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Amines and Aniline pH of aqueous ammonia, cyclohexylamine, and aniline, iodination of aniline, oxidation of aniline with benzoyl peroxide, the nitrous acid test, diazo coupling, reaction of luminol and light sticks are demonstrated.
Organic : FunctionalGroups (18 Variations) The structure for niacin (one of the B-vitamins) is shown below. Which of the following functional groups is present in niacin?
Synthesis and NMR Spectral Analysis of Amine Heterocycles: The Effect of Asymmetry on the 1H and 13C NMR Spectra of N,O-AcetalsShahrokh Saba, James A. Ciaccio, Jennifer Espinal, and Courtney E. Aman Describe an undergraduate organic laboratory experiment in which students prepare two N,O-acetals that differ only in a single ring substituent that introduces asymmetry, giving each compound a distinct 1H and 13C NMR spectral pattern that must be explained by students. Saba, Shahrokh; Ciaccio, James A.; Espinal, Jennifer; Aman, Courtney E. J. Chem. Educ.2007, 84, 1011.
Amines / Ammonium Compounds |
Chirality / Optical Activity |
Green Chemistry |
Heterocycles |
NMR Spectroscopy |
Stereochemistry |
Synthesis
TriethylamineJay A. Young The hazards of triethylamine are discussed. Young, Jay A. J. Chem. Educ.2007, 84, 926.
Amines / Ammonium Compounds |
Laboratory Management
Teaching Structure–Property Relationships: Investigating Molecular Structure and Boiling PointPeter M. Murphy The boiling points for 392 organic compounds are tabulated by carbon chain length and functional group to facilitate a wide range of inquiry-based activities that correlate the effects of chemical structure on physical properties. Murphy, Peter M. J. Chem. Educ.2007, 84, 97.