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A Kool Reaction from the Fine Print Susan A. S. Hershberger and Arlyne M. Sarquis Students investigate the reduction of artificial food dyes by citric acid-promoted oxidation of a metal in the form of fine or coarse steel wool. The artificial red and yellow food dyes present in drink mixes contain azo linkages (nitrogennitrogen double bonds) that are readily reduced to colorless products under mild reducing conditions. Hershberger, Susan A. S.; Sarquis, Arlyne M. J. Chem. Educ. 2006, 83, 1792A.
Acids / Bases |
Consumer Chemistry |
Descriptive Chemistry |
Dyes / Pigments |
Food Science |
Oxidation / Reduction |
Reactions
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Predicting Inorganic Reaction Products: A Critical Thinking Exercise in General Chemistry David G. DeWit Describes a course module designed to afford practice in applying the principles encountered throughout the general chemistry sequence to understanding and predicting chemical reactivity and the products of simple inorganic reactions. DeWit, David G. J. Chem. Educ. 2006, 83, 1625.
Acids / Bases |
Descriptive Chemistry |
Learning Theories |
Metals |
Nonmetals |
Oxidation / Reduction |
Periodicity / Periodic Table |
Reactions
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Laboratory Experiments on the Electrochemical Remediation of the Environment. Part 7: Microscale Production of Ozone Jorge G. Ibanez, Rodrigo Mayen-Mondragon, M. T. Moran-Moran, Alejandro Alatorre-Ordaz, Bruce Mattson, and Scot Eskestrand Ozone, a powerful oxidizing and disinfecting agent, is produced electrochemically in the undergraduate laboratory with simple equipment and under very mild conditions. Tests are given to characterize it, to observe its action in simulated environmental applications, and to measure its rate of production. Ibanez, Jorge G.; Mayen-Mondragon, Rodrigo; Moran-Moran, M. T.; Alatorre-Ordaz, Alejandro; Mattson, Bruce; Eskestrand, Scot. J. Chem. Educ. 2005, 82, 1546.
Aqueous Solution Chemistry |
Descriptive Chemistry |
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials |
Laboratory Equipment / Apparatus |
Microscale Lab |
Oxidation / Reduction |
Reactions
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Mass Relationships in a Chemical Reaction: Incorporating Additional Graphing Exercises into the Introductory Chemistry Laboratory Stephen DeMeo The purpose of this article is to increase student involvement with graph construction specifically in the context of introductory laboratory activities that involve mass relationships between reacting substances and products. In this regard, five massmass plots derived from a synthesis of a binary compound from its elements are presented as well as a set of questions to focus learners on the significance of each plot. The benefit of providing learners with these types of graphing activities include the use of higher-order cognitive processes as well as the elucidation of fundamental chemical knowledge such as the law of the conservation of mass, the law of constant composition, limiting and excess reactants, and empirical formula. DeMeo, Stephen. J. Chem. Educ. 2005, 82, 1219.
Stoichiometry |
Oxidation / Reduction |
Reactions |
Quantitative Analysis
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Kinetics of Alcohol Dehydrogenase-Catalyzed Oxidation of Ethanol Followed by Visible Spectroscopy Kestutis Bendinskas, Christopher DiJiacomo, Allison Krill, and Ed Vitz A two-week biochemistry experiment was introduced in the second-semester general chemistry laboratory to study the oxidation of ethanol in vitro in the presence of the enzyme alcohol dehydrogenase (ADH). This reaction should pique student interest because the same reaction also occurs in human bodies when alcoholic drinks are consumed. Procedures were developed to follow the biochemical reaction by visible spectroscopy and to avoid specialized equipment. The effect of substrate concentration on the rate of this enzymatic reaction was investigated during the first week. The effects of temperature, pH, the specificity of the enzyme to several substrates, and the enzyme's inhibition by heavy metals were explored during the second week. Bendinskas, Kestutis; DiJiacomo, Christopher; Krill, Allison; Vitz, Ed. J. Chem. Educ. 2005, 82, 1068.
Enzymes |
Kinetics |
Oxidation / Reduction |
Reactions |
UV-Vis Spectroscopy |
Alcohols |
Biophysical Chemistry |
Food Science
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Conceptual Considerations in Molecular Science Donald T. Sawyer The undergraduate curriculum and associated textbooks include several significant misconceptions. Sawyer, Donald T. J. Chem. Educ. 2005, 82, 985.
