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Manual Data Processing in Analytical Chemistry: Linear Calibration Dora Melucci Most science students are familiar with Excel spreadsheets, but determining which of Excels statistical functions perform a calculation equivalent to a classical equation and calculating errors with Excel are not trivial exercises. Melucci, Dora. J. Chem. Educ. 2008, 85, 1346.
Calibration |
Chemometrics |
Quantitative Analysis
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Helping Students Assess the Relative Importance of Different Intermolecular Interactions Paul G. Jasien A semi-quantitative model has been developed to estimate the relative effects of dispersion, dipoledipole interactions, and H-bonding on the normal boiling points for a series of simple, straight-chain organic compounds. Application of this model may be useful in addressing student misconceptions related to the additivity of intermolecular interactions. Jasien, Paul G. J. Chem. Educ. 2008, 85, 1222.
Chemometrics |
Molecular Properties / Structure |
Noncovalent Interactions |
Physical Properties
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Using Pooled Data and Data Visualization To Introduce Statistical Concepts in the General Chemistry Laboratory Robert J. Olsen This article describes how data pooling and visualization can be employed in the first-semester general chemistry laboratory to introduce core statistical concepts such as central tendency and dispersion of a data set. Olsen, Robert J. J. Chem. Educ. 2008, 85, 544.
Chemometrics |
Stoichiometry
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Reaction Order Ambiguity in Integrated Rate Plots Joe Lee This article provides a theoretical and statistical justification for the necessity of monitoring a reaction to a substantial fraction of completion if integrated rate plots plots are to yield unambiguous orders. Lee, Joe. J. Chem. Educ. 2008, 85, 141.
Chemometrics |
Kinetics |
Rate Law
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The Penny Experiment Revisited: An Illustration of Significant Figures, Accuracy, Precision, and Data Analysis Joseph Bularzik In this general chemistry laboratory the densities of pennies are measured by weighing them and using two different methods to measure their volumes. The average and standard deviation calculated for the resulting densities demonstrate that one measurement method is more accurate while the other is more precise. Bularzik, Joseph. J. Chem. Educ. 2007, 84, 1456.
Chemometrics |
Nomenclature / Units / Symbols |
Nonmajor Courses |
Physical Properties
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Teaching Mathematics to Chemistry Students with Symbolic Computation J. F. Ogilvie and M. B. Monagan The authors explain how the use of mathematical software improves the teaching and understanding of mathematics to and by chemistry students while greatly expanding their abilities to solve realistic chemical problems. Ogilvie, J. F.; Monagan, M. B. J. Chem. Educ. 2007, 84, 889.
Chemometrics |
Computational Chemistry |
Fourier Transform Techniques |
Mathematics / Symbolic Mathematics |
Nomenclature / Units / Symbols
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Understanding Isotopic Distributions in Mass Spectrometry Juris Meija Offers a simple graphical tool for obtaining complex isotopic distributions. Meija, Juris. J. Chem. Educ. 2006, 83, 1761.
Mass Spectrometry |
Isotopes |
Chemometrics
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The Importance and Efficacy of Using Statistics in the High School Chemistry Laboratory Paul S. Matsumoto This paper describes some statistical concepts and their application to various experiments used in high school chemistry. Matsumoto, Paul S. J. Chem. Educ. 2006, 83, 1649.
Chemometrics |
Mathematics / Symbolic Mathematics
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Complexometric Titration of Aluminum and Magnesium Ions in Commercial Antacids. An Experiment for General and Analytical Chemistry Laboratories Shui-Ping Yang and Ruei-Ying Tsai A novel experiment for determining the total and individual aluminum and magnesium ion content in commercial antacids is described. This experiment is developed with three independent protocols based on complexometric direct and back titrations containing the concepts and usages of blocking, masking, buffer controls and metallic indicators. Yang, Shui-Ping; Tsai, Ruei-Ying. J. Chem. Educ. 2006, 83, 906.
Aqueous Solution Chemistry |
Chemometrics |
Consumer Chemistry |
Medicinal Chemistry |
Quantitative Analysis |
Titration / Volumetric Analysis |
UV-Vis Spectroscopy
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Further Analysis of Boiling Points of Small Molecules, CHwFxClyBrz Guy Beauchamp Multiple linear regression analysis has proven useful in selecting predictor variables that could significantly clarify the boiling point variation of the CHwFxClyBrz molecules. Beauchamp, Guy. J. Chem. Educ. 2005, 82, 1842.
Chemometrics |
Physical Properties |
Hydrogen Bonding |
Molecular Properties / Structure |
Alkanes / Cycloalkanes
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Cross-Proportions: A Conceptual Method for Developing Quantitative Problem-Solving Skills Elzbieta Cook and Robert L. Cook This paper focuses attention on the cross-proportion (C-P) method of mathematical problem solving, which was once widely used in chemical calculations. We propose that this method regain currency as an alternative to the dimensional analysis (DA) method, particularly in lower-level chemistry courses. In recent years, the DA method has emerged as the only problem solving mechanism offered to high-school and general chemistry students in contemporary textbooks, replacing more conceptual methods, C-P included. Cook, Elzbieta; Cook, Robert L. J. Chem. Educ. 2005, 82, 1187.
Learning Theories |
Stoichiometry |
Chemometrics |
Student-Centered Learning
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The Reaction Quotient Is Unnecessary To Solve Equilibrium Problems Paul S. Matsumoto The traditional method to determine the equilibrium concentration of chemicals in a reaction, given the equilibrium constant and the initial concentration of chemicals in the reaction, involves the determination of the reaction quotient. This article will demonstrate that this step may be eliminated; thereby simplifying the algorithm to solve such problems. Such a reduction in the complexity of the algorithm may result in more students successfully being able to solve such problems. Matsumoto, Paul S. J. Chem. Educ. 2005, 82, 406.
Equilibrium |
Learning Theories |
Chemometrics
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Capillary Electrophoresis Analysis of Cations in Water Samples. An Experiment for the Introductory Laboratory Christopher J. Pursell, Bert Chandler, and Michelle M. Bushey This experiment can be done in a lab, as a "dry-lab", or as an in-class exercise. Students explore a number of basic separation topics and work with figures of merit for real and meaningful samples. We have adopted a strategy where students encounter various instruments and methods of analyses multiple times throughout the curriculum. The level of sophistication in the exposures increases with the experience level of the students. Through this repeated exposure students will gain a better and fuller understanding of these methods than they would with a single exposure to the technique in the analytical or instrumental laboratory. Pursell, Christopher J.; Chandler, Bert; Bushey, Michelle M. J. Chem. Educ. 2004, 81, 1783.
Electrophoresis |
Quantitative Analysis |
Separation Science |
Chemometrics |
Water / Water Chemistry
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Statistical Comparison of Data in the Analytical Laboratory Michael J. Samide In this article, an experiment designed to provide students with an experience involving statistical treatment of data is described. This experiment allows students to compare 11 different techniques for measuring specific volumes of water. Replicate measurements are taken for each technique and comparisons are made both within a data set and between different data sets. Through calculation of t-values, students are able to draw conclusions about the precision and accuracy of these various techniques. Samide, Michael J. J. Chem. Educ. 2004, 81, 1641.
Chemometrics
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Unified Approximations: A New Approach for Monoprotic Weak Acid–Base Equilibria Harry L. Pardue, Ihab N. Odeh, and Teweldemedhin M. Tesfai This article describes a new approach to approximate calculations for monoprotic acidbase equilibria in otherwise pure water. The new approach, identified herein as unified approximations, uses a simple decision criterion to select between situations that should be treated as deprotonation and protonation reactions. The remaining treatment takes account of changes in concentrations of conjugate acidbase pairs for all situations and ignores autoprotolysis only for situations for which the analytical concentration of either the conjugate acid or conjugate base will always be larger than zero. Pardue, Harry L.; Odeh, Ihab N.; Tesfai, Teweldemedhin M. J. Chem. Educ. 2004, 81, 1367.
Acids / Bases |
Equilibrium |
Chemometrics
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Reaction to Why Do We Teach Equilibrium Calculations? Stephen J. Hawkes "Rigor" in introductory chemistry is often equated with quantitation. Consequently the understanding of chemical reactions and properties is obscured. This was illustrated by Stumpo who asked students to calculate ?E of a reaction, and then on another question on the same test asked a question aimed at its meaning. 77% of the students calculated correctly, but only 24% showed understanding of its meaning. The ability to calculate a number does not measure understanding of the number. Hawkes, Stephen J. J. Chem. Educ. 2004, 81, 1265.
Equilibrium |
Chemometrics
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Reaction to Why Do We Teach Equilibrium Calculations? Don L. Lewis A recently published correspondence by Stephen J. Hawkes on teaching equilibrium calculations troubles me. Hawkes dismisses equilibrium calculations as mere algorithms, best deferred until the student can use computer programs. I find it difficult to believe that a computer program enhances understanding. From a chemists point of view, the equilibrium condition is a limit, a limit that (because of stochastic considerations) does not exist. It might be better to make the reaction quotient statement using < or > but the use of those relations is delayed until quantum mechanics. Lewis, Don L. J. Chem. Educ. 2004, 81, 1265.
Equilibrium |
Chemometrics
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Using a Graphing Calculator To Determine a First-Order Rate Constant: Author Reply José E. Cortés-Figueroa When technology is used to help with mathematical calculations, the emphasis must be on the concepts being learned rather than simply the procedures. In our approach we are attempting to help students learn more about the concept and also to attain data analysis skills they will need in the future. Cortés-Figueroa, José E. J. Chem. Educ. 2004, 81, 485.
Kinetics |
Chemometrics
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Using a Graphing Calculator To Determine a First-Order Rate Constant Todd P. Silverstein The authors use the graphing calculator to estimate the infinity reading from linearized kinetics data, and then they use linearized semi-log data to determine the first-order rate constant. Silverstein, Todd P. J. Chem. Educ. 2004, 81, 485.
Kinetics |
Chemometrics
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Effects of an Active Learning Environment: Teaching Innovations at a Research I Institution Maria T. Oliver-Hoyo, DeeDee Allen, William F. Hunt, Joy Hutson, and Angela Pitts This paper describes a new approach for teaching general chemistry that combines lecture and laboratory into one seamless session and incorporates instructional methods supported by research-based findings. The results of a study that compared two instructional formats, conventional passive lecture and the student-centered, highly collaborative format known as cAcL2 (concept Advancement through chemistry LabLecture), are also presented. Oliver-Hoyo, Maria T.; Allen, DeeDee; Hunt, William F.; Hutson, Joy; Pitts, Angela. J. Chem. Educ. 2004, 81, 441.
