TIGER

Assessment Questions: 65 results
Kinetics : ArrheniusActEnergy (4 Variations)
The rate constant for the first-order dehydration of tert-butyl alcohol at 500oC is 1.20 x 10 -4 s -1. The rate constant for this process at 600oC is 6.80 x 10 -3 s -1. Calculate the activation energy for this reaction in kJ/mol. (R = 8.314 J/mol K)
Kinetics |
Chemometrics
Kinetics : ArrheniusTemp (3 Variations)
The activation energy for the isomerization of cyclopropane to propene is 274 kJ/mol. By what factor does the rate of reaction increase as the temperature rises from 500oC to 550oC assuming all else remains constant? (R = 8.314 J/mol k)

Hint: This is asking for the ratio of rates which is proportional to the ratio of the rate constants, all else being equal.


Kinetics |
Chemometrics
Kinetics : InterpretEnergyProfile (16 Variations)
Use the energy profile below to decide if the following statements are true or false.

Kinetics |
Mechanisms of Reactions
Kinetics : ElementaryRxnOrNot (9 Variations)
Which of the following reactions could be elementary and unimolecular reactions?
Kinetics |
Mechanisms of Reactions
Kinetics : IntermediateInMech (15 Variations)
Suppose that for the reaction of nitrogen dioxide and carbon monoxide
NO2 + CO NO + CO2

the following mechanism has been proposed at high temperatures:
(1) NO2 + CO O-N-O-C-O (slow)
(2) O-N-O-C-O NO + CO2 (fast)
Check the box for each species that is an intermediate in this mechanism.


Kinetics |
Mechanisms of Reactions
Kinetics : RxnMechanisms (14 Variations)
Experiments show that the reaction of nitrogen dioxide and carbon monoxide
NO2 + CO NO + CO2

has the following rate expression at high temperatures:

Rate=k[NO2][CO]

Is the following mechanism compatible with the experimental information?
(1) NO2 + CO O-N-O-C-O (slow)
(2) O-N-O-C-O NO + CO2 (fast)
Choose the best answer.


Kinetics |
Mechanisms of Reactions |
Rate Law
Kinetics : ElementRxnRateLaws (13 Variations)
Assume that the equation below represents an elementary reaction. Predict the rate expression (rate law) for this reaction.

CO(g) + Cl2(g) COCl2(g)


Kinetics |
Mechanisms of Reactions |
Rate Law
Aldol Reactions (30 Variations)
A collection of 30 assessment questions about Aldol Reactions
Aldehydes / Ketones |
Esters |
Amides |
Carboxylic Acids |
Mechanisms of Reactions |
Acids / Bases |
Reactions |
Synthesis |
Elimination Reactions |
Resonance Theory
Reactions : StrongWeakAcidBase (10 Variations)
Which of the following are strong acids?
Acids / Bases
Reactions : AcidBaseRxns (20 Variations)
In order to answer the following questions, write the net ionic equation for the reaction between equal volumes of 0.10 M solutions of the following acid and base:

KOH(aq) + HBr(aq)

What are the reaction products? Does the reaction yield an acidic, basic, or neutral aqueous solution?


Acids / Bases |
Reactions |
pH
Acetals (9 Variations)
A collection of 9 assessment questions about Acetals
Aldehydes / Ketones |
Oxidation / Reduction |
Reactions |
Mechanisms of Reactions
Anhydrides (2 Variations)
A collection of 2 assessment questions about Anhydrides
Carboxylic Acids |
Mechanisms of Reactions |
Esters |
Synthesis
Acids_and_Bases : LewisAcidBaseRxns (19 Variations)
Identify the Lewis Acid and Base in the reaction of Ag+ and NH3 to form Ag(NH3)2+
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
Lewis Acids / Bases
Aldehyde and Ketone Addition (2 Variations)
A collection of 2 assessment questions about Aldehyde and Ketone Addition
Aldehydes / Ketones |
Acids / Bases |
Reactions
Acids_and_Bases : IonizationSteps (20 Variations)
Citric acid (which is a triprotic acid) has the following structure:

Which of the following equations corresponds to the first ionization step of the acid?

Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : MolcScaleAcidBase (10 Variations)
Study the four drawings below and then decide which best represents an aqueous solution that has

(Water molecules are not shown in the diagrams.)


Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : ConjugateAcidBase (20 Variations)
Identify the acid and base that are reactants and the conjugate acid and conjugate base that are products in the following equation:
HI(aq) + H2O(l)  H3O+(aq) + I-(aq)

Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : HendersonHassel (20 Variations)
You may want to use the following acid/base table to answer the question below.

Papain is a thiol protease isolated from papaya. The optimal pH for its enzymatic activity is 6.0-7.0. Which of the following buffering systems would work best for a laboratory experiment requiring active papain at pH 6.5? What molar ratios of the compounds would you use to prepare the solution?


Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : IDLewisAcidBase (20 Variations)
Which of the following is a Lewis acid?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : ReactProductFavored (20 Variations)
You may want to use the following acid/base table to answer the question below.

Which of the following reactions will be product -favored?


Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : WeakStrongAcidPics (11 Variations)
Which diagram best represents an aqueous solution of HCl? (Water is not shown.)


Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : ChooseIndicator (8 Variations)

A 25.0 mL aliquot of a 1.44M solution of ammonia (Kb = 1.8 x 10-5) is titrated with 1.50M HCl. Use the Indicator Table below to decide which of the indicators listed would most accurately signal the equivalence point for this titration.

Write the letter corresponding to your choice of indicator in the box.


Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH
Acids_and_Bases : SolnGrams (20 Variations)
How many grams of sodium hydroxide (NaOH) must be dissolved in 510 ml of water to make a solution with a pH = 8.1?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH
Acids_and_Bases : ProtonTransferRxn (20 Variations)
Write an equation to describe the proton transfer that occurs when the following acid is added to water: HSO4-
Enter the products in the space below using the following as an example:
What ions are present in an aqueous calcium nitrate solution?
Ca(NO3)2(aq) Ca2+(aq) + 2NO3-(aq)
In this case, the answer would be: Ca2+(aq) + 2NO3-(aq)
You should enter: Ca^(2+) + 2NO3^(-)
In other words, use the ^ to indicate superscripts; put charges in parentheses; and leave a space on either side of the + sign. Your answer must be an exact match for the computer to grade it correctly, so be careful.

What products will result when HSO4- is added to water?

Acids / Bases |
Reactions |
Aqueous Solution Chemistry
AcidBaseProducts (10 variations)
The following acid/base table may be useful in answering the question below.

What products will result when HSO4- is added to water? Complete and balance the reaction below.

HSO4- + H2O ?


Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : AcidBaseProperties (10 Variations)
Which of the following are properties of HCl?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : AcidicOrBasicSalt (20 Variations)
When dissolved in an aqueous solution, which of the following salts will yield an acidic solution?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry
Acids_and_Bases : PercentDissociationKa (3 Variations)
Calculate the percent dissociation in a {x}M aqueous solution of the weak acid HA. (Ka = {y} x 10-4)

Enter your answer to ONE decimal place.
DO NOT use scientic notation.
DO NOT write in the units.


Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
Equilibrium
Radicals (9 Variations)
A collection of 9 assessment questions about Radicals
Addition Reactions |
Free Radicals |
Mechanisms of Reactions |
Reactions |
Aromatic Compounds
Substitution and Elimination (6 Variations)
A collection of 6 assessment questions about Substitution and Elimination
Mechanisms of Reactions |
Nucleophilic Substitution |
Elimination Reactions |
Carbocations |
Stereochemistry |
Alcohols |
Ethers
Kinetics : ConcVsTimeGraph (8 Variations)
The following graph shows the change in concentration as a function of time for the reaction:
2NO2(g) + F2(g) 2NO2F(g)
What do each of the curves A, B, and C represent?

Kinetics
Kinetics : CompareEnergyProfile (11 Variations)
Consider the following reactions that take place at the same temperature, begin with the same molar concentrations, and whose energy profiles are presented below:
Kinetics
Kinetics : FactorsAffectingRate (7 Variations)
Which of the following changes would NOT affect the rate of the reaction of cisplatin with water?
Pt(NH3)2Cl2(aq) + H2O(l) [Pt(NH3)2(H2O)Cl]+ + Cl-

Kinetics
Kinetics : RxnProfileEaDeltaE (11 Variations)
Based on the reaction profile, what is the energy change for the reaction?

Kinetics
Acids_and_Bases : TitrationCurveKaKb (8 Variations)
Study the graph of the titration of a weak acid with a strong base shown below. What is the approximate Ka for this acid?


Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis
Acids_and_Bases : PracticalAcidBase (20 Variations)
Which of the following statements is true?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
Physical Properties
Acids_and_Bases : WaterAutoIonization (20 Variations)
What effect will the addition of H2CO3 have on the autoionization of water?


Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
Water / Water Chemistry
Acids_and_Bases : WeakAcidSolnpH (20 Variations)
Given an aqueous solution of 0.30 M acetic acid (Ka = 1.8 x 10-5), the pH is approximately ...
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : BufferingCapacity (20 Variations)
If a buffer is prepared using 0.75 mol CH3COOH and 0.45 mol CH3COO- in 1 liter of aqueous solution, is the buffering capacity of the solution great enough to maintain its pH if 10 g NaOH is added?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : pHDilution (6 Variations)
What is the pH of a solution made by diluting {x} mL of {y} M HNO3(aq) to a total volume of 500 mL?

Enter your answer to two decimal places.
DO NOT use scientific notation

Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : pHBufferCalc (4 Variations)
Calculate the pH of a buffer solution containing {x}M NH3 and {y}M NH4NO3.

Enter your answer to TWO decimal places.
DO NOT use scientific notation.
DO NOT enter units
        eg:     4.55

Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : BufferWeakStrong (7 Variations)
How many mL of a 2.50 M HCl solution must be added to 500 mL of a 0.150 M CO32- solution to make a buffer with pH = 10.00?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : CalcSolnpH (5 Variations)
Use this acid/base table to answer the question below.

Calculate the pH of a {x}M sodium acetate solution.

DO NOT use scientific notation
Enter your answer to two decimal places.
DO NOT enter units

Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acids_and_Bases : BufferWeakWeak (14 Variations)
What mass of potassium bicarbonate (KHCO3) must be added to 500 mL of a 0.200 M carbonic acid solution to make a buffer with pH = 6.30?
Acids / Bases |
Reactions |
Aqueous Solution Chemistry |
pH |
Equilibrium
Acid Base (44 Variations)
A collection of 44 assessment questions about Acid Base
Acids / Bases |
Carboxylic Acids |
Alcohols |
Phenols |
Reactions |
Alkanes / Cycloalkanes |
Aldehydes / Ketones |
Esters |
Alkenes |
Alkynes |
Amines / Ammonium Compounds |
Ethers |
Lewis Acids / Bases |
Amides |
Amino Acids
Aromatic (26 Variations)
A collection of 26 assessment questions about Aromatic
Aromatic Compounds |
Nomenclature / Units / Symbols |
Reactions |
Electrophilic Substitution |
Mechanisms of Reactions |
Oxidation / Reduction |
Resonance Theory |
Addition Reactions |
Carbocations |
Synthesis
Alcohols and Ethers (22 Variations)
A collection of 22 assessment questions about Alcohols and Ethers
Alcohols |
Synthesis |
Oxidation / Reduction |
Aldehydes / Ketones |
Alkenes |
Carboxylic Acids |
Grignard Reagents |
Ethers |
Reactions |
Mechanisms of Reactions |
Organometallics |
Nomenclature / Units / Symbols |
Physical Properties
Amino Acids (10 Variations)
A collection of 10 assessment questions about Amino Acids
Amino Acids |
Stereochemistry |
Acids / Bases |
Amines / Ammonium Compounds |
Carboxylic Acids |
Nucleic Acids / DNA / RNA |
Proteins / Peptides |
Synthesis |
Aldehydes / Ketones
Carboxylic Acids (14 Variations)
A collection of 14 assessment questions about Carboxylic Acids
Carboxylic Acids |
Acids / Bases |
Esters |
Amides |
Reactions |
Synthesis |
Grignard Reagents |
Ethers |
Oxidation / Reduction |
Alkenes |
Heterocycles |
Amines / Ammonium Compounds |
Aldehydes / Ketones
Covalent Bonding (11 Variations)
A collection of 11 assessment questions about Covalent Bonding
Carboxylic Acids |
Acids / Bases |
Resonance Theory |
Covalent Bonding |
Phenols |
Amines / Ammonium Compounds |
Free Radicals |
Alkenes |
Amides |
Ethers
Phenols and Aryl Halides (9 Variations)
A collection of 9 assessment questions about Phenols and Aryl Halides
Phenols |
Acids / Bases |
Reactions |
Alcohols |
Amines / Ammonium Compounds |
Carboxylic Acids |
Aromatic Compounds |
Ethers |
Alkylation |
Synthesis |
Esters |
Electrophilic Substitution
Kinetics : Enzyme (7 Variations)
Trypsin assists in digestion by breaking proteins down into smaller peptides. However, this process is not as efficient in the presence of fluorophosphates. Identify the role of each of these components.
Enzymes |
Kinetics
Kinetics : ArrheniusRateConst (4 Variations)
CH3CH2NO2 C2H2 + HNO2

Using the graph below, calculate the rate constant for this reaction at 40.0oC.

