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has the following rate expression at high temperatures:
Rate=k[NO2][CO]
Is the following mechanism compatible with the experimental information? (1) NO2 + CO O-N-O-C-O (slow) (2) O-N-O-C-O NO + CO2 (fast) Choose the best answer.
An Experimental Approach to Teaching and Learning Elementary Statistical MechanicsFrank B. Ellis and David C. Ellis This article details demonstrations that show how equilibrium changes with temperature, energy, and entropy and involve exothermic and endothermic reactions, the dynamic nature of equilibrium, and Le Châtelier's principle. Ellis, Frank B.; Ellis, David C. J. Chem. Educ.2008, 85, 78.
Rotational Mobility in a Crystal Studied by Dielectric Relaxation Spectroscopy. An Experiment for the Physical Chemistry LaboratoryMadalena S. C. Dionísio, Hermínio P. Diogo, J. P. S. Farinha, and Joaquim J. Moura-Ramos In this article we present a laboratory experiment for an undergraduate physical chemistry course. The purpose of this experiment is the study of molecular mobility in a crystal using the technique of dielectric relaxation spectroscopy. The experiment illustrates important physical chemistry concepts. The background of the experimental technique deals with the concepts of orientational and induced polarization and frequency-dependent relative permittivity (or dielectric constant). The kinetic concepts of temperature-dependent relaxation time, activation energy, and activation entropy are involved in the concept of molecular mobility. Dionísio, Madalena S. C.; Diogo, Hermínio P.; Farinha, J. P. S.; Moura-Ramos, Joaquim J. J. Chem. Educ.2005, 82, 1355.
Unimolecular ProcessesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Rate Law
ChemPaths 104 M Feb 21John W. Moore Today in Chem 104:
* Lecture: Rate Laws
* Reading:
Kotz:, Ch. 15, Sec. 3-4
Moore, Ch. 13, Sec. 3-5
* Homework #5 due by 11:55 pm F Feb 25
* Excel assignment due in first discussion section this week
* Quiz 4 in second discussoin section
Kinetics |
Rate Law
The Rate EquationEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
COCl2(g) 