Chemometrics |
Student-Centered Learning
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Don't Be Tricked by Your Integrated Rate Plot Edward Urbansky Reply to comments on original article. Urbansky, Edward. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
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Don't Be Tricked by Your Integrated Rate Plot: Reaction order Ambiguity Sue Le Vent Integrated rate equations (for constant reaction volume) may be given in terms of relative reactant concentration, C (= concentration/initial concentration) and relative time, T (= time/half-life); in these forms, the equations are independent of rate constants and initial concentrations. Le Vent, Sue. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
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Don't Be Tricked by Your Integrated Rate Plot: Pitfalls of Using Integrated Rate Plots Gabor Lente Problems with linearizing the integrated rate law. Lente, Gabor. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
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Don't Be Tricked by Your Integrated Rate Plot: Pitfalls of Using Integrated Rate Plots Gabor Lente Problems with linearizing the integrated rate law. Lente, Gabor. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
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SpecScan: A Utility Program for Generating Numerical Data from Printed Forms of Spectra or Other Signals Constantinos E. Efstathiou SpecSpan is a utility program for Microsoft Windows that generates numerical data from printed spectra or other plots found as figures in text, chart recordings, or freehand drawings. SpecScan can process bitmap (.BMP) images of such figures and drawings. After a brief interaction with the user, it generates and exports numerical data as Excel (.XLS) or text (.TXT) files. Efstathiou, Constantinos E. J. Chem. Educ. 2003, 80, 1093.
Chemometrics |
Spectroscopy
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From Our Peer-Reviewed Collection William F. Coleman and Edward W. Fedosky The JCE WebWare collection continues to evolve and grow. This month we add another program, SpecScan: A Utility Program for Generating Numerical Data from Printed Forms of Spectra or Other Signals, to our collection of peer-reviewed WebWare. Coleman, William F.; Fedosky, Edward W. J. Chem. Educ. 2003, 80, 1093.
Chemometrics |
Spectroscopy
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SpecScan: A Utility Program for Generating Numerical Data from Printed Forms of Spectra or Other Signals Constantinos E. Efstathiou The JCE WebWare collection continues to evolve and grow. This month we add another program, SpecScan: A Utility Program for Generating Numerical Data from Printed Forms of Spectra or Other Signals, to our collection of peer-reviewed WebWare. Efstathiou, Constantinos E. J. Chem. Educ. 2003, 80, 1093.
Chemometrics |
Spectroscopy
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Two Linear Correlation Coefficients Robert de Levie In fitting data to a straight line, many calculators and computer programs display a linear correlation coefficient. Two types of linear correlation coefficients are discussed, one often useful in chemical calculations, the other usually not. de Levie, Robert. J. Chem. Educ. 2003, 80, 1030.
Chemometrics
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Classification of Vegetable Oils by Principal Component Analysis of FTIR Spectra David A. Rusak, Leah M. Brown, and Scott D. Martin Comparing unknown samples of vegetable oils to known samples using FTIR and principal component analysis (PCA) and nearest means classification (NMC). Rusak, David A.; Brown, Leah M.; Martin, Scott D. J. Chem. Educ. 2003, 80, 541.
IR Spectroscopy |
Instrumental Methods |
Food Science |
Lipids |
Chemometrics |
Qualitative Analysis |
Fourier Transform Techniques |
Consumer Chemistry |
Applications of Chemistry
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Teaching Chemistry Using From the Earth to the Moon James G. Goll and Stacie L. Mundinger Teaching chemistry using From the Earth to the Moon (an HBO original movie series). Goll, James G.; Mundinger, Stacie L. J. Chem. Educ. 2003, 80, 292.
Electrochemistry |
Chemometrics |
Reactions |
Mechanisms of Reactions |
Applications of Chemistry
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An Interactive Graphical Approach to Temperature Conversions Jonathan Mitschele Activity to demonstrate the relationship between the Fahrenheit and Celsius temperature scales by graphing measurements of English- and metric-unit thermometers. Mitschele, Jonathan. J. Chem. Educ. 2002, 79, 1235.
Nomenclature / Units / Symbols |
Chemometrics |
Calorimetry / Thermochemistry
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LIMSport: Optimizing a Windows-Based Computer Data Acquisition and Reduction System for the General Chemistry Laboratory Ed Vitz and Brenda P. Egolf Project to develop a Windows/Excel data acquisition system for LIMSport (a mechanism for automatically acquiring data from a variety of sensors into a spreadsheet so that teachers and students only need spreadsheet skills to acquire and analyze data) and evaluate its effectiveness in promoting student learning. Vitz, Ed; Egolf, Brenda P. J. Chem. Educ. 2002, 79, 1060.
Laboratory Computing / Interfacing |
Learning Theories |
Chemometrics
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Precision in Microscale Titration Mono M. Singh, Cynthia B. McGowan, and Zvi Szafran Comparing the precision of a 2-mL graduated pipet and 50-mL graduated buret in performing a microscale titration. Singh, Mono M.; McGowan, Cynthia B.; Szafran, Zvi. J. Chem. Educ. 2002, 79, 941.
Laboratory Equipment / Apparatus |
Chemometrics |
Microscale Lab |
Titration / Volumetric Analysis
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Precision in Microscale Titration Julian L. Roberts Jr. Comparing the precision of a 2-mL graduated pipet and 50-mL graduated buret in performing a microscale titration. Roberts, Julian L., Jr. J. Chem. Educ. 2002, 79, 941.
Laboratory Equipment / Apparatus |
Chemometrics |
Microscale Lab |
Titration / Volumetric Analysis
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Precision in Microscale Titration Julian L. Roberts Jr. Comparing the precision of a 2-mL graduated pipet and 50-mL graduated buret in performing a microscale titration. Roberts, Julian L., Jr. J. Chem. Educ. 2002, 79, 941.
Laboratory Equipment / Apparatus |
Chemometrics |
Microscale Lab |
Titration / Volumetric Analysis
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Experimental Design and Multiplexed Modeling Using Titrimetry and Spreadsheets Peter de B. Harrington, Erin Kolbrich, and Jennifer Cline Determining the acidity of three vinegar samples using multiplexed titrations and an MS Excel spreadsheet. Harrington, Peter de B.; Kolbrich, Erin; Cline, Jennifer. J. Chem. Educ. 2002, 79, 863.
Acids / Bases |
Chemometrics |
Stoichiometry |
Titration / Volumetric Analysis
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Nonlinear Fits of Standard Curves: A Simple Route to Uncertainties in Unknowns Carl Salter and Robert de Levie The problem of covariance in using calibration curves and a nonlinear least-squares procedure that permits a direct estimation of uncertainty without the need for covariance. Salter, Carl; de Levie, Robert. J. Chem. Educ. 2002, 79, 268.
Chemometrics
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Some Unusual Applications of the "Error-Bar" Feature in Excel Spreadsheets Kieran F. Lim Paper demonstrating how the "error-bar" feature in Excel can be sued to produce high-quality graphs for university teaching, learning, and research. Lim, Kieran F. J. Chem. Educ. 2002, 79, 135.
Chemometrics
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Visualizing the Photochemical Steady State with UV-Sensitive Beads (re J. Chem. Educ. 2001, 77, 648A-648B) Jerry A. Bell Analysis of the temperature dependence of the color intensity of UV-sensitive beads. Bell, Jerry A. J. Chem. Educ. 2001, 78, 1594.
Atomic Properties / Structure |
Kinetics |
Photochemistry |
Chemometrics
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On Concepts of Partial Volume and Law of Partial Volume (re J. Chem. Educ. 2001, 78, 238-240) Myung-Hoon Kim Supplementing the law of partial pressures with a law of partial volumes. Kim, Myung-Hoon. J. Chem. Educ. 2001, 78, 1594.
Gases |
Chemometrics |
Physical Properties
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On Concepts of Partial Volume and Law of Partial Volume (re J. Chem. Educ. 2001, 78, 238-240) David W. Miller Supplementing the law of partial pressures with a law of partial volumes. Miller, David W. J. Chem. Educ. 2001, 78, 1594.
Gases |
Chemometrics |
Physical Properties
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Analysis of Success in General Chemistry Based on Diagnostic Testing Using Logistic Regression Margaret J. Legg, Jason C. Legg, and Thomas J. Greenbowe Estimating the probability of succeeding in general chemistry based on diagnostic or placement exam scores. Legg, Margaret J.; Legg, Jason C.; Greenbowe, Thomas J. J. Chem. Educ. 2001, 78, 1117.
Chemometrics |
Learning Theories |
Student / Career Counseling
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Don't Be Tricked by Your Integrated Rate Plot! Edward T. Urbansky Using integrated rate plots to determine reaction order. Urbansky, Edward T. J. Chem. Educ. 2001, 78, 921.
Kinetics |
Mechanisms of Reactions |
Learning Theories |
Chemometrics |
Rate Law
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A Simple Method for Illustrating Uncertainty Analysis Paul C. Yates A fast and simple method for generating data for uncertainty analysis; includes statistical analysis and calculation of maximum probable error for a sample set of data. Yates, Paul C. J. Chem. Educ. 2001, 78, 770.
Chemometrics |
Quantitative Analysis
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Chemistry Report. MAA-CUPM Curriculum Foundations Workshop in Biology and Chemistry, Macalester College, November 2-5, 2000 Norman C. Craig Chemists list specific knowledge and skills in mathematics needed by chemistry students and indicate whether mathematicians or chemists should deliver the instruction; the course level of the instruction and the use of technological aids are also designated. Craig, Norman C. J. Chem. Educ. 2001, 78, 582.
Chemometrics |
Mathematics / Symbolic Mathematics |
Learning Theories
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What's Been Happening to Undergraduate Mathematics David M. Bressoud An overview of some of the changes that have been occurring in undergraduate mathematics education; based on a workshop held by the Mathematical Association of America to determine what chemists expect their students to learn from undergraduate mathematics courses in terms of understanding, content, and use of technology. Bressoud, David M. J. Chem. Educ. 2001, 78, 578.
Learning Theories |
Mathematics / Symbolic Mathematics |
Chemometrics
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Understanding Solubility through Excel Spreadsheets Pamela Brown This article describes assignments related to the solubility of inorganic salts that can be given in an introductory general chemistry course. These assignments address the need for math, graphing, and computer skills in the chemical technology program by developing skill in the use of Microsoft Excel to prepare spreadsheets and graphs and to perform linear and nonlinear curve-fitting. Brown, Pamela. J. Chem. Educ. 2001, 78, 268.
Aqueous Solution Chemistry |
Chemometrics |
Precipitation / Solubility
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A Simple Laboratory Experiment for the Determination of Absolute Zero Myung-Hoon Kim, Michelle Song Kim, and Suw-Young Ly A novel method that employs a remarkably simple and inexpensive apparatus and is based on the extrapolation of the volume of a given amount of dry air to zero volume after a volume of air trapped inside a 10-mL graduated cylinder is measured at various temperatures. Kim, Myung-Hoon; Kim, Michelle Song; Ly, Suw-Young. J. Chem. Educ. 2001, 78, 238.
Gases |
Physical Properties |
Chemometrics
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How Can an Instructor Best Introduce the Topic of Significant Figures to Students Unfamiliar with the Concept? Richard A. Pacer The focus of this paper is how best to introduce the concept of significant figures so that students find it meaningful before a stage is reached at which they become turned off. The approach described begins with measurements students are already familiar with from their life experiences and involves the students as active learners. Pacer, Richard A. J. Chem. Educ. 2000, 77, 1435.