Kinetics |
Chemometrics
Kinetics : CatalystTrueFalse (7 Variations)
Check the box for each statement about catalysts that is true.
Kinetics |
Catalysis
Kinetics : CatalyticConverters (4 Variations)
The following table illustrates the changes in emissions requirements for automobiles:
Pollutant1970 Emissions1990 EmissionsCA ultra-low emissions
CxHy1.5 g/mile0.25 g/mile0.04 g/mile
CO15 g/mile3.4 g/mile1.7 g/mile
NOx3.1 g/mile0.4 g/mile0.2 g/mile
Catalytic converters are used in automobiles to convert pollutants in engine emissions to benign products. Catalytic converters in today's automobiles are made of a porous ceramic brick that has been coated with catalysts, additives, stabilizers, and support materials. Corning has developed bricks that have very thin-walled channels with 600 channels per square inch. Which of the following research goals did they target?

Kinetics |
Catalysis
Equilibrium : EquilAndRxnRates (8 Variations)

For the reaction of A B, which of the following statements about the rates of forward and reverse reactions is true at time x?

Equilibrium |
Kinetics
Kinetics : ExpDataRateConst (16 Variations)
Use the experimental data below to determine the rate constant for the following reaction.



Kinetics |
Chemometrics
Amines (30 Variations)
A collection of 30 assessment questions about Amines
Amines / Ammonium Compounds |
Synthesis |
Acids / Bases |
Reactions |
Amides |
Electrophilic Substitution |
Stereochemistry |
Carboxylic Acids |
Oxidation / Reduction |
Aldehydes / Ketones |
Alkanes / Cycloalkanes |
Dyes / Pigments |
Grignard Reagents
Bonding (34 Variations)
A collection of 34 assessment questions about Bonding
Molecular Properties / Structure |
Covalent Bonding |
IR Spectroscopy |
VSEPR Theory |
Aromatic Compounds |
Lewis Structures |
Resonance Theory |
Aldehydes / Ketones |
Carboxylic Acids |
Acids / Bases
Organometallic (13 Variations)
A collection of 13 assessment questions about Organometallic
Organometallics |
Grignard Reagents |
Epoxides |
Alcohols |
Esters |
Alkanes / Cycloalkanes |
Aldehydes / Ketones |
Synthesis |
Ethers |
Aromatic Compounds |
Reactions |
Carboxylic Acids |
Alkenes |
Amines / Ammonium Compounds |
Acids / Bases |
Alkynes
Kinetics : RateConstantUnits (8 Variations)
The isomerization of CH3NC to CH3CN has a rate constant of 0.46 s-1 at 600 K.

(1) Based on the units of the rate constant, what is the order of the reaction? {1:MULTICHOICE:zero-order#No, that is not correct.~=first-order#Correct!~second-order#No, that is not correct.~third-order#No, that is not correct.}

(2) What is the concentration of CH3CN after 0.20 minutes of reaction if the initial concentration is 0.10 M? {1:NUMERICAL:=4e-4:1e-5#Correct!~%50%4e-4:5e-5#Close, but not quite.}(Do not include units!)


Kinetics |
Rate Law
Kinetics : RateLawChangeConc (10 Variations)
The rate law for a reaction is rate=k[A][B]. If the concentration of A doubles, the rate of the reaction will do which of the following?
Kinetics |
Rate Law
Kinetics : IntegratedRateLaw (6 Variations)
The following kinetics information may be useful in answering this problem.

Use the plots below to determine the order of the reaction with respect to A.




Kinetics |
Rate Law
Kinetics : InitialRateMethod (16 Variations)
Use the experimental data below to determine the rate equation for the following reaction.



Kinetics |
Chemometrics |
Rate Law
Kinetics : RxnOrder (10 Variations)
For the reaction below, determine the order with respect to each reactant and the overall order.
2NO2(g) + F2(g) 2NO2F(g)
rate = k[NO2][F2]

Kinetics |
Rate Law