Freiser, Henry J. Chem. Educ. 1970, 47, 809.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Chemometrics
|
Ratio diagrams: A simple graphical representation of complicated equilibria de Levie, R. Introduces and demonstrates the usefulness and general applicability of ratio diagrams as the simplest graphical representation of equilibria involving mononuclear species. de Levie, R. J. Chem. Educ. 1970, 47, 187.
Equilibrium |
Acids / Bases |
pH |
Aqueous Solution Chemistry |
Precipitation / Solubility
|
Hydrolysis of sodium carbonate Nakayama, F. S. Presents a procedure for obtaining the ion concentrations of the various component species produced by the hydrolysis of sodium carbonate. Nakayama, F. S. J. Chem. Educ. 1970, 47, 67.
Aqueous Solution Chemistry |
Chemometrics |
pH
|
Component concentrations in solutions of weak acids Goldish, Dorothy M. presents a new approach to teaching the subject of weak acid equilibria and its associated calculations. Goldish, Dorothy M. J. Chem. Educ. 1970, 47, 65.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Chemometrics |
pH
|
Computer programs for calculating pH Schlessinger, Gert G. A brief note on the availability of a Fortran II program for calculating the pH of weak acids and bases and salts of these species in aqueous solution. Schlessinger, Gert G. J. Chem. Educ. 1969, 46, 680.
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
A versatile reagent for general chemistry Dauphinee, G. A.; Heit, M. L. This short note lists seven general chemistry experiments on various aspects of potassium hydrogen oxalate. Dauphinee, G. A.; Heit, M. L. J. Chem. Educ. 1969, 46, 660.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Qualitative Analysis
|
Graphical method for acidity constants Heck, Ludwig The author presents a graphical method for the determination of acidity constants of very weak acids. Heck, Ludwig J. Chem. Educ. 1969, 46, 535.
Acids / Bases |
Aqueous Solution Chemistry |
pH
|
Monoprotic or diprotic? Goldman, James A. The author demonstrates that the results of an earlier article are not altogether unexpected. Goldman, James A. J. Chem. Educ. 1969, 46, 123.
Acids / Bases |
Aqueous Solution Chemistry |
pH
|
Chemical queries. Especially for introductory chemistry teachers Young, J. A.; Malik, J. G. (1) Is there such a thing as a negative pH value? Or one above 14? (2) What is entropy, in terms a beginner may understand? (3) On calculating the molecular weight of a solute from concentration and freezing point depression. Young, J. A.; Malik, J. G. J. Chem. Educ. 1969, 46, 36.
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Thermodynamics |
Molecular Properties / Structure
|
Circular slide rule conversion of pH to [H+] Grimm, Larry C. This short note discusses the use of a circular slide rule to convert pH to [H+]. Grimm, Larry C. J. Chem. Educ. 1969, 46, 22.
Chemometrics |
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Carbon and its inorganic compounds. C. Carbon dioxide Colo, August J.; Klug, Evangeline B.; Alyea, Hubert N. Demonstrations include rising mothballs with CO2, dry ice into limewater, and producing school colors: CO2 changing pH. Colo, August J.; Klug, Evangeline B.; Alyea, Hubert N. J. Chem. Educ. 1968, 45, A517.
pH
|
Errors in calculating hydrogen ion concentration House, J. E., Jr.; Reiter, R. C. The possibility of avoiding the full quadratic calculation in determining hydrogen ion concentration depends on both the dissociation constant and the concentration of the acid or base. House, J. E., Jr.; Reiter, R. C. J. Chem. Educ. 1968, 45, 679.
Acids / Bases |
Aqueous Solution Chemistry |
pH
|
Corrections for simple equations for titration curves of monoprotic acids Cortelyou, W. P. Presents corrections for simple equations for titration curves of monoprotic acids and their derivations. Cortelyou, W. P. J. Chem. Educ. 1968, 45, 677.
Acids / Bases |
Titration / Volumetric Analysis |
pH |
Aqueous Solution Chemistry
|
Is a weak acid monoprotic? A new look at titration curves Sturrock, Peter E. It is suggested that experimental values of ?pH may be employed as a simple, yet sensitive, criterion to determine whether an unknown acid is monoprotic. Sturrock, Peter E. J. Chem. Educ. 1968, 45, 258.
Acids / Bases |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis |
pH
|
The acid base calculator Flack, Arnold This short note describes an acid base calculator designed to assist in the teaching of logarithmic relationships. Flack, Arnold J. Chem. Educ. 1967, 44, 466.
Acids / Bases |
pH
|
A pH scaler Alpern, D. K. Describes a convenient pocket size scale made using log paper and a linear graph sheet. Alpern, D. K. J. Chem. Educ. 1967, 44, 330.