Learning Theories |
Nonmajor Courses |
Chemometrics
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Pixel Conversion: A Simple Way to Extract Coordinates of Points from a Printed Graph Christian Aymard and Randall B. Shirts A very simple method is described for extracting the coordinates of points from printed graphs, student reports, or publications. One only needs a flatbed scanner and a desktop computer. This is a convenient and inexpensive alternative to the tedious traditional method using a ruler or to the more costly programs available commercially. A Windows program has been made available to perform the required operations. Aymard, Christian; Shirts, Randall B. J. Chem. Educ. 2000, 77, 1230.
Chemometrics
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Encouraging Meaningful Quantitative Problem Solving Jeff Cohen, Meghan Kennedy-Justice, Sunny Pai, Carmen Torres, Rick Toomey, Ed DePierro, and Fred Garafalo This paper describes the efforts of a group of teachers to help college freshman chemistry students and high school science students to improve their problem-solving skills. The presentation includes several sets of questions intended to elucidate ideas and to involve the reader in the process of reflecting upon his or her own problem-solving strategies. Cohen, Jeff; Kennedy-Justice, Meghan; Pai, Sunny; Torres, Carmen; Toomey, Rick; DePierro, Ed; Garafalo, Fred. J. Chem. Educ. 2000, 77, 1166.
Mathematics / Symbolic Mathematics |
Chemometrics
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A Classroom Exercise in Sampling Technique Michael R. Ross A classroom hands-on demonstration has been developed that looks at the two important sampling considerations, sample size and non-homogeneous sample materials. This classroom activity makes use of readily available M&M candies for the sample size and NERDS for the non-homogeneous sample exercises. Ross, Michael R. J. Chem. Educ. 2000, 77, 1015.
Quantitative Analysis |
Chemometrics
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Spreadsheet Calculation of the Propagation of Experimental Imprecision Robert de Levie A spreadsheet is used to compute the propagation of imprecision, and a macro is described that will do this automatically. de Levie, Robert. J. Chem. Educ. 2000, 77, 534.
Chemometrics |
Quantitative Analysis |
Laboratory Computing / Interfacing
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Predicting Acid-Base Titration Curves without Calculations Dennis W. Barnum In this paper a qualitative and systematic method for sketching titration curves is presented. Even the more complex cases such as salts or polyprotic acids and bases are treated just as easily as simple monoprotic acids. Having students predict the shape of titration curves from known equilibrium constants helps to focus attention on the general principles without distraction by the mathematics. Barnum, Dennis W. J. Chem. Educ. 1999, 76, 938.
Acids / Bases |
Quantitative Analysis |
Water / Water Chemistry |
Equilibrium |
Learning Theories |
Titration / Volumetric Analysis |
Chemometrics
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Do pH in Your Head Addison Ault Every aqueous solution has a pH. Two factors determine this pH: the acidic or basic strength of the solute, and its concentration. When you use pKa values to express acidic and basic strength you can easily estimate the approximate pH of many aqueous solutions of acids, bases, and their salts and their buffers. Ault, Addison. J. Chem. Educ. 1999, 76, 936.
Equilibrium |
Acids / Bases |
Aqueous Solution Chemistry |
Learning Theories |
Chemometrics |
Brønsted-Lowry Acids / Bases
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Precision and Accuracy in Measurements (the author replies) Treptow, Richard S. Relation between instrument resolution and skill. Treptow, Richard S. J. Chem. Educ. 1999, 76, 471.
Chemometrics |
Instrumental Methods
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Precision and Accuracy in Measurements Thomsen, Volker The difference between instrument resolution and precision. Thomsen, Volker J. Chem. Educ. 1999, 76, 471.
Chemometrics |
Instrumental Methods
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An Easy and Effective Classroom Demonstration of Population Distributions Marjorie A. Jones Using a simple experimental design and easily obtained materials, a classroom experiment was conducted to demonstrate normal-distribution behavior for a population. We used popcorn and a hot-air popper. Popped kernels were collected with time and data were plotted as popped kernels per time interval versus time. The data clearly showed a normal (Gaussian) distribution. Jones, Marjorie A. J. Chem. Educ. 1999, 76, 384.
Chemometrics
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Effect of Sample Size on Sampling Error: An Experiment for Introductory Analytical Chemistry Joseph E. Vitt and Royce C. Engstrom Students acquire samples of various size from a binary population, calculate the relative standard deviations for each sample size, and compare these results with those predicted by the binomial distribution. This experiment gives excellent agreement for the pooled student data, and the results show the expected decrease in sampling error as the sample size increases. Vitt, Joseph E.; Engstrom, Royce C. J. Chem. Educ. 1999, 76, 99.
Quantitative Analysis |
Instrumental Methods |
Chemometrics
|
CHEMiCALC (4000161) and CHEMiCALC Personal Tutor (4001108), Version 4.0 (by O. Bertrand Ramsay) Scott White and George Bodner CHEMiCALC is a thoughtfully designed software package developed for use by high school and general chemistry students, who will benefit from the personal tutor mode that helps to guide them through unit conversion, empirical formula, molecular weight, reaction stoichiometry, and solution stoichiometry calculations. White, Scott; Bodner, George M. J. Chem. Educ. 1999, 76, 34.
Chemometrics |
Nomenclature / Units / Symbols |
Stoichiometry
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Temperature Scale Conversion as a Linear Equation: True Unit Conversion vs Zero-Offset Correction Reuben Rudman The equation used for the interconversion between the Fahrenheit and Celsius temperature scales is in reality the general case of the straight-line equation (y = ax + b). This equation is the paradigm for many of the calculations taught in introductory chemistry. Rudman, Reuben. J. Chem. Educ. 1998, 75, 1646.
Nomenclature / Units / Symbols |
Chemometrics
|
Modeling Nuclear Decay: A Point of Integration between Chemistry and Mathematics Kent J. Crippen and Robert D. Curtright A four-part activity utilizing a graphing calculator to investigate nuclear stability is described. Knowledge acquired through the activity provides background for answering the societal question of using nuclear materials for energy production. Crippen, Kent J.; Curtright, Robert D. J. Chem. Educ. 1998, 75, 1434.
Nuclear / Radiochemistry |
Atomic Properties / Structure |
Chemometrics
|
There Seems To Be Uncertainty about the Use of Significant Figures in Reporting Uncertainties of Results Julio F. Caballero and Delphia F. Harris A cursory review of two journals indicates that uncertainties in experimental results are not consistently reported in the literature with the correct number of significant figures. The problem seems more frequent in computer generated results in both chemical education and research articles. Examples of published values with uncertainty inappropriately reported are included along with the appropriate rounding. Caballero, Julio F.; Harris, Delphia F. J. Chem. Educ. 1998, 75, 996.
Laboratory Equipment / Apparatus |
Learning Theories |
Chemometrics
|
Precision and Accuracy in Measurements: A Tale of Four Graduated Cylinders Richard S. Treptow The concepts of precision and accuracy help students understand that uncertainty accompanies even our best scientific measurements. A model experiment can be used to distinguish the two terms. The experiment uses four graduated cylinders which give measurements of different accuracy and precision. Such terms as mean, range, standard deviation, error, and true value are defined through an illustration. Treptow, Richard S. J. Chem. Educ. 1998, 75, 992.
Quantitative Analysis |
Chemometrics
|
Precision and Accuracy (the authors reply, 2) Midden, W. Robert Rounding-off rules and significant figures. Midden, W. Robert J. Chem. Educ. 1998, 75, 971.
Chemometrics
|
Precision and Accuracy (the authors reply, 1) Guare, Charles J. Rounding-off rules and significant figures. Guare, Charles J. J. Chem. Educ. 1998, 75, 971.
Chemometrics
|
Precision and Accuracy (3) Rustad, Douglas Rounding-off rules and significant figures. Rustad, Douglas J. Chem. Educ. 1998, 75, 970.
Chemometrics
|
Precision and Accuracy (1) Sykes, Robert M. Standard procedures for determining and maintaining significant figures in calculations. Sykes, Robert M. J. Chem. Educ. 1998, 75, 970.
Chemometrics
|
Percent Composition and Empirical Formula - A New View George L. Gilbert A new method of obtaining the empirical formula for a compound from its percent composition is proposed. The method involves the determination of a minimum molar mass for the compound based on the percentage of each element, obtaining the lowest common molar mass and using this data to calculate the integer values used in writing the empirical formula. Gilbert, George L. J. Chem. Educ. 1998, 75, 851.
Atomic Properties / Structure |
Stoichiometry |
Chemometrics
|
Production of Numerical Chemical Problems Using a Spreadsheet Peter G. Hall The use of spreadsheets for "personalized" assignments. These assignments take the form of printed chemical problems such that every student has different numerical data. The problem sets make a challenging student introduction to word processing and spreadsheet use. Hall, Peter G. J. Chem. Educ. 1998, 75, 243.
Chemometrics
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The Chemistry Maths Book (by Erich Steiner) C. Michael McCallum The Chemistry Maths Book contains all the mathematical methods that 99% of chemists would need. Designed as a text for an actual Maths for Chemists course, it is laid out in a logical progression from simple (decimals, algebra, and functions) to the more complicated but no less important (matrix algebra, differential equations, and matrix eigenvalue problems). It seems well suited both for its stated purpose and as a "brush-up" book for undergraduates, graduate students, and others. McCallum, C. Michael. J. Chem. Educ. 1997, 74, 1400.
Chemometrics |
Mathematics / Symbolic Mathematics
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A Note on Covariance in Propagation of Uncertainty Edwin F. Meyer It is pointed out that whenever both the slope and the intercept are used in calculating a physical quantity from a linear regression, propagation of error must include the covariance as well as the variances. The point is illustrated with a calculation of the boiling point of water from the parameters of the lnP vs 1/T fit. If the covariance is omitted from the propagation of error, the estimate of uncertainty is unreasonably large. Meyer, Edwin F. J. Chem. Educ. 1997, 74, 1339.
Chemometrics
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Spreadsheet Applications in Chemistry Using Microsoft Excel by Dermot Diamond and Venita C. A. Hanratty Jeffery A. Greathouse Provides chemistry instructors with an introduction to Excel and its applications in chemistry. Greathouse, Jeffery A. J. Chem. Educ. 1997, 74, 1279.
Chemometrics
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MathBrowser: Web-Enabled Mathematical Software with Application to the Chemistry Curriculum, v 1.0 Jack G. Goldsmith MathBrowser, a freeware web-enabled derivative of the MathCad mathematical software (MathSoft Inc., Cambridge, MA), is designed to reconcile the problem of how to distribute mathematically rich information over the WWW and to maintain interactivity for the end user. Goldsmith, Jack G. J. Chem. Educ. 1997, 74, 1164.
Mathematics / Symbolic Mathematics |
Chemometrics
|
Graham's Law and Perpetuation of Error Stephen J. Hawkes Grahams Laws of effusion and diffusion are used in recent articles for traditional experiments to which they do not in fact apply and for which they give the wrong answer. Hawkes, Stephen J. J. Chem. Educ. 1997, 74, 1069.
