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Nucleophilic Substitution Reactions Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Nucleophilic Substitution
Chirality A series of chiral and achiral objects, the interaction of polarized light with organic molecules, the assignment of R- and S- configuration, Fisher projections, and a stereospecific reaction are demonstrated.
Animation of Imaginary Frequencies at the Transition StateRobert H. Higgins 176. Software tutorial for strengthening spatial skills and an understanding of stereochemistry in exploring molecular structures. Higgins, Robert H. J. Chem. Educ.1995, 72, 699.
Molecular Properties / Structure |
Stereochemistry |
Molecular Modeling
Chart for Deciding Mechanism for Reaction of Alkyl Halide with Nucleophile/BaseMcClelland, Bruce W. The decision chart offered here is based upon the well-known and accepted characteristics of the reaction system mechanisms described in typical introductory organic chemistry textbooks. McClelland, Bruce W. J. Chem. Educ.1994, 71, 1047.
Stereochemistry TutorialNicola Burrmann Master the concepts organic stereochemistry with this interactive tutorial. It includes definitions, different three dimensional representations, assigning priorities to stereocenters, and determining the stereochemical relationship between molecules. Each section is followed by a question set that tests knowledge and understanding.
Stereochemistry |
Chirality / Optical Activity
Mage; A Tool for Developing Interactive Instructional GraphicsStephen F. Pavkovic Mage is a graphics program especially well suited for visualizing three-dimensional structures of proteins and other macromolecules. It is an important tool for biochemists and finds many applications in biochemistry courses. We utilize Mage to create interactive instructional graphics of potential use in a wider range of undergraduate chemistry courses, and present some of those applications here.
