1.18. Nomenclature and Properties of Halogenated Alkanes
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Alkanes and Cycloalkanes The structures and conformations of alkanes and cycloalkanes and the vibrational, rotational, and translational motion of alkanes in the gas phase are demonstrated.
Alkanes / Cycloalkanes
Combustion of Methane Methane combustion in balloons, a Bunsen burner flame, and methane combustion in chlorine are demonstrated.
Alkanes / Cycloalkanes |
Reactions
Combustion of Hexane Combustion of hexane with limited oxygen and addition of water to burning hexane are demonstrated.
Entropy and the Shelf Model: A Quantum Physical Approach to a Physical PropertyArnd H. Jungermann A quantum physical approach relying on energy quantization leads to three simple rules which are the key to understanding the physical property described by molar entropy values. Jungermann, Arnd H. J. Chem. Educ.2006, 83, 1686.
Alcohols |
Alkanes / Cycloalkanes |
Carboxylic Acids |
Covalent Bonding |
Ionic Bonding |
Physical Properties |
Quantum Chemistry |
Thermodynamics
Semiempirical and DFT Investigations of the Dissociation of Alkyl HalidesJack R. Waas Enthalpy changes corresponding to the gas phase heats of dissociation of 12 organic halides were calculated using two semiempirical methods, the HartreeFock method, and two DFT methods. All five methods agreed generally with the expected empirically known trends in the dissociation of alkyl halides. Waas, Jack R. J. Chem. Educ.2006, 83, 1017.
Alkanes / Cycloalkanes |
Computational Chemistry |
Mechanisms of Reactions |
Molecular Modeling |
Reactions |
Reactive Intermediates |
Thermodynamics |
Elimination Reactions |
Nucleophilic Substitution
Further Analysis of Boiling Points of Small Molecules, CHwFxClyBrzGuy Beauchamp Multiple linear regression analysis has proven useful in selecting predictor variables that could significantly clarify the boiling point variation of the CHwFxClyBrz molecules. Beauchamp, Guy. J. Chem. Educ.2005, 82, 1842.
AlkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
CycloalkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
Hexane 1 (GCMP)David M. Whisnant Hexane 1: this is a resource in the collection "General Chemistry Multimedia Problems". Hexane, a liquid hydrocarbon with the formula C6H14, burns when ignited in the presence of oxygen. In this problem we will observe videos of this combustion reaction. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