Gases |
Chemometrics |
Transport Properties
|
Rounding Numbers: Why the "New System" Doesn't Work W. Robert Midden This paper explains a correction to the rounding rule previously published in this Journal. The earlier article reported that the best way to round numbers is to always round up when the first digit dropped is 5. However, this will lead to accumulation of error when errors are averaged. Midden, W. Robert. J. Chem. Educ. 1997, 74, 405.
Chemometrics
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Sensitivity to Experimental Parameters via Spreadsheets B. R. Sundheim In spreadsheet computations wherever the functional dependence of calculated results on experimental quantities is obscure, sensitivities may be obtained by testing the effects of variations in relevant inputs. An example is given where Hess' law is explored calorimetrically. Sundhein, B. R. . J. Chem. Educ. 1997, 74, 328.
Chemometrics
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Curve Fitting: An Alternative Approach to Analyzing Kinetic Data in Introductory Chemistry Coleman, William F. 183. The availability of high quality software for performing nonlinear curve fitting on microcomputers allows students to take an alternative approach to data analysis, one that concentrates on functional forms that may be more natural than some of the algebraic machinations necessary to render relationships into linear forms. An example of the application of such an approach to the analysis of kinetic data is presented in this paper. Coleman, William F. J. Chem. Educ. 1996, 73, 243.
Chemometrics |
Kinetics
|
Significant Figures in Graph Interpretation Donald M. Graham A means is derived for calculating the number of significant figures in the slope and intercept of an experimental linear graph. The method is based on the actual scatter in the points rather than on the nominal precision in the original data, and it can be used even by students who are mathematically fairly unsophisticated. Graham, Donald M. J. Chem. Educ. 1996, 73, 211.
Chemometrics
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Management of First-Year Chemistry Laboratories Using Spreadsheets Collins, Frank E.; Williams, Charles W. Use of spreadsheets to record, analyze, and assess experimental data. Collins, Frank E.; Williams, Charles W. J. Chem. Educ. 1995, 72, A182.
Chemometrics
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Experimental Methods: An Introduction to the Analysis of Data (Kirkup, Les) Title of interest. J. Chem. Educ. 1995, 72, A72.
Chemometrics
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Dimensional Analysis: An Analogy to Help Students Relate the Concept to Problem Solving James R. McClure Using dominoes to help students understand the conversion factor method of dimensional analysis. McClure, James R. J. Chem. Educ. 1995, 72, 1093.
Nomenclature / Units / Symbols |
Chemometrics
|
Celsius to Fahrenheit--Quick and Dirty Colin Hester Simple algorithm for converting Celsius temperature to Fahrenheit temperature. Hester, Colin. J. Chem. Educ. 1995, 72, 1026.
Calorimetry / Thermochemistry |
Nomenclature / Units / Symbols |
Chemometrics
|
Those Baffling Subscripts Arthur W. Friedel and David P. Maloney Study of the difficulties students have in interpreting subscripts correctly and distinguishing atoms from molecules when answering questions and solving problems. Friedel, Arthur W.; Maloney, David P. J. Chem. Educ. 1995, 72, 899.
Nomenclature / Units / Symbols |
Stoichiometry |
Chemometrics
|
How to Determine the Best Straight Line S. R. Logan Consideration of situations in which the use of a least-squares regression is inappropriate. Logan, S. R. J. Chem. Educ. 1995, 72, 896.
Chemometrics
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The Relationship between the Number of Elements and the Number of Independent Equations of Elemental Balance in Inorganic Chemical Equations R. Subramanian, N.K. Goh, and L. S. Chia The criterion for determining whether a chemical equation can be balanced fully by the algebraic technique and its application. Subramaniam, R.; Goh, N. K.; Chia, L. S. J. Chem. Educ. 1995, 72, 894.
Stoichiometry |
Chemometrics
|
From Titration Data to Buffer Capacities: A Computer Experiment for the Chemistry Lab or Lecture Roy W. Clark, Gary D. White, Judith M. Bonicamp, and Exum D. Watts Provides titration curve data that students can plot and analyze using spreadsheets to develop student understanding of pH, derivatives, buffer capacity, and the behavior of dilute buffers; includes sample graphs and analysis. Clark, Roy W.; White, Gary D.; Bonicamp, Judith M.; Watts, Exum D. J. Chem. Educ. 1995, 72, 746.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Chemometrics
|
Statistical Analysis Experiment for the Freshman Chemistry Lab John C. Salzsieder Procedure that provides sufficient data for statistical analysis by a freshman chemistry class. Salzsieder, John C. J. Chem. Educ. 1995, 72, 623.
Chemometrics
|
Buoyancy Programs; Viscosity of Polymer Solutions; Precision of Calculated Values Bertrand, Gary L. Software to simulate the determination of the density of solids; the preparation of polymer solutions and their time to flow through a viscometer; and a program to calculate the uncertainties of results given the input values. Bertrand, Gary L. J. Chem. Educ. 1995, 72, 492.
Physical Properties |
Chemometrics
|
Rapid Calculation for Preparing Solutions Calero, Diego Lozano Streamlined method for dilution calculations. Calero, Diego Lozano J. Chem. Educ. 1995, 72, 424.
Aqueous Solution Chemistry |
Solutions / Solvents |
Chemometrics
|
The MATCH Program: A Combined Mathematics and Chemistry Curriculum Wink, Donald J. A curriculum that integrates introductory chemistry with intermediate algebra. Wink, Donald J. J. Chem. Educ. 1995, 72, 411.
Chemometrics
|
Spreadsheet-Controlled Potentiometric Analyses Mullin, Jerome; Marquardt, Michael 173. Bits and pieces, 53. Discussion of collecting experimental data on spreadsheets directly from laboratory instruments. Mullin, Jerome; Marquardt, Michael J. Chem. Educ. 1995, 72, 400.
Laboratory Computing / Interfacing |
Chemometrics |
Potentiometry
|
REACT: Exploring Practical Thermodynamic and Equilibrium Calculations Ramette, Richard W. Description of REACT software to balance complicated equations; determine thermodynamic data for all reactants and products; calculate changes in free energy, enthalpy, and entropy for a reaction; and find equilibrium conditions for the a reaction. Ramette, Richard W. J. Chem. Educ. 1995, 72, 240.
Stoichiometry |
Equilibrium |
Thermodynamics |
Chemometrics
|
Measuring with a Purpose: Involving Students in the Learning Process Metz, Patricia A.; Pribyl, Jeffrey R. Constructivist learning activities for helping students to understand measurement, significant figures, uncertainty, scientific notation, and unit conversions. Metz, Patricia A.; Pribyl, Jeffrey R. J. Chem. Educ. 1995, 72, 130.
Nomenclature / Units / Symbols |
Chemometrics |
Constructivism
|
Introducing Spreadsheet Data Analysis in the First-Semester Laboratory Bushey, Michelle M. Massing a collection of pennies in order to introduce statistical concepts about small and large data sets as well as introduce students to the use of spreadsheets. Bushey, Michelle M. J. Chem. Educ. 1994, 71, A90.
Chemometrics
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Spreadsheet Statistics Simpson, John M. Using computer spreadsheets to do statistical analysis on data. Simpson, John M. J. Chem. Educ. 1994, 71, A88.
Chemometrics
|
Symbolic Algebra and Stoichiometry DeToma, Robert P. Applying symbolic algebra (instead of the factor-label method) to stoichiometry calculations. DeToma, Robert P. J. Chem. Educ. 1994, 71, 568.
Chemometrics |
Nomenclature / Units / Symbols
|
A Simple Laboratory Experiment Using Popcorn To Illustrate Measurement Errors Kimbrough, Doris R.; Meglen, Robert R. This experiment focuses on the difference between accuracy and precision and demonstrates the necessity for multiple measurements of an experimental variable. Kimbrough, Doris R.; Meglen, Robert R. J. Chem. Educ. 1994, 71, 519.
Chemometrics
|
A Joke Based on Significant Figures Ruekberg, Ben Joke to introduce significant figures. Ruekberg, Ben J. Chem. Educ. 1994, 71, 306.
Chemometrics
|
Solving equilibria problems with a graphing calculator: A robust method, free of algebra and calculus Ruch, David K.; Chasteen, T. G. The method of successive approximations is frequently introduced in freshman chemistry as a means for solving equilibrium equations. However, this often requires an understanding of calculus that is problematic for introductory chemistry students. An alternative method to solving such equations is to use graphic calculators to solve problems graphically. Ruch, David K.; Chasteen, T. G. J. Chem. Educ. 1993, 70, A184.
Equilibrium |
Chemometrics
|
Shell thickness of the copper-clad cent Vanselow, Clarence H.; Forrester, Sherri R. An exercise in determining the thickness of the copper layer of modern pennies presents the opportunities to combine good chemistry, instrumentation, simple curve fitting, and geometry to solve a simply stated problem. Vanselow, Clarence H.; Forrester, Sherri R. J. Chem. Educ. 1993, 70, 1023.
Metals |
Quantitative Analysis |
Chemometrics
|
How thick/thin is your mirror? McCullough, Thomas; Bell, Lisa When a student reported that his/her water film was 6 cm thick, these authors felt a review of significant figures and dimensional analysis may be in order. McCullough, Thomas; Bell, Lisa J. Chem. Educ. 1993, 70, 851.
Chemometrics
|
Measurement scales: Changing Celsius to Kelvin is not just a unit conversion Nordstrom, Brian H. The key to understanding the difference between Celsius and Kelvin lies in the different types of measurement scales. Students may have an easier time manipulating equations (such as gas laws) if they knew the difference between these scales. Nordstrom, Brian H. J. Chem. Educ. 1993, 70, 827.
Chemometrics |
Kinetic-Molecular Theory |
Gases
|
Statistical analysis of errors: A practical approach for an undergraduate chemistry lab: Part 1. The concepts Guedens, W. J.; Yperman, J.; Mullens, J.; Van Poucke, L. C.; Pauwels, E. J. A concise and practice-oriented introduction to the analysis and interpretation of measurement and errors. Guedens, W. J.; Yperman, J.; Mullens, J.; Van Poucke, L. C.; Pauwels, E. J. J. Chem. Educ. 1993, 70, 776.
Chemometrics
|
Introducing probabilistic concepts in chemistry: The preparation of 10-24 M solution as a limiting case de Vicente, M. Sastre A straightforward dilution experiment that can be used as the starting point for establishing a link between chemistry and concepts of probability theory. de Vicente, M. Sastre J. Chem. Educ. 1993, 70, 674.
Solutions / Solvents |
Chemometrics
|
AnswerSheets Cornelius, Richard Review of a spreadsheet-based program that has modules on significant figures, VSEPR structures, stoichiometry, and unit conversions. Cornelius, Richard J. Chem. Educ. 1993, 70, 460.