Catalysis |
Covalent Bonding |
Electrolytic / Galvanic Cells / Potentials |
Oxidation / Reduction |
Reactions |
Reactive Intermediates |
Thermodynamics |
Water / Water Chemistry
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Procedure for Decomposing a Redox Reaction into Half-Reactions Ilie Fishtik and Ladislav H. Berka The principle of stoichiometric uniqueness provides a simple algorithm to check whether a simple redox reaction may be uniquely decomposed into half-reactions in a single way. For complex redox reactions the approach permits a complete enumeration of a finite and unique number of ways a redox reaction may be decomposed into half-reactions. Several examples are given. Fishtik, Ilie; Berka, Ladislav H. J. Chem. Educ. 2005, 82, 553.
Stoichiometry |
Equilibrium |
Electrochemistry |
Oxidation / Reduction |
Reactions |
Thermodynamics
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The Determination of the Percent of Oxygen in Air Using a Gas Pressure Sensor James Gordon and Katherine Chancey A new detection method is applied to a classic experiment in which gaseous atmospheric oxygen in a test tube is reacted with the iron in steel wool to produce rust. A gas pressure sensor interfaced to a calculator-based data collection system was used to measure the percent of oxygen in the air as the reaction proceeded. The results from the calculator-based experiment were compared to the results from a more traditional water-measurement experiment. The average percent of oxygen obtained using the calculator system was 19.4 0.4%. Gordon, James; Chancey, Katherine. J. Chem. Educ. 2005, 82, 286.
Atmospheric Chemistry |
Gases |
Oxidation / Reduction |
Reactions
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A Methane Balloon Inflation Chamber Curtis J. Czerwinski and Tanya J. Cordes While several lecture demonstrations are possible using methane-filled balloons, it is often inconvenient to prepare these balloons since the pressure from standard laboratory and lecture hall gas nozzles is too low. As a solution to this problem, a methane balloon inflation chamber, prepared from a translucent 3.5-gallon pail and an aspirator or house-vacuum, provides an inexpensive and convenient method for inflating balloons in laboratories or lecture halls. Prepared in this way, methane-filled balloons can be used to demonstrate the effects of vacuum, the lifting power of low-density gases, and the explosive combustion of methane. Czerwinski, Curtis J.; Cordes, Tanya J. J. Chem. Educ. 2005, 82, 248.
Alkanes / Cycloalkanes |
Calorimetry / Thermochemistry |
Gases |
Oxidation / Reduction |
Reactions
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Old Nassau Demonstration with Wilkinson Modification Lawrence E. Wilkinson A modification of the Old Nassau Reaction demonstration is presented, wherein a 0.025 M silver nitrate solution is used in place of the mercury(II) chloride solution employed in the original demonstration. Wilkinson, Lawrence E. J. Chem. Educ. 2004, 81, 1474.
Aqueous Solution Chemistry |
Kinetics |
Oxidation / Reduction |
Reactions
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A Reaction That Takes Place in Beakers but Not in Conical Flasks: A Catalysis-Related Demonstration Colin White A striking demonstration emphasizing that substances which promote reactions are not catalysts if they are consumed in the process. The demonstration is based on the iron(II) induced oxidation of iodide by chromium(VI). White, Colin. J. Chem. Educ. 2004, 81, 364.
Catalysis |
Oxidation / Reduction |
Reactions
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Incomplete Combustion with Candle Flames: A Guided-Inquiry Experiment in the First-Year Chemistry Lab Joseph MacNeil and Lisa Volaric Investigating a burning candle as an introduction to incomplete combustion, thermodynamics, kinetics, and gas chromatography. MacNeil, Joseph; Volaric, Lisa. J. Chem. Educ. 2003, 80, 302.
Chromatography |
Gases |
Reactions |
Oxidation / Reduction |
Thermodynamics |
Kinetics |
Gas Chromatography
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Tick Tock, a Vitamin C Clock Stephen W. Wright Uses supermarket chemicals to perform a clock reaction; students vary the concentration of reactants and observe the effect on the time required for the reaction to reach its endpoint. Wright, Stephen W. J. Chem. Educ. 2002, 79, 40A.
Consumer Chemistry |
Oxidation / Reduction |
Vitamins |
Equilibrium |
Mechanisms of Reactions
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Redox Redux: Recommendations for Improving Textbook and IUPAC Definitions Ed Vitz Defining oxidation / reduction reactions as those in which oxidation states of the reactant(s) change. Vitz, Ed. J. Chem. Educ. 2002, 79, 397.
Electrochemistry |
Mechanisms of Reactions |
Oxidation / Reduction |
Oxidation State
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Teaching about Flame Retardants. A Joint Israeli-Dutch Project Miri Kesner and Wobbe de Vos Flame retardants make interesting chemistry and moreover, the chemistry is highly relevant from an everyday life point of view. This article reports on a joint Israeli-Dutch project aimed at teaching the production, properties, and applications of some bromine-containing flame retardants, including their environmental aspects, in secondary education. Kesner, Miri; de Vos, Wobbe. J. Chem. Educ. 2001, 78, 41.
