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Alkanes and Cycloalkanes The structures and conformations of alkanes and cycloalkanes and the vibrational, rotational, and translational motion of alkanes in the gas phase are demonstrated.
Study of Molecular-Shape Selectivity of Zeolites by Gas ChromatographyPei-Yu Chao, Yao-Yuan Chuang, Grace Hsiuying Ho, Shiow-Huey Chuang, Tseng-Chang Tsai, Chi-Young Lee, Shang-Tien Tsai, and Jun-Fu Huang This analytical or physical chemistry sorption experiment uses hexane isomers as probe molecules to demonstrate the "molecular-shape selectivity" behavior of zeolites. Students can also modify the sorption protocol to build their own experiments. Chao, Pei-Yu; Chuang, Yao-Yuan; Ho, Grace Hsiuying; Chuang, Shiow-Huey; Tsai, Tseng-Chang; Lee, Chi-Young; Tsai, Shang-Tien; Huang, Jun-Fu. J. Chem. Educ.2008, 85, 1558.
Alkanes / Cycloalkanes |
Constitutional Isomers |
Gas Chromatography |
Molecular Properties / Structure |
Physical Properties |
Separation Science |
Solid State Chemistry |
Molecular Recognition
A Set of Hands-On Exercises on Conformational AnalysisSilvina C. Pellegrinet and Ernesto G. Mata This article describes a set of comprehensive exercises on conformational analysis that employs a hands-on approach by the use of molecular modeling kits. In addition, the exercises provide illustrations of other topics such as nomenclature, functional groups, and isomerism, and introduce some notions of chirality. Pellegrinet, Silvina C.; Mata, Ernesto G. J. Chem. Educ.2005, 82, 73.
Alkanes / Cycloalkanes |
Conformational Analysis |
Constitutional Isomers |
Molecular Properties / Structure |
Stereochemistry
Using Hydrocarbon Acidities To Demonstrate Principles of Organic Structure and BondingAndrew P. Dicks This article demonstrates the utility of hydrocarbon acidity as a teaching tool within the undergraduate classroom. Acidities of compounds containing only hydrogen and carbon vary by at least 50 orders of magnitude. Differences in acidities are rationalized by invoking principles of hybridization, resonance, induction, and aromaticity. Dicks, Andrew P. J. Chem. Educ.2003, 80, 1322.
ChemPaths 104 F Jan 21John W. Moore Today in Chem 104:
* Lecture: Organic Structures; Isomers
* Reading:
Kotz Ch. 10, Sec. 1-2; Appendix E (pp. A-17-20)
Moore Ch. 3: Sec. 3-4; Ch. 8: Sec. 3, 5; App E (pp. A.26-A.30)
* Practice Quiz and Homework #1 are due by 11:55 pm M Jan 24.
Alkanes / Cycloalkanes |
Constitutional Isomers
CycloalkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkanes / Cycloalkanes
AlkanesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