VSEPR Theory |
Stoichiometry |
Chemometrics
|
A mole of M&M's Merlo, Carmela; Turner, Kathleen E. Engaging students by asking the question: How thick would the layer of M&M candies be if we covered the continental United States with a mole of these candies? Compare this to a mole of water. Merlo, Carmela; Turner, Kathleen E. J. Chem. Educ. 1993, 70, 453.
Stoichiometry |
Chemometrics
|
AnswerSheets Cornelius, Richard Review of a spreadsheet-like program that includes modules on significant figures, conversions, stoichiometry, and VSEPR structures. Cornelius, Richard J. Chem. Educ. 1993, 70, 387.
VSEPR Theory |
Stoichiometry |
Chemometrics
|
Empirical formulas from atom ratios: A simple method to obtain the integer factors of a rational number Weltin, E. Most textbooks advise students to use a method tantamount to trial and error when they encounter a ratio in empirical formula calculations where it is not immediately apparent what the coefficients should be. The author describes a simple procedure that is an effective way to find the integer factors. Weltin, E. J. Chem. Educ. 1993, 70, 280.
Stoichiometry |
Chemometrics
|
Measuring Avogadro's number on the overhead projector Solomon, Sally; Hur, Chinhyu A Petri dish filled with water and stearic acid dissolved in petroleum ether upon an overhead projector can be used to introduce the topic of Avogadro's number. Solomon, Sally; Hur, Chinhyu J. Chem. Educ. 1993, 70, 252.
Chemometrics |
Stoichiometry
|
Using monetary analogies to teach average atomic mass Last, Arthur M.; Webb, Michael J. Some strategies to overcome the frequent problem novice students have with calculating average atomic mass. Last, Arthur M.; Webb, Michael J. J. Chem. Educ. 1993, 70, 234.
Chemometrics |
Stoichiometry
|
Relative atomic mass and the mole: A concrete analogy to help students understand these abstract concepts de Sanabia, Josefina Arce Suggestions on how to improve student understandings of the mathematical idea of "ratio" to enhance conceptual understanding of this fundamental chemistry concept. de Sanabia, Josefina Arce J. Chem. Educ. 1993, 70, 233.
Chemometrics |
Stoichiometry
|
Concept learning versus problem solving: There is a difference Nakhleh, Mary B.; Mitchell, Richard C. Previous studies indicate that there is little connection between algorithmic problem solving skills and conceptual understanding. The authors provide some ways to evaluate students along a continuum of low-high algorithmic and conceptual problem solving skills. The study shows that current lecture method teaches students to solve algorithms rather than teaching chemistry concepts. Nakhleh, Mary B.; Mitchell, Richard C. J. Chem. Educ. 1993, 70, 190.
Chemometrics |
Learning Theories |
Student-Centered Learning
|
An Investigative Density Experiment Samsa, Richard A. A laboratory exercise about density that is engaging and allows students to use higher-level thinking skills and develop a plan to solve a problem. Samsa, Richard A. J. Chem. Educ. 1993, 70, 149.
Laboratory Computing / Interfacing |
Chemometrics |
Physical Properties
|
More on the Question of Significant Figures Clase, Howard J. Because so many students have a hard time understanding what significant figures are all about, this author developed a method using "?" to substitute for insignificant zeros. This helps many students finally grasp this convention. Clase, Howard J. J. Chem. Educ. 1993, 70, 133.
Chemometrics
|
Equilibrium Calculator Allendoerfer, Robert The equilibrium calculator can calculate the equilibrium concentrations of all reagents in an arbitrary chemical reaction with as many as five reactants and products. Allendoerfer, Robert J. Chem. Educ. 1993, 70, 126.
Equilibrium |
Chemometrics
|
Ideas of Equality and Ratio: Mathematical Basics for Chemistry and the Fallacy of Unitary Conversion Ochiai, El-Ichiro. The author argues against dimensional analysis (referred to as the "unitary conversion method" in this article) and champions the more elegant "ratio" or "equality" paradigms as a way to help students make sense of chemical equations and "de-algorithmize" chemical calculations at the introductory level. Ochiai, El-Ichiro. J. Chem. Educ. 1993, 70, 44.
Chemometrics
|
Is Dimensional Analysis the Best We Have to Offer? Canagaratna, Sebastian G. Dimensional analysis is a unit based approach while the alternative, "method of equations" is a relations-based approach to solving mathematical problems. The author argues that quantitative chemistry involves relationships between quantities and not units, making the later method more pedagogically sound. Canagaratna, Sebastian G. J. Chem. Educ. 1993, 70, 40.
Chemometrics
|
Applying a simple linear least-squares algorithm to data with uncertainties in both variables Ogren, Paul J.; Norton, J. Russell There are cases in which it is desirable to find an optimum linear least-squares fit to data with significant uncertainties in both the x and y variables. Ogren, Paul J.; Norton, J. Russell J. Chem. Educ. 1992, 69, A130.
Chemometrics
|
An hydrogen sulfide free analytical technique for cation analysis: The statistical approach Gaggero, Fernando Labandera; Luaces, Victor Martinez In this analysis the study of each cation was carried out independently without taking into account the other cations present in the solutions. Gaggero, Fernando Labandera; Luaces, Victor Martinez J. Chem. Educ. 1992, 69, 934.
Chemometrics |
Qualitative Analysis |
Precipitation / Solubility
|
Classroom experience: Using estimated answers in solving chemistry problems Green, Michael E.; Garland, Denise A. A textbook is described in which students solve all problems by estimation. Green, Michael E.; Garland, Denise A. J. Chem. Educ. 1992, 69, 898.
Chemometrics |
Learning Theories
|
On the chemically impossible "other" roots in equilibrium calculations, II Ludwig, Oliver G. In a previous paper the author described, using mathematics accessible to students, how an equilibrium calculation leading to a quadratic equation may be shown to have but one "chemical" root. The present work extends this demonstration to some reactions leading to cubic equations. Ludwig, Oliver G. J. Chem. Educ. 1992, 69, 884.
Chemometrics |
Equilibrium
|
The metric system Mason, Lynn M. Metric conversions commonly encountered in chemistry and biology, with tests over each lesson. Mason, Lynn M. J. Chem. Educ. 1992, 69, 818.
Nomenclature / Units / Symbols |
Enrichment / Review Materials |
Chemometrics
|
A demonstration of the molar volume of nitrogen gas Hughes, Elvin, Jr. A graphic illustration and a calculation of the approximate molar volume of nitrogen gas. Hughes, Elvin, Jr. J. Chem. Educ. 1992, 69, 763.
Gases |
Chemometrics
|
Storing solar energy in calcium chloride Wilkins, Curtis C.; Hunter, Norman W.; Pearson, Earl F. Using common chemistry concepts to determine the feasibility of storing solar energy in calcium chloride hexahydrate. Wilkins, Curtis C.; Hunter, Norman W.; Pearson, Earl F. J. Chem. Educ. 1992, 69, 753.
Calorimetry / Thermochemistry |
Stoichiometry |
Chemometrics
|
A graphing activity to freshen up the laboratory Pribyl, Jeffrey R. A laboratory activity designed to address students' difficulties in interpreting data from graphs and tables. Pribyl, Jeffrey R. J. Chem. Educ. 1992, 69, 752.
Chemometrics
|
First-year chemistry laboratory calculations on a spreadsheet Edwards, Paul A.; McKay, J. Brian; Sink, Charles W. 140. A laboratory exercise to introduce students to the use of computers and spreadsheets. Edwards, Paul A.; McKay, J. Brian; Sink, Charles W. J. Chem. Educ. 1992, 69, 648.
Chemometrics
|
A mole of salt crystals-Or how big is the Avogadro number? Hoyt, William. Calculations designed to help students put the size of Avogadro's number into perspective. Hoyt, William. J. Chem. Educ. 1992, 69, 496.
Nomenclature / Units / Symbols |
Chemometrics
|
A simple but effective demonstration for illustrating significant figure rules when making measurements and doing calculations Zipp, Arden P. Students can be surprised and confused when different arithmetical operations are performed on experimental data, because the rules change when changing from addition to subtraction to multiplication or division. The following is a simple way to illustrate several aspects of these rules. Zipp, Arden P. J. Chem. Educ. 1992, 69, 291.
Chemometrics
|
Spreadsheet titration of diprotic acids and bases Breneman, G. L.; Parker, O. J. 133. Bits and pieces, 47. A spreadsheet and chart, set up using Excel, for showing titration curves of any diprotic acid or base is described. Breneman, G. L.; Parker, O. J. J. Chem. Educ. 1992, 69, 46.
Acids / Bases |
Chemometrics |
Titration / Volumetric Analysis
|
Having fun with the metric system Campbell, Mark L. A puzzle adds some fun to the mundane treatment of the metric system. Campbell, Mark L. J. Chem. Educ. 1991, 68, 1043.
Chemometrics
|
Some conundrums of chemical nomenclature Quigley, Michael N. When talking about chemistry, we use some awfully confusing terms that warrant scrutiny. Quigley, Michael N. J. Chem. Educ. 1991, 68, 1009.
Chemometrics
|
The development of statistical concepts in a design-oriented laboratory course in scientific measuring Goedhart, Martin J.; Verdonk, Adri H. This article offers a contribution to the development of curriculum that includes design and evaluation of measurements. Goedhart, Martin J.; Verdonk, Adri H. J. Chem. Educ. 1991, 68, 1005.
Chemometrics
|
Chemical equations are actually matrix equations Alberty, Robert A. Chemists tend to think that chemical equations are unique to chemistry and they are not used to thinking of chemical equations as the mathematical equations they in fact are. The objective of this paper is to illustrate the mathematical significance of chemical equations. Alberty, Robert A. J. Chem. Educ. 1991, 68, 984.
Stoichiometry |
Chemometrics
|
KC? Discoverer: Exploring the properties of the chemical elements Liebel, Michael This software program allows users to explore a large number of properties of the elements. The program can find all elements associated with a certain property, graph numeric properties against other numeric properties, list elements, sort elements, and use the periodic table to select elements. Liebel, Michael J. Chem. Educ. 1991, 68, 956.
Periodicity / Periodic Table |
Physical Properties |
Chemometrics |
Descriptive Chemistry
|
A carbonate project introducing students to the chemistry lab Dudek, Emily A description of a first semester general chemistry laboratory that helps acquaint students with a large variety of chemistry laboratory procedures. Dudek, Emily J. Chem. Educ. 1991, 68, 948.
Chemometrics |
Gravimetric Analysis |
Titration / Volumetric Analysis |
Separation Science
|
The use of "marathon" problems as effective vehicles for the presentation of general chemistry lectures Burness, James H. A marathon problem is a long, comprehensive, and difficult problem that ties together many of the topics in a chapter and that is solved together by the instructor and students. Sample problems are included and advantages and disadvantages of this approach are discussed. Burness, James H. J. Chem. Educ. 1991, 68, 919.
Chemometrics
|
An SI mnemonic Quigley, M. N. A mnemonic to help remember the physical quantities associated with the nine base SI units. Quigley, M. N. J. Chem. Educ. 1991, 68, 815.
