7-8. Writing Lewis Formulas: Limitations of the Octet Rule
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Bonding : ImpossibleStructure (10 Variations)
Which of the following formulas represent substances that are likely to be stable at ordinary temperature and pressure? A good way to decide is to ask for which of the formulas is it possible to draw a reasonable Lewis structure (one that obeys the usual rules for drawing Lewis structures)?
A New "Bottom-Up" Framework for Teaching Chemical BondingTami Levy Nahum, Rachel Mamlok-Naaman, Avi Hofstein, and Leeor Kronik This article presents a general framework for bonding that can be presented at different levels of sophistication depending on the student's level and needs. The pedagogical strategy for teaching this model is a "bottom-up" one, starting with basic principles and ending with specific properties. Levy Nahum, Tami; Mamlok-Naaman, Rachel; Hofstein, Avi; Kronik, Leeor. J. Chem. Educ.2008, 85, 1680.
Atomic Properties / Structure |
Covalent Bonding |
Ionic Bonding |
Lewis Structures |
Materials Science |
MO Theory |
Noncovalent Interactions
Exploring Solid-State Structure and Physical Properties: A Molecular and Crystal Model ExerciseThomas H. Bindel This laboratory allows students to examine relationships among the microscopicmacroscopicsymbolic levels using crystalline mineral samples and corresponding crystal models. The exercise also reinforces Lewis dot structures, VSEPR theory, and the identification of molecular and coordination geometries. Bindel, Thomas H. J. Chem. Educ.2008, 85, 822.
Crystals / Crystallography |
Molecular Properties / Structure |
Molecular Modeling |
Solids |
VSEPR Theory |
Lewis Structures |
Physical Properties
More on ClO and Related RadicalsWilliam B. Jensen The novel Lewis structure for the ClO radical and other related 13e isoelectronic species presented by Hirsch and Kobrak is identical to that proposed by Linnett over 40 years ago for the same species on the basis of his well-known double-quartet approach to Lewis structures. Jensen, William B. J. Chem. Educ.2008, 85, 783.