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Carbohydrates Dehydration of sucrose, Fehling's test, Benedict's test, osazone formation, destructive distillation of wood, oxidation of sucrose with potassium chlorate, and guncotton are demonstrated.
Structures for the ABO(H) Blood Group: Which Textbook Is Correct?John M. Risley Six textbooks and two Internet sites show different structures for the A, B, and O(H) antigens of the ABO(H) blood group, but none of them are correct. This article emphasizes the correct molecular structures because it is important to distinguish between those carbohydrates that make up the antigens and those that are not part of the antigenic structures. Risley, John M. J. Chem. Educ.2007, 84, 1546.
Bioorganic Chemistry |
Carbohydrates |
Natural Products |
Molecular Properties / Structure
Acetal Protecting Groups in the Organic Laboratory: Synthesis of Methyl 4,6-O-Benzylidene-α-D-GlucopyranosideAlexei V. Demchenko, Papapida Pornsuriyasak, and Cristina De Meo The synthesis of methyl 4,6-O-benzylidene-a-D-glucopyranoside provides an opportunity to synthesize a cyclic acetal; stereoselectively introduce a chirality center; and learn extraction, evaporation, precipitation, optical rotation, melting point measurement, thin-layer chromatography, IR-spectroscopy, mass spectrometry, and various NMR techniques. Demchenko, Alexei V.; Pornsuriyasak, Papapida; De Meo, Cristina. J. Chem. Educ.2006, 83, 782.
Carbohydrates |
IR Spectroscopy |
Medicinal Chemistry |
NMR Spectroscopy |
Thin Layer Chromatography |
Synthesis
Glycosyltransferases A and B: Four Critical Amino Acids Determine Blood TypeNatisha L. Rose, Monica M. Palcic, and Stephen V. Evans Human A, B, and O blood type is determined by the presence or absence of distinct carbohydrate structures on red blood cells. In this review the chemistry of the blood group ABO system and the role of glycosyltransferase A, glycosyltransferase B, and the four amino acids critical to determining blood group status are discussed. Rose, Natisha L.; Palcic, Monica M.; Evans, Stephen V. J. Chem. Educ.2005, 82, 1846.
DisaccharidesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Carbohydrates
Simple SugarsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Carbohydrates
ChemPaths 104 W Feb 9John W. Moore Today in Chem 104:
* Lecture: Biochemistry: Carbohydrates and Polysaccharides
* Reading: Moodle Tutorials
o Carbohydrates (including debriefing)
o Lipids (including debriefing)
o Carbohydrates and Lipids Quiz due F Feb 11 11:55 pm
* Homework #4 due F Feb 11 11:55 pm
or 
glycosidic bond.