Chemometrics
|
Developmental instruction: Part II. Application of the Perry model to general chemistry Finster, David C. The Perry scheme offers a framework in which teachers can understand how students make meaning of their world, and specific examples on how instructors need to teach these students so that the students can advance as learners. Finster, David C. J. Chem. Educ. 1991, 68, 752.
Learning Theories |
Atomic Properties / Structure |
Chemometrics |
Descriptive Chemistry
|
Grafit Lisensky, George C. A data manipulation tool and plotting program useful at all levels of chemistry. Lisensky, George C. J. Chem. Educ. 1991, 68, 587.
Laboratory Computing / Interfacing |
Chemometrics
|
Space-filling P-V-T models Hilton, Don B. Space-filling models help beginning students visualize the numerical aspects of the empirical gas laws. Hilton, Don B. J. Chem. Educ. 1991, 68, 496.
Gases |
Noncovalent Interactions |
Kinetic-Molecular Theory |
Chemometrics
|
When figures signify nothing Ahmad, Jamil Significant figures in the "real world" set poor standards and confusing examples for chemistry students. Ahmad, Jamil J. Chem. Educ. 1991, 68, 469.
Chemometrics
|
Solving quadratic equations to the correct number of significant figures Thomas, Rudolf Presenting an application of the successive approximations method for solving quadratic or higher order expressions. Thomas, Rudolf J. Chem. Educ. 1991, 68, 409.
Equilibrium |
Chemometrics
|
Is 8C equal to 50F? Thompson, H. Bradford A play, commentary, modest proposal, and a "less modest" proposal regarding calculations and significant figures. Thompson, H. Bradford J. Chem. Educ. 1991, 68, 400.
Chemometrics
|
The effect of context on the translation of sentences into algebraic equations Niaz, Mansoor; Herron, J. Dudley; Phelps, Amy J. Assessing students in a one-semester preparatory chemistry course to see how well students understand proportional relationships. Niaz, Mansoor; Herron, J. Dudley; Phelps, Amy J. J. Chem. Educ. 1991, 68, 306.
Chemometrics
|
Chemical equilibrium: III. A few math tricks Gordus, Adon A. The third article in a series on chemical equilibrium that considers a few math "tricks" useful in equilibrium calculations and approximations. Gordus, Adon A. J. Chem. Educ. 1991, 68, 291.
Acids / Bases |
Equilibrium |
Chemometrics |
Titration / Volumetric Analysis
|
Chemical equilibrium: II. Deriving an exact equilibrium equation Gordus, Adon A. In this article appearing in a series on chemical equilibrium, authors consider how to derive a completely general equation for any chemical mixture. Gordus, Adon A. J. Chem. Educ. 1991, 68, 215.
Equilibrium |
Chemometrics
|
A simple first-order consecutive rate reaction: A different method for its solution Hughes, Elvin, Jr. Power series methods should be used whenever possible in chemistry courses. Hughes, Elvin, Jr. J. Chem. Educ. 1991, 68, 180.
Chemometrics |
Equilibrium
|
A simple first-order consecutive rate reaction: A different method for its solution Castillo S., Carlos; Micolta S., Germania A different way to present an equilibrium equation that appeared previously in this Journal. Castillo S., Carlos; Micolta S., Germania J. Chem. Educ. 1991, 68, 179.
Chemometrics |
Equilibrium
|
Finding largest common factors and simplest integer ratios Macomber, Roger S. General chemistry students can ease some of their math-phobia with an exam question that deals with a familiar topic prior to putting these same mathematical principles into the context of chemistry. Macomber, Roger S. J. Chem. Educ. 1991, 68, 42.
Chemometrics
|
SEQS 3.0 Student Version Simultaneous Equation Solver (Tucker, Edwin E.) Dierenfeldt, K.E. SEQS 3.0 is a program of considerable versatility for solving sets of nonlinear simultaneous equations. Dierenfeldt, K.E. J. Chem. Educ. 1990, 67, A149.
Chemometrics
|
A classroom experiment using the Pythagorean theorem in a discussion of the scientific method Sauls, Frederic, C. Experiment to verify the Pythagorean theorem as a means of introducing the importance of accurate measurements, accuracy and error. Sauls, Frederic, C. J. Chem. Educ. 1990, 67, 958.
Nonmajor Courses |
Chemometrics
|
Accuracy of measurements and the U.S. Census Gorin, George Some aspects of taking the Census can help students to understand the problem of measurement error and the use of significant figures. Gorin, George J. Chem. Educ. 1990, 67, 936.
Chemometrics
|
Lessons learned from Lord Rayleigh on the importance of data analysis Larsen, Russell D. Analysis of the data collected by Lord Rayleigh in association with his discovery of argon presented as a model for scientific inquiry. Larsen, Russell D. J. Chem. Educ. 1990, 67, 925.
Chemometrics |
Atmospheric Chemistry
|
ChemCalc: A scientific calculator Allendoerfer, Robert D. A scientific calculator program that can be used as a stand-alone or incorporated into other software written in BASIC. Allendoerfer, Robert D. J. Chem. Educ. 1990, 67, 770.
Chemometrics
|
A straightforward derivation of stoichiometric mass relationships Gorin, George An alternative to the factor label method for solving stoichiometric mass relationship problems. Gorin, George J. Chem. Educ. 1990, 67, 762.
Stoichiometry |
Chemometrics
|
A significant example: How many days in a century? Lisensky, George Calculating the number of days in a century can help clarify the subject of significant figures. Lisensky, George J. Chem. Educ. 1990, 67, 562.
Nomenclature / Units / Symbols |
Chemometrics
|
Dynamic data storage in FORTRAN Chung-Phillips, Alice 115. Bits and pieces, 44. The purpose of this article is to promote the use of dynamic storage allocation in FORTRAN to chemistry instructors and students in the present computing environment. Chung-Phillips, Alice J. Chem. Educ. 1990, 67, 500.
Chemometrics
|
Solving quadratic equations Brown, R. J. C. A better technique than the quadratic equation for chemical equilibria is offered here. Brown, R. J. C. J. Chem. Educ. 1990, 67, 409.
Chemometrics |
Equilibrium
|
Introduction to experiment design for chemists Strange, Ronald S. One purpose of this paper is to review basic concepts and terminology of experimental design, analysis of data, and optimization. Strange, Ronald S. J. Chem. Educ. 1990, 67, 113.
Chemometrics
|
Exception to solving chem problems without the factor-label approach (the author replies) Cardulla, Frank There are other ways to teach problem solving, and they can produce competent, successful, and enthusiastic students. Cardulla, Frank J. Chem. Educ. 1989, 66, 1066.
Chemometrics |
Nomenclature / Units / Symbols
|
Exception to solving chem problems without the factor-label approach Gillette, Marcia L. The classroom analogy Cardulla uses could be made much more meaningful if it were used to demonstrate the relation between what is obvious and what is not. Gillette, Marcia L. J. Chem. Educ. 1989, 66, 1065.
Chemometrics |
Nomenclature / Units / Symbols
|
The acid-base package: A collection of useful programs for proton-transfer systems Hawkes, Stephen J. Four programs that deal with the types of acid-base calculations normally encountered in introductory and analytical chemistry courses. Hawkes, Stephen J. J. Chem. Educ. 1989, 66, 830.
Acids / Bases |
Chemometrics
|
Atlantic-Pacific sig figs Stone, Helen M. Examples of applications of significant figures in calculations. Stone, Helen M. J. Chem. Educ. 1989, 66, 829.
Nomenclature / Units / Symbols |
Chemometrics
|
How to visualize Avogadro's number van Lubeck, Henk Three examples to help students visualize the size of a mole. van Lubeck, Henk J. Chem. Educ. 1989, 66, 762.
Nomenclature / Units / Symbols |
Chemometrics
|
Significant figure rules for general arithmetic functions Graham, D. M. Rules for determining what happens to the number of significant figures as various types of mathematical operations are performed upon certain quantities. Graham, D. M. J. Chem. Educ. 1989, 66, 573.
Chemometrics
|
A stoichiometric journey Molle, Brian A story to help students overcome some of the difficulties they encounter in stoichiometry calculations. Molle, Brian J. Chem. Educ. 1989, 66, 561.
Stoichiometry |
Chemometrics
|
Being a participant in the future Parker, O. Jerry Integrating computer technology into undergraduate chemistry courses. Parker, O. Jerry J. Chem. Educ. 1989, 66, 500.
Administrative Issues |
Chemometrics
|
The relationship between M-demand, algorithms, and problem solving: A neo-Piagetian analysis Niaz, Mansoor One of the most important implements developed by the neo-Piagetian theory is task analysis, that is, the evaluation of the M-demand of a problem. M-demand can be defined as: maximum number of steps that the subject must mobilize simultaneously in in the course of executing a task. Niaz, Mansoor J. Chem. Educ. 1989, 66, 422.
Learning Theories |
Chemometrics
|
Significant Figures and Error Propagation West, Allen C. Schwartz is wrong to say that 125 mL +/- 5% means a systematic error of +/-5%. West, Allen C. J. Chem. Educ. 1989, 66, 272.
Chemometrics
|
Accurate equations of state in computational chemistry projects Allbee, David; Jones, Edward 101. This article presents one method that allows students to become familiar with the use of modern equations of state and also enhances their understanding of how computers can be used in the study and application of chemistry. [Includes "Editor's note: Changes in the computer series", by Lagowski, J. J., p. 226] Allbee, David; Jones, Edward J. Chem. Educ. 1989, 66, 226.
Applications of Chemistry |
Chemometrics
|
Visible spectrophotometric determination of the partition coefficient of methyl violet: A microscale extraction experiment Sonnenberger, David C.; Ferroni, Edward L. This experiment is designed to demonstrate the principles of separation by solvent extraction, partition coefficient, and the construction and use of a Beer-Lambert standard curve. Sonnenberger, David C.; Ferroni, Edward L. J. Chem. Educ. 1989, 66, 91.
Separation Science |
Chemometrics
|
Graphical analysis III (Vernier, David L.) Carpenter, Jeanette; Bowers, Caroline H. Two reviews of a complete graphing tool suitable for high school and college applications with a wide range of operations varying in complexity. Carpenter, Jeanette; Bowers, Caroline H. J. Chem. Educ. 1988, 65, A269.
Chemometrics
|
Chemistry according to ROF (Fee, Richard) Radcliffe, George; Mackenzie, Norma N. Two reviews on a software package that consists of 68 programs on 17 disks plus an administrative disk geared toward acquainting students with fundamental chemistry content. For instance, acids and bases, significant figures, electron configuration, chemical structures, bonding, phases, and more. Radcliffe, George; Mackenzie, Norma N. J. Chem. Educ. 1988, 65, A239.
Chemometrics |
Atomic Properties / Structure |
Equilibrium |
Periodicity / Periodic Table |
Periodicity / Periodic Table |
Stoichiometry |
Physical Properties |
Acids / Bases |
Covalent Bonding
|
Analysis of kinetic data with a spreadsheet program Henderson, John An article about spreadsheet templates that accept concentration versus time data for several runs of an experiment, determination of least-squares lines through data points for each run, and will allow the user to exclude points from the least-squares calculation. Henderson, John J. Chem. Educ. 1988, 65, A150.
