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Diels-Alder Visualization Several computer animations of a Diels-Alder reaction that were created as an undergraduate student project are presented.
Addition Reactions |
Alkenes
Addition Reactions of Alkenes The Diels-Alder reaction, addition of oxygen to tetrakis(N, N-dimethylamino) ethylene, polymerization of ethylene, and addition of iodine to a-pinene are demonstrated. Molecular models of ethene are shown.
Was Markovnikov's Rule an Inspired Guess?Peter Hughes A study of 19th century literature shows that neither Markovnikov nor any of his contemporaries carried out the reactions often attributed to himthe addition of hydrogen bromide or hydrogen chloride to propene. Since there is little evidence for Markovnikov's rule in his 1870 article, it is likely that it was more of an inspired guess than a rational conclusion. Hughes, Peter. J. Chem. Educ.2006, 83, 1152.
Addition Reactions |
Alkenes |
Mechanisms of Reactions
The electrophilic addition to alkynesWeiss, Hilton M. Electrophilic additions to alkynes traditionally do not receive as much attention in organic textbooks as electrophilic addition to alkenes. Weiss, Hilton M. J. Chem. Educ.1993, 70, 873.