Industrial Chemistry |
Oxidation / Reduction |
Reactions |
Applications of Chemistry
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Combustion Demonstration Using Updated Flame Tornado Edward G. Senkbeil This demonstration uses the combustion of different forms of cellulose and an updated version of the "flame tornado" as an ignition source to illustrate the factors affecting the combustion process. The objectives of the experiment are to illustrate the factors affecting the rate of a combustion reaction and to demonstrate the factors affecting the production of a flame by using the flame tornado. Senkbeil, Edward G. J. Chem. Educ. 2000, 77, 1449.
Descriptive Chemistry |
Oxidation / Reduction |
Reactions |
Rate Law
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Catalytic Oxidation of Ammonia: A Sparkling Experiment Vladimir A. Volkovich and Trevor R. Griffiths A lecture demonstration experiment on the catalytic oxidation of ammonia using chromium(III) oxide as a catalyst is described. Volkovich, Vladimir A.; Griffiths, Trevor R. J. Chem. Educ. 2000, 77, 177.
Catalysis |
Oxidation / Reduction |
Reactions
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The Methane Balloon Walter H. Corkern and Elvin Hughes Jr. The objectives are (i) to describe a novel method of inflating a balloon with methane, (ii) to show that methane is lighter than air, and (iii) to demonstrate the flammability of methane. Corkern, Walter H.; Hughes, Elvin, Jr. J. Chem. Educ. 1999, 76, 794.
Gases |
Oxidation / Reduction |
Reactions
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Microscale Thermite Reactions Francisco J. Arnáiz, Rafael Aguado, and Susana Arnáiz The reaction of aluminum with the oxides of a variety of elements illustrates exothermic reactions that require a high activation energy. It is also an appropriate experiment with regard to the discussion of Ellingham diagrams. When drama is not the main objective, conducting these reactions at microscale level offers numerous advantages over the usual scale. Arnáiz, Francisco J.; Aguado, Rafael; Arnáiz, Susana. J. Chem. Educ. 1998, 75, 1630.
Microscale Lab |
Reactions |
Oxidation / Reduction
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Slide Projector Corrosion Cell Silvia Tejada, Estela Guevara, and Esperanza Olivares The process of corrosion can be demonstrated in a slide projector, since the cell is in the shape of a slide, or on the stage of an overhead projector by setting up a simple galvanic cell. Corrosion occurs as the result of a galvanic cell reaction, in which the corroding metal acts as the anode. Several simple demonstrations relating to corrosion are described here. Tejada, Silvia; Guevara, Estela; Olivares, Esperanza. J. Chem. Educ. 1998, 75, 747.
Electrochemistry |
Microscale Lab |
Oxidation / Reduction |
Reactions |
Electrolytic / Galvanic Cells / Potentials |
Applications of Chemistry
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Chemical Domino Demonstration M. Dale Alexander The Chemical Domino Demonstration is both educational and entertaining. It provides an excellent means for a review of chemical concepts at the conclusion of a general chemistry course. This demonstration consists of a number of different chemical reactions occurring in sequence in a Rube Goldberg-type apparatus. M. Dale Alexander. J. Chem. Educ. 1998, 75, 490.
Reactions |
Acids / Bases |
Oxidation / Reduction
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Letter to the Editor about Letter to the Editor "Redox Challenges" from David M. Hart and Response from Roland Stout (J. Chem. Educ. 1996, 73, A226-7) Andrzej Sobkowiak Examples of a variety of redox equations. Sobkowiak, Andrzej. J. Chem. Educ. 1997, 74, 1256.
Stoichiometry |
Reactions |
Oxidation / Reduction
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Redox Challenges: Good Times for Puzzle Fanatics Roland Stout Three difficult to balance redox equations. Stout, Roland. J. Chem. Educ. 1995, 72, 1125.
Reactions |
Stoichiometry |
Oxidation / Reduction |
Enrichment / Review Materials
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Fe(s) + Cu(II)(aq) ----> Fe(II)(aq) + Cu(s): Fifteen Centuries of Search Vladimir Karpenko Historical development of understanding of the title reaction, particularly erroneous alchemical beliefs. Karpenko, Vladimir. J. Chem. Educ. 1995, 72, 1095.
Metals |
Enrichment / Review Materials |
Reactions |
Oxidation / Reduction
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Making Sparklers: An Introductory Laboratory Experiment Allen Keeney, Christina Walters, and Richard D. Cornelius Method for producing sparklers to illustrate redox reactions. Keeney, Allen; Walters, Christina; Cornelius, Richard D. J. Chem. Educ. 1995, 72, 652.