Chemometrics |
Laboratory Computing / Interfacing |
UV-Vis Spectroscopy |
Rate Law |
Kinetics |
Enzymes
|
Teaching students to use algorithms for solving generic and harder problems in general chemistry Kean, Elizabeth; Middlecamp, Catherine Hurt; Scott, D. L. This paper describes teaching strategies that help students improve their problem-solving skills. Kean, Elizabeth; Middlecamp, Catherine Hurt; Scott, D. L. J. Chem. Educ. 1988, 65, 987.
Stoichiometry |
Chemometrics
|
Let's separate theories from calculations Freilich, Mark B. This author writes in a 'provocative opinion' article challenging the readers to think about heavily emphasizing 'thought problems' in chemistry and allowing students to master those before throwing calculations into the mix. Freilich, Mark B. J. Chem. Educ. 1988, 65, 442.
Chemometrics
|
An alternative to using the PV = nRT equation Desmarais, George This author shares his application of the factor-label method to solving gas problems which involves using the ideal gas constant as the starting point in the relationship. Desmarais, George J. Chem. Educ. 1988, 65, 392.
Gases |
Stoichiometry |
Chemometrics
|
Avogadro's number: A perverse view Lehman, Thomas A. A way to think of Avogadro's number: take anything and double it 79 times. Lehman, Thomas A. J. Chem. Educ. 1988, 65, 282.
Chemometrics |
Stoichiometry
|
Remember E = hv is correct only half of the time Leo, Howard, R. Reminder that the title equation (Planck) is not algebraically correct. Leo, Howard, R. J. Chem. Educ. 1988, 65, 11.
Chemometrics |
Photochemistry
|
Good numerical technique in chemistry: The quadratic equation Thompson, H. Bradford Texts commonly avoid examples with bad round-off problems or handle them by approximation; none of this is necessary, for simple techniques are available to handle quadratic equations easily and precisely. Thompson, H. Bradford J. Chem. Educ. 1987, 64, 1009.
Chemometrics
|
Reaction stoichiometry and suitable "coordinate systems" Tykodi, R. J. Methods for dealing with problems involving reactions stoichiometry: unitize and scale up, factor-label procedure, de Donder ratios, and titration relations. Tykodi, R. J. J. Chem. Educ. 1987, 64, 958.
Stoichiometry |
Titration / Volumetric Analysis |
Chemometrics
|
Hard ways and easy ways Schwartz, Lowell M. Two examples of common general chemistry calculations and different approaches ("hard" and "easy") to solving them. Schwartz, Lowell M. J. Chem. Educ. 1987, 64, 698.
Stoichiometry |
Chemometrics
|
Solving limiting reagent problems (the author replies) Kalantar, A. H. Thanks for clarification and suggestion. Kalantar, A. H. J. Chem. Educ. 1987, 64, 472.
Stoichiometry |
Chemometrics
|
Solving limiting reagent problems Skovlin, Dean O. Uncertainty in the meaning of the term X. Skovlin, Dean O. J. Chem. Educ. 1987, 64, 472.
Stoichiometry |
Chemometrics
|
Statistical evaluation of class data for two buret readings Gordus, Adon A. Data that serve to illustrate both random and systematic errors in measurements characteristic of titrations. Gordus, Adon A. J. Chem. Educ. 1987, 64, 376.
Chemometrics |
Titration / Volumetric Analysis
|
Mole fraction revisited Mancott, A. This problem requires the use of algebraic reasoning to derive and solve a fraction linear equation based on the concept of moles and conservation of moles. Mancott, A. J. Chem. Educ. 1987, 64, 320.
Stoichiometry |
Chemometrics
|
Slopes of straight lines when neither axis is error free Kalantar, A. H. The iterative effective variance method is not reliable and its use is pedagogically unwise. Kalantar, A. H. J. Chem. Educ. 1987, 64, 28.
Chemometrics
|
The length of a pestle: A class exercise in measurement and statistical analysis O'Reilly, James E. Too many students get through chemistry without acquiring a basic understanding and appreciation of the concepts of measurement science. The purpose of this report is to outline an extremely simple class exercise as a concrete paradigm of the entire process of making chemical measurements and treating data. O'Reilly, James E. J. Chem. Educ. 1986, 63, 894.
Chemometrics
|
Calculation of Madelung constants in the first year chemistry course Elert, Mark; Koubek, Edward 76. Bits and pieces, 31. A computer program aids in understanding the nature of the Madelung constants. Elert, Mark; Koubek, Edward J. Chem. Educ. 1986, 63, 840.
Crystals / Crystallography |
Chemometrics
|
Teaching significant figures using a learning cycle Guymon, E. Park; James, Helen J.; Saeger, Spencer L. Can we teach significant figures in a way that will be better retained by our students? These authors propose a solution. Guymon, E. Park; James, Helen J.; Saeger, Spencer L. J. Chem. Educ. 1986, 63, 786.
Learning Theories |
Chemometrics
|
A flowchart for dimensional analysis Graham, D. M. A flowchart to help students organize their thoughts when solving conversion problems. Graham, D. M. J. Chem. Educ. 1986, 63, 527.
Chemometrics |
Nomenclature / Units / Symbols |
Stoichiometry
|
Where did that number come from? DeLorenzo, Ronald With more careful labeling and handling of numbers, instructors can reduce the confusion students sometimes feel when watching problems being solved by the instructor on the board. DeLorenzo, Ronald J. Chem. Educ. 1986, 63, 514.
Chemometrics |
Nomenclature / Units / Symbols
|
Factor-label: Another view Maloy, Joseph T. It is of interest to our students' academic development that we teach them the mathematical theory behind factor label approaches to problems solving. Maloy, Joseph T. J. Chem. Educ. 1986, 63, 186.
Chemometrics
|
Unit basis a neglected problem-solving technique Beichl, George J. A technique that will prevent students from using ineffective problem-solving techniques such as dimensional analysis. Beichl, George J. J. Chem. Educ. 1986, 63, 146.
Chemometrics |
Stoichiometry
|
On writing equations Campbell, J.A. The author presents a very direct approach to writing complicated equations without using a matrix approach. Campbell, J.A. J. Chem. Educ. 1986, 63, 63.
Stoichiometry |
Chemometrics
|
An interactive, screen-oriented, general linear regression program Joshi, Bhairav D. 65. Bits and pieces, 26. Description of GSLINE, a program runs linear regressions. Joshi, Bhairav D. J. Chem. Educ. 1985, 62, 1027.
Chemometrics
|
Mathematics in the chemistry classroom. Part 2. Elementary entities play their part Dierks, Werner; Weninger, Johann; Herron, J. Dudley One of the problems that learners have to overcome when doing stoichiometry calculations is to learn how statements about elementary entities given by formulas and equations are related to statements about portions of substances as measured in the macroscopic world. Dierks, Werner; Weninger, Johann; Herron, J. Dudley J. Chem. Educ. 1985, 62, 1021.
Chemometrics |
Stoichiometry
|
Pandemonium pesticide: A simple demonstration illustrating some fundamental chemical concepts Kauffman, George B.; Chooljian, Steven H.; Ebner, Ronald D. Demonstration that uses large, visible particles to simulate calculations of atomic / molecular mass, percentage composition, and molecular formula. Kauffman, George B.; Chooljian, Steven H.; Ebner, Ronald D. J. Chem. Educ. 1985, 62, 870.
Atomic Properties / Structure |
Molecular Properties / Structure |
Stoichiometry |
Chemometrics
|
Mathematics in the chemistry classroom. Part 1. The special nature of quantity equations Dierks, Werner; Weninger, Johann; Herron, J. Dudley Differences between operation on quantities and operation on numbers and how chemical quantities should be described mathematically. Dierks, Werner; Weninger, Johann; Herron, J. Dudley J. Chem. Educ. 1985, 62, 839.
Chemometrics |
Stoichiometry |
Nomenclature / Units / Symbols
|
Determination of molecular dimensions using monolayers: Another approach McNaught, Ian J.; Peckham, Gavin D. A preliminary activity to help students understand the concept and calculations of the determination of molecular dimensions using monolayers. McNaught, Ian J.; Peckham, Gavin D. J. Chem. Educ. 1985, 62, 795.
Molecular Properties / Structure |
Chemometrics
|
Propagation of significant figures Schwartz, Lowell M. The rules of thumb for propagating significant figures through arithmetic calculations frequently yield misleading results. Schwartz, Lowell M. J. Chem. Educ. 1985, 62, 693.
Chemometrics
|
A different look at the solubility-product principle Hugus, Z Z., Jr.; Hentz, F. C., Jr. The progressive addition of Cl- to Ag+ yields an ion-product equal to Ksp at two different points. Hugus, Z Z., Jr.; Hentz, F. C., Jr. J. Chem. Educ. 1985, 62, 645.
Precipitation / Solubility |
Aqueous Solution Chemistry |
Solutions / Solvents |
Chemometrics
|
Working backwards is a forward step in the solution of problems by dimensional analysis Drake, Robert F. Solving chemistry calculations by determining the units of the desired answer and then working backwards using dimensional analysis. Drake, Robert F. J. Chem. Educ. 1985, 62, 414.
Chemometrics |
Nomenclature / Units / Symbols
|
"Chemistry" problems without chemical terminology Ciereszko, Leon S. Three questions analogous to percentage composition and Charles' law calculations. Ciereszko, Leon S. J. Chem. Educ. 1985, 62, 402.
Chemometrics
|
Derivation of the ideal gas law Levine, S. Derivation of the ideal gas law from a thermodynamic influence. Levine, S. J. Chem. Educ. 1985, 62, 399.
Gases |
Thermodynamics |
Chemometrics
|
Using a conversion matrix to simplify stoichiometric calculations from balanced equations Berger, Selman A. Two examples of using a conversion matrix to simplify stoichiometric calculations from balanced equations. Berger, Selman A. J. Chem. Educ. 1985, 62, 396.
Chemometrics |
Stoichiometry
|
Problem-solving skills in chemistry made easier Fast, Kenneth V. Step-by-step format for performing common calculations in chemistry. Fast, Kenneth V. J. Chem. Educ. 1985, 62, 396.
Stoichiometry |
Chemometrics
|
A convenient device to demonstrate statistically based sampling error in a particulate mixture Reid, R. S. Apparatus to demonstrate statistically based sampling error using a mixture of colored beads. Reid, R. S. J. Chem. Educ. 1985, 62, 252.
Chemometrics
|
Why isn't my rain as acidic as yours? Zajicek, O. T. Calculating of pH values of acid rain and comparisons to uncontaminated samples. Zajicek, O. T. J. Chem. Educ. 1985, 62, 158.
Acids / Bases |
Atmospheric Chemistry |
pH |
Chemometrics
|
Limiting reagent problems made simple for students Kalantar, A. H. Method for determining the limiting reagent among three or more reactants. Kalantar, A. H. J. Chem. Educ. 1985, 62, 106.
