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Reactions : WillSolnConduct (5 Variations) One gram of each of the following compounds is mixed with 100mL of water. Which will form solutions that will conduct electricity?
Dynamic Reaction Figures: An Integrative Vehicle for Understanding Chemical ReactionsEmeric Schultz Describes the dynamic reaction figure, a flexible learning tool that can be used to balance chemical equations, predict the results of potential reactions, present the underlying mechanism of reactions, and solve quantitative problems in a number of areas. Schultz, Emeric. J. Chem. Educ.2008, 85, 386.
Acids / Bases |
Aqueous Solution Chemistry |
Mechanisms of Reactions |
Nonmajor Courses
Investigating Students' Ability To Transfer Ideas Learned from Molecular Animations of the Dissolution ProcessResa M. Kelly and Loretta L. Jones This study examines what features of the particulate nature of matter learned from viewing two animations of sodium chloride dissolution students would transfer to their descriptions of the participation of aqueous sodium chloride in a chemical reaction. Kelly, Resa M.; Jones, Loretta L. J. Chem. Educ.2008, 85, 303.
Aqueous Solution Chemistry |
Precipitation / Solubility |
Solutions / Solvents |
Constructivism
Determining the Solubility Product of Fe(OH)3: An Equilibrium Study with Environmental SignificanceMichelle Meighan, Joseph MacNeil, and Renee Falconer This study explores the environmental impact of acidic mine drainage by investigating the relationship between pH and the aqueous solubility of heavy metals. Students precipitate Fe(OH)3 from acidic FeCl3 and NaOH and use the concentrations of ferric and hydroxide ionsdetermined through pH and flame spectroscopyto calculate the Ksp of Fe(OH)3. Meighan, Michelle; MacNeil, Joseph; Falconer, Renee. J. Chem. Educ.2008, 85, 254.
Molecular Models of EDTA and Other Chelating AgentsWilliam F. Coleman Deirdre Bell-Oudry presents a variation on an old theme in her paper on using an indirect EDTA titration for sulfate analysis (1). EDTA and (often loosely) related species are this month's Featured Molecules.EDTA is a hexaprotic acid (H6Y2+) having the pKa values given in the featured paper (1). Figure 1 shows a distribution diagram for the EDTA system (2). At the pH of normal waters, the predominant species have one or both of the nitrogen atoms protonated.Complexation, however, requires that both nitrogens be deprotonated and it is generally assumed that the form that complexes with metal ions is Y4−. Structures of several forms of EDTA are included in the molecule collection (Figure 2). These structures are quite flexible having many conformations that are readily accessible at room temperature.An introduction to EDTA chemistry leads to broader questions of metal ion chelation or sequestration. Related chelating agents included in the molecule collection are EGTA, DCTA, NTA, BAPTA, and DTPA. Molecular dynamics and Hartree-Fock calculations on BAPTA (Figure 2) confirm that many conformations, ranging from those with the phenyl rings parallel to one another, to more elongated forms, are essentially isoenergetic in room temperature aqueous solution (3).Also included in the molecule collection are several crown ethers, an isophore (nonactin), and a cryptand. These not only provide students with a glimpse of the types of molecules being employed for metal ion sequestration but open a wide range of topics of current research in a variety of areas of inorganic, industrial, environmental, and biological chemistry.
Aqueous Solution Chemistry
Hydration of IonsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Aqueous Solution Chemistry
Conjugate Acid-Base Pairs and pHEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
AgCl (s) + HNO3(aq) 