Oxidation / Reduction |
Reactions |
Metals
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Resistance Measurement as a Tool for Corrosion Studies Singh, N. P.; Gupta, S. C.; Sood, B. R. Procedure for determining the rate of corrosion by measuring changes in the resistance of a thin wire or strip of metal; sample data and analysis included. Singh, N. P.; Gupta, S. C.; Sood, B. R. J. Chem. Educ. 1995, 72, 465.
Oxidation / Reduction |
Metals |
Rate Law |
Reactions |
Electrochemistry
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Pyrotechnic Reactions Without Oxygen Wright, Stephen W. Reaction of K3FeF6 with Al and poly(tetrafluoroethylene) with Mg. Wright, Stephen W. J. Chem. Educ. 1994, 71, 251.
Oxidation / Reduction |
Reactions
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Is This Reaction a Substitution, Oxidation-Reduction, or Transfer? Imyanitov, Naum S. Author argues that separation of chemical reaction types based on convention do not always follow objective and consistent rules. This leads to confusion among students and artificial borders within the various sub-disciplines in chemistry. Imyanitov, Naum S. J. Chem. Educ. 1993, 70, 14.
Reactions |
Oxidation / Reduction
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Gas reactions in plastic bags: Relating laboratory observations to the atomic-molecular model Robinson, Maurice; Barrow, Gordon M. Carrying out chemical reactions in Ziplock bags to investigate a variety of chemical concepts. Robinson, Maurice; Barrow, Gordon M. J. Chem. Educ. 1992, 69, 1026.
Kinetic-Molecular Theory |
Gases |
Reactions |
Acids / Bases |
Oxidation / Reduction |
Photochemistry |
Atmospheric Chemistry |
Physical Properties
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The bird-scarer (combustion) demo Battino, Rubin; Arehart, James D.; Foot, Neville W.; Stott, James B. This is a demonstration version of a device used to scare birds with loud noises occurring at regular intervals. Battino, Rubin; Arehart, James D.; Foot, Neville W.; Stott, James B. J. Chem. Educ. 1992, 69, 64.
Reactions |
Oxidation / Reduction
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Recovery of silver from and some uses for waste silver chloride Murphy, J. A.; Ackerman, A. H.; Heeren, J. K. Procedures for conversion to silver nitrate, using waste AgCl as an oxidizing agent, and electrodepositon experiments. Murphy, J. A.; Ackerman, A. H.; Heeren, J. K. J. Chem. Educ. 1991, 68, 602.
Reactions |
Oxidation / Reduction |
Electrochemistry
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In praise of copper Tykodi, R. J. The reactions of copper make impressive lecture demonstrations and worthwhile laboratory activities. Tykodi, R. J. J. Chem. Educ. 1991, 68, 106.
Reactions |
Oxidation / Reduction
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A bromate clock reaction: The formation of purple tris(diphosphato)manganate(III) Rich, Ronald L.; Noyes, Richard M. Bromate is used to oxidize nearly colorless Mn(II) to a deep purple complex of Mn(III). Rich, Ronald L.; Noyes, Richard M. J. Chem. Educ. 1990, 67, 606.
Reactions |
Oxidation / Reduction |
Kinetics
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Chemical Reactions, Reactions in Aqueous Solution, and Oxidation Reduction Reactions, Review II (Weyh, J. A.; Crook, J. R.; Hauge, L. N.) Coleman, William F. Programs intended to provide students with drill and practice in equation writing (including formula writing), equation balancing, and reaction predicting. Coleman, William F. J. Chem. Educ. 1989, 66, A172.
Reactions |
Aqueous Solution Chemistry |
Oxidation / Reduction |
Enrichment / Review Materials
|
Chemical Reactions, Reactions in Aqueous Solution, and Oxidation Reduction Reactions, Review I (Weyh, J. A.; Crook, J. R.; Hauge, L. N.) Balahura, Robert J. Programs intended to provide students with drill and practice in equation writing (including formula writing), equation balancing, and reaction predicting. Balahura, Robert J. J. Chem. Educ. 1989, 66, A172.
Reactions |
Aqueous Solution Chemistry |
Oxidation / Reduction |
Enrichment / Review Materials
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Preparation of lead compounds: An exercise in applied chemistry Laing, Michael; Williams-Wynn, David; Suhramoney, Saroj Uses and synthesis of Pb(NO3)2, PbO2, PbCrO4, PbS, PbO, lead carbonate, lead acetate, and lead metal itself. Laing, Michael; Williams-Wynn, David; Suhramoney, Saroj J. Chem. Educ. 1987, 64, 811.
Synthesis |
Metals |
Oxidation / Reduction |
Oxidation State |
Reactions |
Descriptive Chemistry
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Introduction to overhead projector demonstrations Kolb, Doris General suggestions for using the overhead projector and 21 demonstrations. [Debut] Kolb, Doris J. Chem. Educ. 1987, 64, 348.