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
Simple equipment for automatic potentiometric pH titrations Olsen, Eugene D. This paper describes a simple yet versatile apparatus employing a siphon pipet to deliver titrant solution automatically and accurately during the course of a titration. Olsen, Eugene D. J. Chem. Educ. 1966, 43, 310.
pH |
Titration / Volumetric Analysis |
Electrochemistry |
Aqueous Solution Chemistry |
Quantitative Analysis |
Laboratory Equipment / Apparatus
|
Letter to the editor Roberts, N. K. Discusses the action of buffer solutions to resist changes in pH. Roberts, N. K. J. Chem. Educ. 1966, 43, 108.
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
A computer program for use in teaching chemical equilibrium Zajicek, O. T. Describes a computer program for use in teaching chemical equilibrium. Zajicek, O. T. J. Chem. Educ. 1965, 42, 622.
Equilibrium |
Acids / Bases |
pH
|
Slide rule conversion of [H+] to pH Irby, Bobby N. Describes a method for the conversion of [H+] to pH using a slide rule. Irby, Bobby N. J. Chem. Educ. 1965, 42, 546.
pH
|
Teaching ionic equilibrium: Use of log chart transparencies Freiser, Henry; Fernando, Quintus The use of graphical methods brings the problem of significance of various terms in complicated expressions into proper focus. Furthermore, a pictorial representation permits the student to see at a glance how the concentrations of various species in a system at equilibrium change with conditions. Freiser, Henry; Fernando, Quintus J. Chem. Educ. 1965, 42, 35.
Aqueous Solution Chemistry |
Equilibrium |
Acids / Bases |
pH |
Chemometrics |
Brønsted-Lowry Acids / Bases
|
Solubility and pH Calculations (Butler, James N.) Ramette, R. W.
Ramette, R. W. J. Chem. Educ. 1964, 41, A970.
Aqueous Solution Chemistry |
Precipitation / Solubility |
pH |
Acids / Bases |
Chemometrics |
Enrichment / Review Materials
|
Overhead projection with the pH meter Hoff, Darrel B. Describes a means of projecting an image of a pH meter. Hoff, Darrel B. J. Chem. Educ. 1964, 41, 662.
pH |
Acids / Bases |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis
|
The hydration of carbon dioxide: A double clock experiment Jones, P.; Haggett, Max L.; Longridge, Jethro L. This extension of the "Soda Water Clock" experiment provides a quantitative kinetics investigation. Jones, P.; Haggett, Max L.; Longridge, Jethro L. J. Chem. Educ. 1964, 41, 610.
Reactions |
Rate Law |
Kinetics |
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
Automatic titrimetry in introductory college chemistry Zajicek, O. T. The experiment described here employs an automatic pH titrator as a tool for the teaching of a detailed treatment of simultaneous equilibria. Zajicek, O. T. J. Chem. Educ. 1964, 41, 554.
Titration / Volumetric Analysis |
pH |
Aqueous Solution Chemistry |
Acids / Bases |
Equilibrium
|
A versatile and inexpensive pH recording electrometer Malmstadt, H. V. Presents the design and operation of a modular pH unit with automatic temperature compensation. Malmstadt, H. V. J. Chem. Educ. 1964, 41, 148.
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
Development of the pH concept: A historical survey Szabadvary, Ferenc; Oesper, Ralph E., trans. Traces the historical development of the following: a recognition of the importance of hydrogen ion concentration; an understanding of buffer solutions; and the concept and measurement of pH. Szabadvary, Ferenc; Oesper, Ralph E., trans. J. Chem. Educ. 1964, 41, 105.
pH |
Acids / Bases |
Aqueous Solution Chemistry
|
An easily prepared wide range buffer series Carmody, W. R. Provides suggestions for research to accompany earlier published articles. Carmody, W. R. J. Chem. Educ. 1963, 40, A386.
Undergraduate Research |
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Effect of chloride ion on precipitation of cadmium sulfide O'Donnell, T. A. Adding NaCl or KCl to suspended CdS causes the suspension to disappear. O'Donnell, T. A. J. Chem. Educ. 1963, 40, A313.
Precipitation / Solubility |
pH |
Equilibrium
|
Precipitation from homogeneous solution Gordon, L.; Salesin, E. D. Suggests research questions based on an earlier published article. Gordon, L.; Salesin, E. D. J. Chem. Educ. 1963, 40, A306.
Undergraduate Research |
Solutions / Solvents |
Precipitation / Solubility |
pH
|
Making baking powder biscuits: A practical experiment on hydrolysis of salts Rainey, R. C. A "take home" experiment tying together the topics of the hydrolysis of salts and their effects on the pH of water solutions. Rainey, R. C. J. Chem. Educ. 1962, 39, 363.
