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Molecular Handshake: Recognition through Weak Noncovalent InteractionsParvathi S. Murthy This article traces the development of our thinking about molecular recognition through noncovalent interactions, highlights their salient features, and suggests ways for comprehensive education on this important concept. Murthy, Parvathi S. J. Chem. Educ.2006, 83, 1010.
Applications of Chemistry |
Biosignaling |
Membranes |
Molecular Recognition |
Noncovalent Interactions |
Chromatography |
Molecular Properties / Structure |
Polymerization |
Reactions
The Amazingly Versatile Titanocene DerivativesDonald C. Bowman Derivatives of titanocene are remarkably versatile in their chemical applications. This article presents a brief review of the derivatives' uses in the fields of polymers, medical oncology, and organic synthesis. Bowman, Donald C. J. Chem. Educ.2006, 83, 735.
Applications of Chemistry |
Catalysis |
Drugs / Pharmaceuticals |
Organometallics |
Polymerization |
Synthesis
Olefin Metathesis Polymerization: The Unexpected Role of Carbenoid Species in Formation of MacromoleculesDonald M. Snyder One particularly interesting topic still rarely seen outside of the research literature is the subject of metathesis polymerization. This article is intended to present the interested reader with a brief introduction to the mechanism of this unique process, its historical background, and some recent developments in the field. Snyder, Donald M. J. Chem. Educ.1996, 73, 155.
Addition PolymersEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Polymerization
Condensation PolymersEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Polymerization
Copoly; A Tool for Understanding Copolymerization and Monomer Sequence Distribution of CopolymersMassoud Miri, Juan A. Morales-Tirado The study of the composition and monomer sequence distribution of binary copolymers is often complicated because of the many definitions of representative properties for the sequence distribution, the numerous calculations required, and occasionally the abstract treatment of the statistical processes describing the copolymer formation. Copoly resolves these issues with a user-friendly, highly visual interface to perform all calculations. Using Microsoft Excel and Word, Copoly is compatible with Windows and Mac OS. In Copoly the students enter up to five independent data parameters using the Data Input Window, and immediately see the results. To obtain diagrams for a copolymerization obeying a second-order Markovian process, the fraction of one monomer, A, and the reactivity ratios, rA, rB, rA´ and rB´ need to be entered; for a first-order Markovian process only the first three of these are required. For a Bernoullian- or zeroth-order Markovian process only A and rA are required. The results are displayed on separate sheets labeled: 1. Copolymerization Diagrams, 2. Dyads and Triads, 3. Sequence Length Distribution, 4. Simulated Copolymer Design, and 5. Summary.