Rate Law |
Reactions |
Catalysis |
Equilibrium |
Transition Elements |
Metals |
Oxidation / Reduction |
Acids / Bases
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Annotating reaction equations Tykodi, R. J. Annotating aqueous solution reactions fosters recognition of the fundamental reaction categories; ready recognition of a reaction type is the first step toward understanding the "whys and wherefores" inherent in the reaction. Tykodi, R. J. J. Chem. Educ. 1987, 64, 243.
Aqueous Solution Chemistry |
Reactions |
Acids / Bases |
Gases |
Precipitation / Solubility |
Oxidation / Reduction
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New stoichiometry for copper dissolution in nitric acid El-Cheikh, F. M.; Khalil, S. A.; El-Manguch, M. A.; Omar, Hadi A. NO2 does not appear to be a primary product in the oxidation of copper metal by nitric acid. El-Cheikh, F. M.; Khalil, S. A.; El-Manguch, M. A.; Omar, Hadi A. J. Chem. Educ. 1985, 62, 761.
Reactions |
Stoichiometry |
Oxidation / Reduction
|
Iodine clock reaction mechanisms Lambert, Jack L.; Fina, Gary T. Outlines the mechanism for the simple iodine clock reaction and the "Old Nassau" modification. Lambert, Jack L.; Fina, Gary T. J. Chem. Educ. 1984, 61, 1037.
Mechanisms of Reactions |
Reactions |
Kinetics |
Oxidation / Reduction
|
How to get the most from the dichromate volcano demonstration: Aluminothermy Trogler, William C. Reducing the green ash produced by the dichromate volcano (Cr2O3) with aluminum in a thermite-like display. Trogler, William C. J. Chem. Educ. 1984, 61, 908.
Reactions |
Oxidation / Reduction
|
Indigo Fernelius, W. Conard; Renfrew, Edgar E. A brief history of the uses and origins of indigo as well as a look at the molecular structure of this molecule. Fernelius, W. Conard; Renfrew, Edgar E. J. Chem. Educ. 1983, 60, 633.
Dyes / Pigments |
Heterocycles |
Oxidation / Reduction |
Reactions
|
Spontaneous combustion of familiar substances in chlorine Briggs, Thomas S. Reacting chlorine generated from liquid bleach with red phosphorus (from a match book) and iron from steel wool. Briggs, Thomas S. J. Chem. Educ. 1982, 59, 788.
Reactions |
Oxidation / Reduction
|
A unified approach to the study of chemical reactions in freshman chemistry Cassen, T.; DuBois, Thomas D. An approach that aims to provide students with the background that will enable them to make reasonable predictions as to the likely products of a chemical reaction. Cassen, T.; DuBois, Thomas D. J. Chem. Educ. 1982, 59, 377.
Reactions |
Atomic Properties / Structure |
Oxidation State |
Oxidation / Reduction |
Aqueous Solution Chemistry |
Periodicity / Periodic Table
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The thermite lecture demonstration Bozzelli, Joseph W.; Barat, Robert B. Glycerine plus KMnO4 are used to ignite the thermite in a clay flower pot. Bozzelli, Joseph W.; Barat, Robert B. J. Chem. Educ. 1979, 56, 675.
Reactions |
Oxidation / Reduction
|
Acid-base half-reactions - A useful formalism for review lessons Atkinson, G. F. An effective way to draw analogies between acid-base and redox effects while reviewing both. Atkinson, G. F. J. Chem. Educ. 1979, 56, 238.
Oxidation / Reduction |
Reactions |
Acids / Bases |
Enrichment / Review Materials
|
The burning sugar cube Smith, Douglas D. A wide range of powdered solids can be used to produce a burning sugar cube. Smith, Douglas D. J. Chem. Educ. 1977, 54, 552.
Carbohydrates |
Oxidation / Reduction |
Reactions |
Catalysis
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Singlet oxygen in aqueous solution: A lecture demonstration Shakhashiri, Bassam Z.; Williams, Lloyd G. Lecture demonstrations involving chemiluminescence are useful for the purpose both of displaying chemical phenomena and of illustrating specific principles. Shakhashiri, Bassam Z.; Williams, Lloyd G. J. Chem. Educ. 1976, 53, 358.
Photochemistry |
Reactions |
Oxidation / Reduction |
Spectroscopy
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A simple general chemistry kinetics experiment Gellender, Martin The oxidation of iodide ion by persulfate provides a gradual and clearly distinguishable appearance of color as the reaction proceeds. Gellender, Martin J. Chem. Educ. 1975, 52, 806.
