8.7. Effect of Substituents on the Rate of the SN1 Reaction
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Nucleophilic Substitution Reactions Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Nucleophilic Substitution
Paramagnetism The paramagnetic properties of oxygen are demonstrated using a strong magnet, and compared with diamagnetic nitrogen.
Gases : IDGasFromVelocity (8 Variations)
The following are graphs of molecular velocities versus the relative number of molecules for argon, chlorine, methane and xenon at 300K. Which graph is for argon?
The Sassafras Tree and Designer Drugs: From Herbal Tea to EcstasyFrench, Larry G. Using historical development of material from the sassafras tree and elicit synthesis of the drug ecstasy (MDMA) as a venue for presenting methodology for amine synthesis in organic chemistry. French, Larry G. J. Chem. Educ.1995, 72, 484.
Drugs / Pharmaceuticals |
Synthesis |
Enrichment / Review Materials |
Molecular Properties / Structure
Chart for Deciding Mechanism for Reaction of Alkyl Halide with Nucleophile/BaseMcClelland, Bruce W. The decision chart offered here is based upon the well-known and accepted characteristics of the reaction system mechanisms described in typical introductory organic chemistry textbooks. McClelland, Bruce W. J. Chem. Educ.1994, 71, 1047.
Mechanisms of Reactions |
Nucleophilic Substitution
Nucleophilic substitution reactions: Modifications and an extensionNewton, T. A.; Warren, H. W. Modifications to a procedure comparing the reaction of n-butyl and t-butyl alcohol with equimolar amounts of HCl and HBr. Newton, T. A.; Warren, H. W. J. Chem. Educ.1980, 57, 747.
The Shapes of MoleculesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Molecular Properties / Structure
Multiple Bonds and Molecular ShapesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Molecular Properties / Structure
Monomer of KevlarWilliam F. Coleman The WebWare Molecules for July are from the paper Modern Sport and Chemistry: What a Chemically Aware Sports Fanatic Should Know by Giffin, Boone, Cole, McKay and Kopitzke.
