TIGER

Journal Articles: 17 results
A Green Polymerization of Aspartic Acid for the Undergraduate Organic Laboratory  George D. Bennett
Based on a technology that won a Presidential Green Chemistry Challenge Award, this experiment involves the thermal polymerization of aspartic acid and subsequent hydrolysis to give sodium poly(aspartate). The procedure is suitable for introducing students to the important topic of polymers and for illustrating several of the principles of green chemistry.
Bennett, George D. J. Chem. Educ. 2005, 82, 1380.
Green Chemistry |
Synthesis |
Industrial Chemistry |
Natural Products |
Polymerization |
Proteins / Peptides
Chemical Recycling of Pop Bottles: The Synthesis of Dibenzyl Terephthalate from the Plastic Polyethylene Terephthalate  Craig J. Donahue, Jennifer A. Exline, and Cynthia Warner
Procedure in which students depolymerize a common plastic (PET from 2-L pop bottles) under mild conditions using nontoxic chemicals to produce monomer building blocks.
Donahue, Craig J.; Exline, Jennifer A.; Warner, Cynthia. J. Chem. Educ. 2003, 80, 79.
Industrial Chemistry |
Synthesis |
Aromatic Compounds |
Polymerization
Chemical Magic: Polymers from a Nonexistent Monomer  Seymour, Raymond B.; Kauffman, George B.
Synthesis, properties, and applications of polyvinyl alcohol and related polymers.
Seymour, Raymond B.; Kauffman, George B. J. Chem. Educ. 1994, 71, 582.
Polymerization |
Alcohols
Polymer additives: III. Surface property and processing modifiers  Stevens, Malcolm P.
The final installment of a three-part paper on the subject of polymer additives. Some of the properties these additives bring to polymers are: anti-blocking agents, anti-fogging agents, antistatic agents, coupling and releasing agents, blowing and crosslinking agents, defoaming agents, emulsifiers, and heat stabilizers.
Stevens, Malcolm P. J. Chem. Educ. 1993, 70, 713.
Polymerization |
Materials Science |
Applications of Chemistry |
Consumer Chemistry
Differential scanning calorimetry study of the cross-linking of styrene and an unsaturated polyester: The chemistry of canoe manufacture.  Vebrel, Joel; Grohens, Yves; Kadmiri, Abderazak; Gowling, Eric W.
An activity geared toward a course where experiments are designed to investigate the preparation of materials, the properties essential to understanding their formation, and the optimization of their application.
Vebrel, Joel; Grohens, Yves; Kadmiri, Abderazak; Gowling, Eric W. J. Chem. Educ. 1993, 70, 501.
Materials Science |
Polymerization |
Reactions |
Calorimetry / Thermochemistry
Synthesis of a phenol-formaldehyde thermosetting polymer  Bedard, Y.; Riedl, B.
Procedure that allows for the synthesis of a 50% aqueous solution of a prepolymer that, with the proper application of heat and pressure, can be used to bind together wood or other materials.
Bedard, Y.; Riedl, B. J. Chem. Educ. 1990, 67, 977.
Synthesis |
Aldehydes / Ketones |
Phenols |
Polymerization
Competency-based modular experiments in polymer science and technology  Pearce, Eli M.; Wright, Carl E.; Bordoloi, Binoy K.
15 modular experiments in polymer science are listed; one of these is presented in detail.
Pearce, Eli M.; Wright, Carl E.; Bordoloi, Binoy K. J. Chem. Educ. 1980, 57, 375.
Polymerization
Polymer preparations in the laboratory  Lampman, Gary M.; Ford, Doug W.; Hale, Wayne R.; Pinkers, Arthur; Sewell, Christopher G.
Some convenient procedures for preparing polymers that have been used in a course for industrial arts students.
Lampman, Gary M.; Ford, Doug W.; Hale, Wayne R.; Pinkers, Arthur; Sewell, Christopher G. J. Chem. Educ. 1979, 56, 626.
Polymerization |
Nonmajor Courses |
Industrial Chemistry
Ethylene: The organic chemical industry's most important building block  Fernelius, Condrad W.; Wittcoff, Harold; Varnerin, Robert E.
The sources, chemistry, and industrial uses of ethylene.
Fernelius, Condrad W.; Wittcoff, Harold; Varnerin, Robert E. J. Chem. Educ. 1979, 56, 385.
Alkenes |
Industrial Chemistry |
Applications of Chemistry |
Polymerization
A demonstration of polymer crosslinking and gel formation without heating  Ross, Joseph H.
Produces an elastic gel at room temperature and provides an effective demonstration of gel properties to use in a discussion of lyophilic colloids.
Ross, Joseph H. J. Chem. Educ. 1977, 54, 110.
Polymerization |
Molecular Properties / Structure |
Colloids
Kinetics of condensation polymerization: Preparation of a polyester  McCaffery, Edward L.
This experiment involves determining the reaction-rate constant for a condensation polymerization.
McCaffery, Edward L. J. Chem. Educ. 1969, 46, 59.
Kinetics |
Polymerization |
Synthesis |
Esters |
Rate Law
Preparation of terephthaloyl chloride: Prelude to ersatz Nylon  Rose, Norman C.
Describes the preparation of terephthaloyl chloride, from which nylon may be generated.
Rose, Norman C. J. Chem. Educ. 1967, 44, 283.
Synthesis |
Polymerization
Preparation and crosslinking of an unsaturated polyester: An organic chemistry experiment  Stevens, M. P.
Unsaturated polyesters are ideally suited for introducing students to polymer chemistry in the laboratory because they are easy to prepare, the use both condensation and addition polymerization, and they serve to demonstrate the techniques involved in preparing the most widely used polymers.
Stevens, M. P. J. Chem. Educ. 1967, 44, 160.
Polymerization |
Esters
The effect of structure on chemical and physical properties of polymers  Price, Charles C.
Suggests using polymers to teach the effect of changes in structure on chemical reactivity, the effect of structure on physical properties, the role of catalysts, and the basic principles of a chain reaction mechanism.
Price, Charles C. J. Chem. Educ. 1965, 42, 13.
Physical Properties |
Molecular Properties / Structure |
Polymerization |
Kinetics |
Reactions |
Catalysis |
Mechanisms of Reactions
The nylon rope trick: Demonstration of condensation polymerization  Morgan, Paul W.; Kwolek, Stephanie L.
Describes the chemistry and variations of the classic polymerization demonstration.
Morgan, Paul W.; Kwolek, Stephanie L. J. Chem. Educ. 1959, 36, 182.
Polymerization
Linear polymerization and synthetic fibers  Moncrieff, Robert W.
Examines early research in polymers, the synthesis of polyesters and polyamides, the polymerization of hydrocarbons, and condensation and addition polymerization.
Moncrieff, Robert W. J. Chem. Educ. 1954, 31, 233.
Polymerization
The mechanisms of the reactions of aliphatic hydrocarbons  Schmerling, Louis
Examines the formation of carbonium ions and free radicals, the polymerization of olefins, hydrogen-halogen exchange, the condensation of haloalkanes with alkenes, the alkylation of paraffins, the condensation of paraffins with chloroolefins, the cracking of paraffins and olefins, and the isomerization of paraffins.
Schmerling, Louis J. Chem. Educ. 1951, 28, 562.
Mechanisms of Reactions |
Alkanes / Cycloalkanes |
Free Radicals |
Polymerization