Kinetics |
Rate Law |
Reactions |
Oxidation / Reduction
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Conversion of black and white prints to color in daylight. A demonstration lecture for general and organic courses Wheeler, Thomas N. A black and white print is converted to a full color print with the lights on; includes a detailed discussion of the chemical processes involved in the demonstration. Wheeler, Thomas N. J. Chem. Educ. 1975, 52, 607.
Photochemistry |
Reactions |
Consumer Chemistry |
Dyes / Pigments |
Oxidation / Reduction
|
What is oxidation? Herron, J. Dudley Why do most teachers continue to define oxidation and reduction in terms of a gain and loss of electrons rather than in terms of a change in oxidation number? [Debut] Herron, J. Dudley J. Chem. Educ. 1975, 52, 51.
Oxidation / Reduction |
Oxidation / Reduction |
Atomic Properties / Structure |
Reactions
|
Properties of air-A freshman chemistry lecture demonstration Schultz, C. W. A simple yet dramatic lecture demonstration can help tie together concepts of oxygen chemistry, combustion, gas properties and rates of reactions. Schultz, C. W. J. Chem. Educ. 1974, 51, 751.
Oxidation / Reduction |
Reactions |
Gases
|
The octane cannon experiment updated for television Richtol, H. H.; Nelson, D. L.; Reeves, R. R. Video recording the detonation of octane in a clear tube for frame-by-frame analysis of a rapid reaction. Richtol, H. H.; Nelson, D. L.; Reeves, R. R. J. Chem. Educ. 1973, 50, 856.
Alkanes / Cycloalkanes |
Reactions |
Oxidation / Reduction
|
Some reactions of tungsten: A lecture demonstration Nelson, D. L.; Reeves, R. R.; Richtol, H. H. Several demonstrations involving reactions of tungsten. Nelson, D. L.; Reeves, R. R.; Richtol, H. H. J. Chem. Educ. 1973, 50, 810.
Metals |
Reactions |
Oxidation / Reduction
|
The reduction of CuO with burner gas and without a fume hood. A high school chemistry experiment Zidick, Clem; Weismann, Thomas This experiment is a modification of the classic reduction of CuO with hydrogen gas, except natural gas is used as the reducing agent, eliminating the danger of working with hydrogen. Zidick, Clem; Weismann, Thomas J. Chem. Educ. 1973, 50, 717.
Oxidation / Reduction |
Reactions |
Stoichiometry
|
The reducing property of ammonia Long, Robert H. Heating black copper (II) oxide with ammonium carbonate yields metallic copper, red copper (I) oxide, and water. Long, Robert H. J. Chem. Educ. 1972, 49, A85.
Oxidation / Reduction |
Reactions
|
When your car rusts out Knockemus, Ward Explains the rusting of a car by considering electrochemical corrosion and the Nernst equation. Knockemus, Ward J. Chem. Educ. 1972, 49, 29.
Electrochemistry |
Oxidation / Reduction |
Applications of Chemistry |
Reactions
|
A color indicating time reaction Chen, Philip S. Combining solutions of sodium thoisulfate and ferric chloride produces a dramatic color change. Chen, Philip S. J. Chem. Educ. 1970, 47, A784.
Reactions |
Oxidation / Reduction |
Aqueous Solution Chemistry
|
Demonstration notes: Spontaneous combustion Johnson, Joseph E. Modifications or additions to previously published demonstration. Johnson, Joseph E. J. Chem. Educ. 1970, 47, A439.
Oxidation / Reduction |
Reactions |
Gases |
Transport Properties |
Coordination Compounds
|
Miscellaneous Alyea, Hubert N. These twelve overhead projection demonstrations include rates of reactions, clock reactions, the effect of temperature and the presence of a catalyst on the decomposition of hydrogen peroxide, the relationship between viscosity and temperature, equilibria, solubility product, and the common ion effect. Alyea, Hubert N. J. Chem. Educ. 1970, 47, A437.
Oxidation / Reduction |
Kinetics |
Rate Law |
Reactions |
Acids / Bases |
Catalysis |
Equilibrium |
Precipitation / Solubility
|
Miscellaneous Alyea, Hubert N. 13 demonstrations, including electrophoresis, electrolysis, corrosion inhibition, endothermic and exothermic reactions, crystals and crystallization, reactions with sodium, and the kinetics of H2O2 decomposition. Alyea, Hubert N. J. Chem. Educ. 1970, 47, A387.
Electrophoresis |
Dyes / Pigments |
Electrochemistry |
Oxidation / Reduction |
Calorimetry / Thermochemistry |
Phases / Phase Transitions / Diagrams |
Reactions |
Crystals / Crystallography |
Kinetics
|
Catalysis demonstrations with Cr2O3 Briggs, Thomas S. Cr2O3 is used as a catalyst in the oxidation of nonflammable substances such as glycerine and glacial acetic acid. Briggs, Thomas S. J. Chem. Educ. 1970, 47, A206.
