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The Mechanism of the Ritter Reaction in Combination with Wagner-Meerwein Rearrangements. A Cooperative Learning ExperienceMaría I. Colombo, María L. Bohn, and Edmundo A. Rúveda Procedure in which students develop analytical and problem-solving skills by investigating an organic reaction mechanism, predicting the most likely products, and suggesting experiments to test the postulated mechanistic pathways and possible intermediates. Colombo, María I.; Bohn, María L.; Rúveda, Edmundo A. J. Chem. Educ.2002, 79, 484.
Mechanisms of Reactions |
Reactive Intermediates |
Amides |
Thin Layer Chromatography |
NMR Spectroscopy
An Unexpected Event When Chymotrypsin Performs Its Physiological RoleIvan G. Darvey One of the events that occur during the chymotrypsin-catalyzed hydrolysis of proteins is an example of an exception to a rule of thumb taught in introductory organic chemistry courses, namely, that amides can't readily be converted to esters. If biochemistry teachers and the authors of textbooks of biochemistry commented on this unusual reaction, it would emphasize further the remarkable part chymotrypsin plays as a catalyst in carrying out its main perceived "physiological role". Darvey, Ivan G. J. Chem. Educ.2000, 77, 422.
