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Carboxylic Acids and Derivatives Conductivity of carboxylic acids, pH of acetic acid derivatives, hydrophobic effect, and soap emulsions of hydrocarbons are demonstrated.
Developing Critical Thinking Skills: The "Sabotaged" Synthesis of Methyl p-BromobenzoateEric J. Mahan and Mary Alice Nading Before beginning an experiment, students are told that someone might have sabotaged their experiment to produce other-than-expected results. The objective is to perform the experiment, determine if any sabotage has occurred, and, if so, identify the changes that were made to the reagents as well as the person responsible. Mahan, Eric J.; Nading, Mary Alice. J. Chem. Educ.2006, 83, 1652.
Alcohols |
Carboxylic Acids |
Esters |
IR Spectroscopy |
NMR Spectroscopy |
Mass Spectrometry |
Synthesis
The Conversion of Carboxylic Acids to Ketones: A Repeated DiscoveryJohn W. Nicholson and Alan Wilson This article describes the history of the reaction converting carboxylic acids to ketones. The reaction has been rediscovered several times, yet has actually been known for centuries. Nicholson, John W.; Wilson, Alan. J. Chem. Educ.2004, 81, 1362.
Synthesis |
Carboxylic Acids |
Aldehydes / Ketones
Organic Acids without a Carboxylic Acid Functional GroupG. V. Perez and Alice L. Perez This paper presents several organic molecules that have been labeled as acids but do not contain a carboxylic acid functional group. Various chemical principles such as pKa, tautomerization, aromaticity, conformation, resonance, and induction are explored. Perez, G. V.; Perez, Alice L. J. Chem. Educ.2000, 77, 910.
