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Structures and Conformations Molecular models are used to demonstrate the conformations of alkanes and cycloalkanes.
Alkanes / Cycloalkanes |
Molecular Properties / Structure |
Nomenclature / Units / Symbols |
Stereochemistry
Aromatic Compounds A molecular model of benzene, the reactions of bromine with cylohexane, cyclohexene, benzene, phenol, and toluene, the effect of substituents and number of methyl groups on the electron density of aromatic rings, and chlorination reactions of methyl benzenes are demonstrated.
Aromatic Compounds
Phenols and Quinones Ferric chloride test for phenols, nitration of acetaminophen, extraction of dichloroindophenol, oxidation of phenols with sodium periodate, nucleophilic addition to quinones, "purple benzene", oxidation of 2,6-Dit-butlhydoquinone, decolorization of crystal violet, and chameleon emulsion are demonstrated.
The IUPAC Rules for Naming Organic MoleculesStanislaw Skonieczny A systematic approach to naming polyfunctional organic compounds is presented. Latest IUPAC rules are incorporated and the table of order of precedence for the major functional groups is assembled. Skonieczny, Stanislaw. J. Chem. Educ.2006, 83, 1633.
Nomenclature / Units / Symbols
Organic Acids without a Carboxylic Acid Functional GroupG. V. Perez and Alice L. Perez This paper presents several organic molecules that have been labeled as acids but do not contain a carboxylic acid functional group. Various chemical principles such as pKa, tautomerization, aromaticity, conformation, resonance, and induction are explored. Perez, G. V.; Perez, Alice L. J. Chem. Educ.2000, 77, 910.
Acids / Bases |
Molecular Properties / Structure |
Nomenclature / Units / Symbols |
Phenols |
Carboxylic Acids |
Aromatic Compounds
A Simple and Convenient Method for Generation and NMR Observation of Stable CarbanionsHamid S. Kasmai A simple and convenient method for the generation and NMR study of stable carbanions is described. The data and sample spectra illustrate that reliable and good quality NMR spectra of stable carbanions may be obtained. The experiments described provide a good opportunity for students to apply the basic principles of 1H and 13C NMR spectrometry and the interesting topic of the exchange phenomenon in NMR. Kasmai, Hamid S. J. Chem. Educ.1999, 76, 830.
