17-3. Variation of Kc with the Form of the Balanced Equation
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Precipitation Reactions Two versions of the Orange Tornado, two reactions under a microscope, and updated stills of other precipitation reactions provide dramatic visual displays of solid formation.
Equilibrium : KspSaturation (12 Variations)
Zn(OH)2 has a Ksp of 4.5 x 10-17. If you have a solution of Zn(OH)2 that has a hydroxide ion concentration equal to 4.6 x 10-6 mol/L, the solution is ... (Assume that the only relevant reaction is the solubility-product equilibrium.)
Separation Anxiety: An In-Class Game Designed To Help Students Discover ChromatographyMichael J. Samide An in-class activity, designed on the basis of plate theory, allows students to physically separate coins on the basis of a provided partition coefficient. Students move coins between stationary and mobile phases to establish equilibrium conditions. The goal is to have students understand equilibration as it relates to separation, which can lead into a discussion of more complex topics. Samide, Michael J. J. Chem. Educ.2008, 85, 1512.
Does the Addition of Inert Gases at Constant Volume and Temperature Affect Chemical Equilibrium?João C. M. Paiva, Jorge Gonçalves, and Susana Fonseca This article examines three approaches, leading to different conclusions, for answering the question "Does the addition of inert gases at constant volume and temperature modify the state of equilibrium?" Paiva, João C. M.; Gonçalves, Jorge; Fonseca, Susana. J. Chem. Educ.2008, 85, 1133.
Nitrogen Oxides (GCMP)David M. Whisnant Nitrogen Oxides: this is a resource in the collection "General Chemistry Multimedia Problems". Two of the most important nitrogen oxides, N2O4 and NO2, are in equilibrium with each other. We are interested in how this equilibrium shifts with temperature. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Equilibrium
How Accurate Is the Steady State ApproximationLars Ole Haustedt, Jonathan M. Goodman The steady-state approximation is commonly used in enzyme catalysis kinetics calculations, but how much error does the approximation introduce? This Java applet allows you to visually determine the accuracy of the steady-state and pre-equilibrium approximations.
Equilibrium
ChemPaths 104 W Mar 2John W. Moore Today in Chem 104:
* Lecture: Chemical Equilibrium
* Reading:
Kotz: Ch. 16, Sec. 1-2
Moore: Ch. 14, Sec. 1-2
* Homework #6 due by 11:55 pm F Mar 4
* Quiz #4 given in second discussion section this week
* Biomolecules Tutorial: Enzymes and Moodle Quiz due Today at 11:55 pm