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The Discovery-Oriented Approach to Organic Chemistry. 7. Rearrangement of trans-Stilbene Oxide with Bismuth Trifluoromethanesulfonate and Other Metal TriflatesJames E. Christensen, Matthew G. Huddle, Jamie L. Rogers, Herbie Yung, and Ram S. Mohan Presents a microscale, green organic chemistry laboratory experiment that illustrates the utility of metal triflates, especially bismuth triflate, as a Lewis acid catalyst. Bismuth compounds are especially attractive for use as catalysts in organic synthesis because of their low toxicity, low cost, and ease of handling. Christensen, James E.; Huddle, Matthew G.; Rogers, Jamie L.; Yung, Herbie; Mohan, Ram S. J. Chem. Educ.2008, 85, 1274.
Catalysis |
Epoxides |
Green Chemistry |
Lewis Acids / Bases |
Mechanisms of Reactions |
Microscale Lab |
NMR Spectroscopy
Concerning Lewis Acid–Base Theory for Proton TransferLawrence J. Sacks Counterpoint commentary in response to a suggestion that the Lewis acidbase approach be applied to reactions such as ammoniawater and HClwater. Sacks, Lawrence J. J. Chem. Educ.2007, 84, 1415.
Acids / Bases |
Lewis Acids / Bases |
Theoretical Chemistry |
Brønsted-Lowry Acids / Bases
J. Chem Ed. 2007, 84, 1056–1061 The article Getting the Weights of Lewis Structures out of Hckel Theory: HckelLewis Configuration Interaction (HL-CI) has an incorrectly printed table on p. 1059. J. Chem. Educ.2007, 84, 1277.
Lewis Acids and BasesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Lewis Acids / Bases
ChemPaths 104 F Apr 15John W. Moore Today in Chem 104:
* Lecture: Titration; Lewis Acids and Bases
* Reading:
Kotz: Ch. 18, Sec. 3; Ch. 17, Sec. 9
Moore: Ch. 17, Sec. 2; Ch. 16, Sec.
* Homework #10 due by 11:55 PM tonight