Consumer Chemistry |
pH
|
Laboratory group exercises in acid-base theory Zuehlke, R. W. An experiment to introduce the topic of acid-base titrimetry and illustrate the properties of acids and bases. Zuehlke, R. W. J. Chem. Educ. 1962, 39, 354.
Acids / Bases |
Titration / Volumetric Analysis |
pH
|
Demonstrations for the overhead projector Spiegler, K. S.; Gruenberg, J.; Trattner, Adriana; Weiss, W. Demonstrations include the production of iron, potentiometric titration, photography, and the measurement of pH by indicators. Spiegler, K. S.; Gruenberg, J.; Trattner, Adriana; Weiss, W. J. Chem. Educ. 1962, 39, 86.
Titration / Volumetric Analysis |
pH |
Aqueous Solution Chemistry |
Acids / Bases
|
Easily prepared wide range buffer series Carmody, Walter R. A series of buffers with pH values ranging from 2.0 to 12.0 that requires the preparation of only two stock solutions and requires only three common chemicals. Carmody, Walter R. J. Chem. Educ. 1961, 38, 559.
Aqueous Solution Chemistry |
Acids / Bases |
pH |
Laboratory Management
|
Is there an alternative to pH? Crane, Francis E., Jr. Provides some alternatives to the traditional definition of pH that introductory students may find more intuitive and less confusing. Crane, Francis E., Jr. J. Chem. Educ. 1961, 38, 365.
pH |
Acids / Bases |
Nomenclature / Units / Symbols
|
pH meters (continued) Lewin, S. Z. Considers the standardization, calibration, and testing of pH meters, as well as Beckman pH meters. Lewin, S. Z. J. Chem. Educ. 1959, 36, A595.
Instrumental Methods |
pH |
Acids / Bases |
Aqueous Solution Chemistry |
Calibration
|
pH meters Lewin, S. Z. Examines the operation and individual components of pH meters. Lewin, S. Z. J. Chem. Educ. 1959, 36, A477.
Laboratory Equipment / Apparatus |
pH |
Acids / Bases
|
Exact colorimetric pH determination Stedman, D. F. Various combinations of three dyes - brom cresol green, methyl red, and brom phenol blue - are used to determine pH values from 4.3 to 5.8. Stedman, D. F. J. Chem. Educ. 1958, 35, 456.
pH |
Dyes / Pigments |
Aqueous Solution Chemistry
|
Research project for general chemistry laboratory Schwolow, Jean In order to modify the routine experiment in which students know the answers before ever entering the laboratory, freshmen were presented with a simulated research project connected with acids, bases, and pH measurements. Schwolow, Jean J. Chem. Educ. 1958, 35, 416.
Undergraduate Research |
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Universal indicator for pH 1-13 Richardson, F. R. Describes a mixture of indicators that serves as a universal indicator for pH 1-13. Richardson, F. R. J. Chem. Educ. 1956, 33, 517.
Dyes / Pigments |
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Indicators and the basis for their use Gorin, George Describes the method for selecting appropriate indicators and the teaching of this subject. Gorin, George J. Chem. Educ. 1956, 33, 318.
Dyes / Pigments |
Titration / Volumetric Analysis |
Acids / Bases |
Aqueous Solution Chemistry |
Quantitative Analysis |
pH
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Amphoteric molecules, ions and salts Davidson, David It is the aim of this paper to call attention to the splendid opportunity amphoteric substances afford for the teaching of acid-base principles. Davidson, David J. Chem. Educ. 1955, 32, 550.
Molecular Properties / Structure |
Acids / Bases |
pH |
Aqueous Solution Chemistry
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Pocket slide rule for pH calculations Pitzer, Edgar C. A pocket slide rule may be used for direct conversion from hydrogen-ion activity to pH, or vice versa, without the need for arithmetical computation. Pitzer, Edgar C. J. Chem. Educ. 1955, 32, 300.
pH |
Aqueous Solution Chemistry |
Chemometrics
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A general equation for approximate hydronium ion calculations Drenan, James W. Presents a general equation for simplifying calculations of the hydronium ion. Drenan, James W. J. Chem. Educ. 1955, 32, 36.
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Chemometrics
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A log table for pH problems Condon, Francis E. Provides a readily remembered log table suitable for computing pH from hydronium-ion concentration and the reverse. Condon, Francis E. J. Chem. Educ. 1954, 31, 323.
pH |
Chemometrics |
Acids / Bases |
Aqueous Solution Chemistry
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pH approximations McBay, Arthur J. Describes the use of data from tables to approximate pH values. McBay, Arthur J. J. Chem. Educ. 1952, 29, 526.
pH |
Acids / Bases |
Aqueous Solution Chemistry
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