Oxidation / Reduction |
Reactions |
Catalysis
|
Autoxidation of benzoin Chen, Philip S. Benzoin in its enediol form undergoes autoxidation in alkaline solution in the presence of air. Chen, Philip S. J. Chem. Educ. 1970, 47, A67.
Oxidation / Reduction |
Reactions
|
Computer evaluation of rates experiment Krieger, Albert G. Notes the availability of a Fortran IV computer program for the numerical evaluation of the "Oxidation of Iodide Ion by Persulfate Ion." Krieger, Albert G. J. Chem. Educ. 1970, 47, 839.
Reactions |
Kinetic-Molecular Theory |
Oxidation / Reduction
|
Interpretation of oxidation-reduction Goodstein, Madeline P. Presents an interpretation of the oxidation number system based upon the electronegativity principle, thus removing the adjective "arbitrary" frequently found in the descriptions of oxidation number. Goodstein, Madeline P. J. Chem. Educ. 1970, 47, 452.
Oxidation / Reduction |
Oxidation State |
Atomic Properties / Structure |
Reactions
|
Oxidizing action of sulfur dioxide Lauren, Paul M. A burning ribbon of magnesium is dropped into a flask of sulfur dioxide produces elemental sulfur. Lauren, Paul M. J. Chem. Educ. 1969, 46, A55.
Oxidation / Reduction |
Reactions
|
The oxidation of hydrazine by basic iodine solutions: A stoichiometric study Cooper, J. N.; Ramette, R. W. This experiment relies on an oxidation-reduction reaction for which a variety of products is energetically possible. Cooper, J. N.; Ramette, R. W. J. Chem. Educ. 1969, 46, 872.
Stoichiometry |
Oxidation / Reduction |
Reactions
|
Thermochemistry of hypochlorite oxidations Bigelow, M. Jerome Students mix various proportions of aqueous sodium hypochlorite and sodium sulfite and plot the change in temperature to determine the stoichiometry of the reaction. Bigelow, M. Jerome J. Chem. Educ. 1969, 46, 378.
Calorimetry / Thermochemistry |
Oxidation / Reduction |
Aqueous Solution Chemistry |
Stoichiometry |
Thermodynamics |
Mechanisms of Reactions
|
Group VI. The Sulfur Family D. Sulfur Dioxide Alyea, Hubert N. Seven demonstrations involving sulfur dioxide. Alyea, Hubert N. J. Chem. Educ. 1968, 45, A977.
Phases / Phase Transitions / Diagrams |
Reactions |
Precipitation / Solubility |
Oxidation / Reduction
|
A transparent dust explosion apparatus Haight, G. P., Jr.; Duvall, Robert.; Phillips, Stanley Design for a transparent dust explosion apparatus Haight, G. P., Jr.; Duvall, Robert.; Phillips, Stanley J. Chem. Educ. 1968, 45, A833.
Oxidation / Reduction |
Reactions
|
Spontaneous combustion Geoghegan, John T.; Sheers, Edward H. Linseed oil is observed to char cotton over a period of time. Geoghegan, John T.; Sheers, Edward H. J. Chem. Educ. 1968, 45, A429.
Oxidation / Reduction |
Reactions |
Calorimetry / Thermochemistry
|
Why does methane burn? Sanderson, R. T. A thermodynamic explanation for why methane burns. Sanderson, R. T. J. Chem. Educ. 1968, 45, 423.
Thermodynamics |
Reactions |
Oxidation / Reduction |
Calorimetry / Thermochemistry |
Covalent Bonding |
Ionic Bonding
|
Burning without access to air Alfthan, Voldemar Permanganate in the presence of sulfuric acid furnishes the oxygen needed for rapid combustion. Alfthan, Voldemar J. Chem. Educ. 1967, 44, A465.
Oxidation / Reduction |
Reactions
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Energy C. Electrical Energy Soule, Dean; Hornbeck, Leroy G.; Jackson, Kenneth V.; Barnard, Robert; Noerdin, Isjrin Demonstrations include aluminum flashed in oxygen; photo-bromination of cinnamic acid, hexane, tartaric acid, toluene; photochemical H2+Cl2 explosion and the slow photochemical H2+Cl2 into 2HCl. Soule, Dean; Hornbeck, Leroy G.; Jackson, Kenneth V.; Barnard, Robert; Noerdin, Isjrin J. Chem. Educ. 1967, 44, A83.
