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2 Videos
17 Assessment Questions
201 Journal Articles
9 Other Resources
Videos: 2 results
Blue Bottle, Red and Blue Bottle  
Color changes are caused by reactions of oxygen in the air with chemicals in a solution. The colors fade over time, but can be regenerated by shaking the flask containing the solution.
Kinetics |
Mechanisms of Reactions |
Oxidation / Reduction
Induction by Iron(II) of the Oxidation of Iodide by Dichromate  
Acidic aqueous solutions containing dichromate and iodide ions are mixed with no reaction. The addition of a solution of iron(II) ion induces the rapid formation of brown triiodide ion.
Catalysis |
Kinetics |
Mechanisms of Reactions |
Oxidation / Reduction
Assessment Questions: First 3 results
Kinetics : RxnMechanisms (14 Variations)
Experiments show that the reaction of nitrogen dioxide and carbon monoxide
NO2 + CO NO + CO2

has the following rate expression at high temperatures:

Rate=k[NO2][CO]

Is the following mechanism compatible with the experimental information?
(1) NO2 + CO O-N-O-C-O (slow)
(2) O-N-O-C-O NO + CO2 (fast)
Choose the best answer.


Kinetics |
Mechanisms of Reactions |
Rate Law
Kinetics : ElementRxnRateLaws (13 Variations)
Assume that the equation below represents an elementary reaction. Predict the rate expression (rate law) for this reaction.

CO(g) + Cl2(g) COCl2(g)


Kinetics |
Mechanisms of Reactions |
Rate Law
Kinetics : RateConstantUnits (8 Variations)
The isomerization of CH3NC to CH3CN has a rate constant of 0.46 s-1 at 600 K.

(1) Based on the units of the rate constant, what is the order of the reaction? {1:MULTICHOICE:zero-order#No, that is not correct.~=first-order#Correct!~second-order#No, that is not correct.~third-order#No, that is not correct.}

(2) What is the concentration of CH3CN after 0.20 minutes of reaction if the initial concentration is 0.10 M? {1:NUMERICAL:=4e-4:1e-5#Correct!~%50%4e-4:5e-5#Close, but not quite.}(Do not include units!)


Kinetics |
Rate Law
View all 17 results
Journal Articles: First 3 results.
Pedagogies:
J. Chem. Educ. 1999, 76, 1578–1583  John Andraos
Corrections to the article A Streamlined Approach to Solving Simple and Complex Kinetic Systems Analytically.
Andraos, John. J. Chem. Educ. 2008, 85, 1624.
Kinetics |
Mechanisms of Reactions |
Theoretical Chemistry
Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) Complexes  Richard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor
Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction.
Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ. 2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
Dynamic Reaction Figures: An Integrative Vehicle for Understanding Chemical Reactions  Emeric Schultz
Describes the dynamic reaction figure, a flexible learning tool that can be used to balance chemical equations, predict the results of potential reactions, present the underlying mechanism of reactions, and solve quantitative problems in a number of areas.
Schultz, Emeric. J. Chem. Educ. 2008, 85, 386.
Acids / Bases |
Aqueous Solution Chemistry |
Mechanisms of Reactions |
Nonmajor Courses
View all 201 articles
Other Resources: First 3 results
Unimolecular Processes  Ed Vitz, John W. Moore
A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Rate Law
Bimolecular Processes  Ed Vitz, John W. Moore
A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Rate Law
ChemPaths 104 M Feb 21  John W. Moore
Today in Chem 104: * Lecture: Rate Laws * Reading: Kotz:, Ch. 15, Sec. 3-4 Moore, Ch. 13, Sec. 3-5 * Homework #5 due by 11:55 pm F Feb 25 * Excel assignment due in first discussion section this week * Quiz 4 in second discussoin section
Kinetics |
Rate Law
View all 9 results