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Carboxylic Acids and Derivatives Conductivity of carboxylic acids, pH of acetic acid derivatives, hydrophobic effect, and soap emulsions of hydrocarbons are demonstrated.
Carboxylic Acids
Blue Bottle, Red and Blue Bottle Color changes are caused by reactions of oxygen in the air with chemicals in a solution. The colors fade over time, but can be regenerated by shaking the flask containing the solution.
Kinetics |
Mechanisms of Reactions |
Oxidation / Reduction
Induction by Iron(II) of the Oxidation of Iodide by Dichromate Acidic aqueous solutions containing dichromate and iodide ions are mixed with no reaction. The addition of a solution of iron(II) ion induces the rapid formation of brown triiodide ion.
Synthesis Explorer: A Chemical Reaction Tutorial System for Organic Synthesis Design and Mechanism PredictionJonathan H. Chen and Pierre Baldi Synthesis Explorer is an interactive tutorial system for organic chemistry that enables students to learn chemical reactions in ways previously unrealized. Pedagogical experiments in undergraduate classes at UC Irvine indicate that the system can improve average student examination performance by ~10%. Chen, Jonathan H.; Baldi, Pierre. J. Chem. Educ.2008, 85, 1699.
Mechanisms of Reactions |
Reactions |
Synthesis
Oxidation of Aromatic Aldehydes Using OxoneRajani Gandhari, Padma P. Maddukuri, and Thottumkara K. Vinod Describes an eco-friendly procedure for the oxidation of aldehydes to carboxylic acids in water or a water-ethanol mixture using Oxone as the oxidant. The use of eco-friendly solvents, a non-toxic reagent, and the elimination of extraction solvents in the procedure demonstrate important green chemistry themes to students. Gandhari, Rajani; Maddukuri, Padma P.; Vinod, Thottumkara K. J. Chem. Educ.2007, 84, 852.
Aldehydes / Ketones |
Aromatic Compounds |
Aqueous Solution Chemistry |
Carboxylic Acids |
Green Chemistry |
Mechanisms of Reactions |
NMR Spectroscopy |
Oxidation / Reduction
Iodolactonization of 4-Pentenoic Acid R. David Crouch, Alexander Tucker-Schwartz, and Kathryn Barker Describes an experiment in which 4-pentenoic acid is converted into a lactone via iodolactonization. Crouch, R. David; Tucker-Schwartz, Alexander; Barker, Kathryn. J. Chem. Educ.2006, 83, 921.
Carboxylic AcidsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Carboxylic Acids
Weak AcidsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Carboxylic Acids
ChemPaths 104 W Feb 23John W. Moore Today in Chem 104:
* Lecture: Mechanisms of Reactions
* Reading:
Kotz, Ch. 15, Sec. 5-6
Moore, Ch. 13, Sec. 6-76
* Homework #5 due by 11:55 pm F Feb 25
* Excel Assignment due in first discussion section this week
* Quiz 4 in second discussion section this week
