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Alcohols Oxidation of alcohols with chromic acid, oxidation of glycerin with potassium permanganate, Lucas test, ethanol cannon, and construction of a baster ball cannon are demonstrated.
Alcohols
Phenols and Quinones Ferric chloride test for phenols, nitration of acetaminophen, extraction of dichloroindophenol, oxidation of phenols with sodium periodate, nucleophilic addition to quinones, "purple benzene", oxidation of 2,6-Dit-butlhydoquinone, decolorization of crystal violet, and chameleon emulsion are demonstrated.
A Discovery-Based Experiment Involving Rearrangement in the Conversion of Alcohols to Alkyl HalidesRichard A. Kjonaas and Ryand J. F. Tucker This article reports a discovery-based experiment in which students convert three alcohols to alkyl halides under acidic conditions and record the 13C NMR spectrum in each case. By comparing the number of resonances observed with the number of resonances predicted for each possible product, students draw several conclusions about the resulting rearrangement. Kjonaas, Richard A.; Tucker, Ryand J. F. J. Chem. Educ.2008, 85, 100.
Alcohols |
Carbocations |
Gas Chromatography |
NMR Spectroscopy |
Nucleophilic Substitution
An Organoleptic Laboratory ExperimentJohn M. Risley Compounds in ten different classes of organic molecules that are used in the fragrance and food industry are provided to students. Students whiff the vapors of each compound and describe the organoleptic properties using a set of terms utilized in the fragrance and food industry. A set of questions guides students to an understanding of the relationship between structure of molecules and smell. Risley, John M. J. Chem. Educ.1996, 73, 1181.
ChemPaths 104 M Jan 24John W. Moore Today in Chem 104:
* Lecture: Organic Chemistry
* Reading:
Kotz: Ch. 10, Sec. 3-4
Moore: Ch. 12: Sec. 1, 3-4
* Practice Quiz, Homework #1 due by 11:55pm Today!
* Also, Safety Quiz is due before lab this week.