Reactions |
Oxidation / Reduction |
Photochemistry
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The stoichiometry of an oxidation-reduction reaction Latimer, George W., Jr. A short note on the titration of hydrazine sulfate with standard bromate in the presence of sodium molybdate that requires students to identify the products through the use of some elementary qualitative analysis. Latimer, George W., Jr. J. Chem. Educ. 1967, 44, 537.
Stoichiometry |
Oxidation / Reduction |
Reactions |
Titration / Volumetric Analysis |
Qualitative Analysis
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Determination of the combining weight of tin: A new look at an old experiment Carmody, Walter R. Describes efforts to improve the determination of the combining weight of tin Carmody, Walter R. J. Chem. Educ. 1967, 44, 416.
Stoichiometry |
Oxidation / Reduction |
Reactions |
Synthesis
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VII - Combustion and flame Anderson, Robbin C. Presents and describes an extensive bibliography on the study of combustion and flames. Anderson, Robbin C. J. Chem. Educ. 1967, 44, 248.
Oxidation / Reduction |
Reactions |
Gases
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The stoichiometry of an oxidation-reduction reaction: An elementary chemistry experiment Child, W. C., Jr.; Ramette, R. W. Students are asked to decide which of a number of nitrogen containing species is a reasonable product of the reaction between the hydroxylammonium ion and iron (III) on the basis of the experimentally determined stoichiometry of the reaction. Child, W. C., Jr.; Ramette, R. W. J. Chem. Educ. 1967, 44, 109.
Stoichiometry |
Oxidation / Reduction |
Reactions
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Combustion versus biological oxidation Asenjo, Conrado F. Describes a simple toy that can be used to illustrate the difference between combustion and biological oxidation. Asenjo, Conrado F. J. Chem. Educ. 1965, 42, 558.
Oxidation / Reduction |
Reactions
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Continuous process for catalytic oxidation of ammonia Olmsted, Michael P. A heated platinum coil catalyzes the oxidation of ammonia. Olmsted, Michael P. J. Chem. Educ. 1964, 41, A973.
Catalysis |
Oxidation / Reduction |
Reactions
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Metallic reduction of aqueous hydrogen chloride Walker, Noojin, Jr. Calcium reacts with HCl to liberate hydrogen gas. Walker, Noojin, Jr. J. Chem. Educ. 1964, 41, A477.
Reactions |
Oxidation / Reduction |
Metals |
Electrochemistry
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The oxidation of iodide ion by persulfate ion Moews, P. C., Jr.; Petrucci, R. H. Presents the oxidation of iodide ion by persulfate ion as an ideal reaction to study as part of an experiment on kinetics. Moews, P. C., Jr.; Petrucci, R. H. J. Chem. Educ. 1964, 41, 549.
Oxidation / Reduction |
Reactions |
Kinetics |
Rate Law
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Oxidation of bromide and iodide ions Dutton, Frederic B. Color changes are indicative of oxidation reactions of bromide and iodide ions. Dutton, Frederic B. J. Chem. Educ. 1963, 40, A241.
Oxidation / Reduction |
Reactions |
Electrochemistry
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Oxidation of bromide and iodide ions Dutton, Frederic B. Color changes are indicative of oxidation reactions of bromide and iodide ions. Dutton, Frederic B. J. Chem. Educ. 1963, 40, A241.
Oxidation / Reduction |
Reactions |
Electrochemistry
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Demonstration notes: Spontaneous combustion of H2S Thomas, P. M. Hydrogen sulfide passed over lead(IV) oxide bursts into flame. Thomas, P. M. J. Chem. Educ. 1962, 39, A839.
Oxidation / Reduction |
Reactions
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Oxidation-reduction mechanisms Duke, F. R. Summarizes various types of oxidation-reduction mechanisms. Duke, F. R. J. Chem. Educ. 1961, 38, 161.
Oxidation / Reduction |
Mechanisms of Reactions
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The stability of solutions for the iodine clock reaction Kauffman, George B.; Hall, Charles R. The results of attempts to stabilize solutions needed for the iodine clock reaction to allow long-term storage. Kauffman, George B.; Hall, Charles R. J. Chem. Educ. 1958, 35, 577.
Reactions |
Kinetics |
Oxidation / Reduction |
Aqueous Solution Chemistry
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Lecture demonstrations of incendiaries. II Antelman, Marvin Demonstrations described involve gunpowder, the combustion of sulfur dioxide, zirconium, nitric acid, sodium peroxide, hot iron, ammonium nitrate, organic chlorates and nitrates, and zinc stearate. Antelman, Marvin J. Chem. Educ. 1955, 32, 273.
Reactions |
Oxidation / Reduction
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Letters Miranda, Bienvenido T. Commmentary on two earlier Journal articles. Miranda, Bienvenido T. J. Chem. Educ. 1953, 30, 264.
Oxidation State |
Oxidation / Reduction |
Reactions
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