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Carboxylic Acids and Derivatives Conductivity of carboxylic acids, pH of acetic acid derivatives, hydrophobic effect, and soap emulsions of hydrocarbons are demonstrated.
Carboxylic Acids
Exploding Soap Bubbles: Hydrogen + Oxygen A series of three videos shows that as the ratio of oxygen to hydrogen in soap bubbles increases, the explosions that occur when the bubbles are ignited get louder. (The fact that with an excess of oxygen the explosions would become softer again is not shown.) Each video is repeated with no voice-over so that only the sounds of the explosions are heard. Five still images are provided to show the stoichiometry on the molecular scale. The videos are intended to be shown in order beginning with Hydrogen Alone and ending with hydrogen plus more oxygen.
A Guided-Inquiry Approach to the Sodium Borohydride Reduction and Grignard Reaction of Carbonyl CompoundsRobert E. Rosenberg Students teams identify unknowns and their reaction products and use their data to deduce that esters are less electrophilic than the other carbonyl compounds present, that Grignard reagents are more nucleophilic than sodium borohydride, and that carboxylic acid derivatives do not undergo the nucleophilic addition reactions that are characteristic of aldehydes and ketones. Rosenberg, Robert E. J. Chem. Educ.2007, 84, 1474.
Addition Reactions |
Aldehydes / Ketones |
Esters |
Grignard Reagents |
IR Spectroscopy |
Oxidation / Reduction |
Reactions |
Student-Centered Learning
Oxidation of Aromatic Aldehydes Using OxoneRajani Gandhari, Padma P. Maddukuri, and Thottumkara K. Vinod Describes an eco-friendly procedure for the oxidation of aldehydes to carboxylic acids in water or a water-ethanol mixture using Oxone as the oxidant. The use of eco-friendly solvents, a non-toxic reagent, and the elimination of extraction solvents in the procedure demonstrate important green chemistry themes to students. Gandhari, Rajani; Maddukuri, Padma P.; Vinod, Thottumkara K. J. Chem. Educ.2007, 84, 852.
Aldehydes / Ketones |
Aromatic Compounds |
Aqueous Solution Chemistry |
Carboxylic Acids |
Green Chemistry |
Mechanisms of Reactions |
NMR Spectroscopy |
Oxidation / Reduction
Ozonolysis Problems That Promote Student ReasoningRay A. Gross Jr. The structural features inherent in acyclic monoterpenes that follow the isoprene rule often lead to unique sets of ozonolysis products from which their structures, excluding stereochemistry, can be determined from molecular formulas only. This article shows how students may elucidate the structures of these compounds by analysis of the oxidative and reductive workup products. Gross, Ray A., Jr. J. Chem. Educ.2006, 83, 604.
ChemPaths 104 M Jan 24John W. Moore Today in Chem 104:
* Lecture: Organic Chemistry
* Reading:
Kotz: Ch. 10, Sec. 3-4
Moore: Ch. 12: Sec. 1, 3-4
* Practice Quiz, Homework #1 due by 11:55pm Today!
* Also, Safety Quiz is due before lab this week.
Alcohols |
Ethers |
Aldehydes / Ketones |
Carboxylic Acids |
Amines / Ammonium Compounds
Aldehydes and KetonesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.