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Synthesis and Spectroscopic Analysis of a Cyclic Acetal: A Dehydration Performed in Aqueous SolutionDavid M. Collard, Adolphus G. Jones, and Robert M. Kriegel Treatment of pentaerythritol with benzaldehyde in aqueous acid to produce the monoacetal, 5,5-bis(hydroxymethyl)-2-phenyl-1,3-dioxane. The reaction has a number of interesting features: the isolated product is the monobenzal not the dibenzal, and the reaction, a dehydration, is performed in water. Collard, David M.; Jones, Adolphus G.; Kriegel, Robert M. J. Chem. Educ.2001, 78, 70.
NMR Spectroscopy |
Synthesis |
Aldehydes / Ketones |
Alcohols
Formaldehyde: A simple compound with many uses.Seymour, Raymond B.; Kauffman, George B. Properties, chemistry, and uses of formaldehyde. Seymour, Raymond B.; Kauffman, George B. J. Chem. Educ.1992, 69, 457.
Aldehydes / Ketones |
Applications of Chemistry |
Polymerization |
Physical Properties
A source of isomer-drawing assignmentsKjonaas, Richard A. A comprehensive source from which instructors can choose a wide variety of good isomer drawing examples to use as homework assignments and exam questions. Kjonaas, Richard A. J. Chem. Educ.1992, 69, 452.