Stoichiometry |
Chemometrics
|
Five Avogadro's number problems Todd, David Five problems involving Avogadro's number. Todd, David J. Chem. Educ. 1985, 62, 76.
Nomenclature / Units / Symbols |
Stoichiometry |
Chemometrics
|
A LAP on moles: Teaching an important concept Ihde, John The objective of the Learning Activity Packet on moles include understanding the basic concept of the mole as a chemical unit, knowing the relationships between the mole and the atomic weights in the periodic table, and being able to solve basic conversion problems involving grams, moles, atoms, and molecules. [Debut] Ihde, John J. Chem. Educ. 1985, 62, 58.
Stoichiometry |
Nomenclature / Units / Symbols |
Chemometrics |
Atomic Properties / Structure |
Molecular Properties / Structure |
Periodicity / Periodic Table
|
Graphical Analysis, Review II (Dice, David R.) Sievers, Dennis A computerized program that generates graphs of empirical data. Sievers, Dennis J. Chem. Educ. 1984, 61, A324.
Chemometrics
|
Graphical Analysis, Review I (Dice, David R.) Palmer, Glenn E. A computerized program that generates graphs of empirical data. Palmer, Glenn E. J. Chem. Educ. 1984, 61, A323.
Chemometrics
|
The Elements of Style in Chemistry, A Computer-assisted Instruction Supported Text (Beatty, James W.; Beatty, James J.) Crawford, Victor A. Intended to support students who have trouble solving important types of problems in chemistry. Crawford, Victor A. J. Chem. Educ. 1984, 61, A27.
Enrichment / Review Materials |
Chemometrics
|
Uncertainty analysis by the "worst case" method Gordon, Roy; Pickering, Miles; Bisson, Denise A new method of uncertainty propagation that is in many ways superior to the traditional manipulation of absolute and relative uncertainty. Gordon, Roy; Pickering, Miles; Bisson, Denise J. Chem. Educ. 1984, 61, 780.
Chemometrics
|
The factor-label method: Is it all that great? Navidi, Marjorie H.; Baker, A. David The development of reasoning skills in chemistry is better achieved by postponing the introduction of the factor-label method. Navidi, Marjorie H.; Baker, A. David J. Chem. Educ. 1984, 61, 522.
Chemometrics
|
The density of solids Burgess, Dale Using density measurements as an opportunity to discuss experimental procedures, error, and significant figures. Burgess, Dale J. Chem. Educ. 1984, 61, 242.
Chemometrics |
Physical Properties
|
Teaching factor-label method without sleight of hand Garrett, James M. As an aid in teaching the factor-label method, the author has developed a rather simple card game involving the matching of symbols and colors. Garrett, James M. J. Chem. Educ. 1983, 60, 962.
Stoichiometry |
Chemometrics |
Nomenclature / Units / Symbols
|
Reflections upon mathematics in the introductory chemistry course Goodstein, Madeline P. It is the purpose of this paper to call attention to the lack of mathematical competence by chemistry students and to invite consideration of one conceptual scheme which may be used to unify the mathematical approach. Goodstein, Madeline P. J. Chem. Educ. 1983, 60, 665.
Chemometrics |
Gases
|
On the chemically impossible "other" roots in equilibrium problems Ludwig, Oliver G. Students often have a hard time knowing when to disregard equilibrium roots that are too large or are negative. The author suggests a convincing proof that helps students understand how the relationship between the conceptual and mathematical. Ludwig, Oliver G. J. Chem. Educ. 1983, 60, 547.
Equilibrium |
Chemometrics
|
Empirical pKb and pKa for nonmetal hydrides from periodic table position Bayless, Philip L. The equation in this article was developed by the author. It estimates the aqueous pKa for certain acids to an average deviation of 0.1pK unit for those with experimentally determined values and agrees with experimentally determined values, and as well as with estimates for those too weak or too strong to be measured. Bayless, Philip L. J. Chem. Educ. 1983, 60, 546.
Acids / Bases |
pH |
Chemometrics
|
Le Châtelier's principle: the effect of temperature on the solubility of solids in liquids Brice, L. K. The purpose of this article is to provide a rigorous but straightforward thermodynamic treatment of the temperature dependence of solubility of solids in liquids that is suitable for presentation at the undergraduate level. The present discussion may suggest how to approach the qualitative aspects of the subject for freshman. Brice, L. K. J. Chem. Educ. 1983, 60, 387.
Thermodynamics |
Liquids |
Solids |
Chemometrics |
Equilibrium
|
The use of the Warnier-Orr program design method in the preparation of general chemistry tutorials Hach, Edwin E., Jr. 39. In this article, a modified Warnier-Orr approach is illustrated for a computer tutorial involving ideal gas calculations. Hach, Edwin E., Jr. J. Chem. Educ. 1983, 60, 348.
Gases |
Chemometrics
|
The spilled can of paint Perkins, Robert The writer describes a problem for students to work out in order to better understand units of conversion. Perkins, Robert J. Chem. Educ. 1983, 60, 343.
Nomenclature / Units / Symbols |
Chemometrics
|
The liquid silver parade Perkins, Robert The activity described in this note is useful in illustrating how small atoms are to students. Perkins, Robert J. Chem. Educ. 1983, 60, 343.
Stoichiometry |
Chemometrics
|
Titration calculations- a problem-solving approach Waddling, Robin E. L. This author shares a strategy for helping students who might be struggling with understanding how to calculate and understand titration data. Waddling, Robin E. L. J. Chem. Educ. 1983, 60, 230.
Acids / Bases |
Titration / Volumetric Analysis |
Chemometrics
|
Mass spectral analysis of halogen compounds Holdsworth, David K. 37. Bits and pieces, 14. A pocket calculator can be programmed to decide and display the halogen combination in a molecular-ion cluster by examination of the (M+2)/M or (X+2)/X percentage values. Holdsworth, David K. J. Chem. Educ. 1983, 60, 103.
Chemometrics |
Mass Spectrometry
|
A pocket calculator program for the solution of pH problems via the method of successive approximations Guida, Wayne C. 37. Bits and pieces, 14. A description of a pocket calculator program for the solution of pH problems via the method of successive approximations . Guida, Wayne C. J. Chem. Educ. 1983, 60, 101.
pH |
Acids / Bases |
Chemometrics
|
Data generation in the classroom Blanco, Luis H. A pendulum device for generating data for statistical analysis. Blanco, Luis H. J. Chem. Educ. 1982, 59, 1028.
Chemometrics |
Laboratory Equipment / Apparatus
|
The estimation of Avogadro's number using cetyl alcohol as the monolayer Feinstein, H. I.; Sisson, Robert F., III Results and calculations using cetyl alcohol as the monolayer in estimating Avogadro's number. Feinstein, H. I.; Sisson, Robert F., III J. Chem. Educ. 1982, 59, 751.
Stoichiometry |
Molecular Properties / Structure |
Chemometrics
|
Chemical equation balancing: A general method which is quick, simple, and has unexpected applications Blakley, G. R. Using matrices to solve mathematical equations and balance chemical equations. From "The Goals of General Chemistry - A Symposium." Blakley, G. R. J. Chem. Educ. 1982, 59, 728.
Stoichiometry |
Chemometrics
|
Mathematics in data analysis: An introduction Wang, Taitzer The meaning of simple mathematical equations are described in a perspective that, for some reasons, many beginning students do not seem to be able to obtain from reading textbooks on the subject. Wang, Taitzer J. Chem. Educ. 1982, 59, 592.
Chemometrics
|
Recurrent difficulties: Solving quantitative problems Kramers-Pals, H.; Lambrechts, J.; Wolff, P. J. Investigating the process students use to solve quantitative problems using a think aloud strategy. Kramers-Pals, H.; Lambrechts, J.; Wolff, P. J. J. Chem. Educ. 1982, 59, 509.
Chemometrics
|
Remedial mathematics for the introductory chemistry course: The "CHEM. 99" concept Bohning, James J. An approach that is aimed specifically at mathematical deficiencies and based on the premise that the deductive reasoning process that accompanies basic mathematical technique is crucial for a meaningful comprehension of general chemistry principles. Bohning, James J. J. Chem. Educ. 1982, 59, 207.
Chemometrics
|
Buffers Gold, Marvin A demonstration based on buffer calculations. Gold, Marvin J. Chem. Educ. 1982, 59, 155.
Acids / Bases |
Chemometrics
|
Calculation of statistical thermodynamic properties Vicharelli, P. A.; Collins, C. B. 25. Bits and pieces, 9. A computer program for the calculation of specific heat, entropy, enthalpy, and Gibbs free energy of polyatomic molecules. Vicharelli, P. A.; Collins, C. B. J. Chem. Educ. 1982, 59, 131.
Calorimetry / Thermochemistry |
Thermodynamics |
Chemometrics
|
CAI Programs in BASIC and an associated MATH subroutine Anderson, Robert Hunt 25. Bits and pieces, 9. Four BASIC programs involving basic calculations and mathematical problems in chemistry. Anderson, Robert Hunt J. Chem. Educ. 1982, 59, 129.
Chemometrics |
Enrichment / Review Materials
|
Basic mathematics for beginning chemistry (Goldish, Dorthoy M.) Ellison, Herbert R.
Ellison, Herbert R. J. Chem. Educ. 1981, 58, A65.
Chemometrics |
Mathematics / Symbolic Mathematics |
Enrichment / Review Materials
|
Think Wheeler, S. J., James D. Students have an easy enough time crunching numbers, but it is alarming how little they understand the concepts behind the numbers. Students should not be making remarks such as, "If they keep changing how they write the problems, how am I supposed to know how to solve them?" Wheeler, S. J., James D. J. Chem. Educ. 1981, 58, 1004.
Learning Theories |
Chemometrics
|
Small things and large numbers Rosenberg, Milton H. Some challenging solubility problems are featured in this note. Rosenberg, Milton H. J. Chem. Educ. 1981, 58, 962.
Solutions / Solvents |
Equilibrium |
Chemometrics
|
Superlative problems Akers, Hugh A.; Akers, Gwyn E. The data in the Guinness Book of World Records holds great potential for fun, interesting chemistry exercises. Akers, Hugh A.; Akers, Gwyn E. J. Chem. Educ. 1981, 58, 795.
Chemometrics
|
Balancing complex redox equations by inspection Kolb, Doris A step-by-step walk through of the inspection process for balancing equations. Kolb, Doris J. Chem. Educ. 1981, 58, 642.
Stoichiometry |
Chemometrics
|
A statistical note on the time lag method for second-order kinetic rate constants Schwartz, Lowell M. A clever method for finding second-order kinetic rate constants by using a time lag method that avoids direct measurement of the end point reading P(infinity) can easily be programmed. Schwartz, Lowell M. J. Chem. Educ. 1981, 58, 588.
Chemometrics |
Kinetics |
Rate Law
|
A mathematics readiness test for prospective chemistry students Weisman, Rence L. A mathematics readiness test is prepared to determine whether students have the minimum competency necessary to succeed in chemistry. Weisman, Rence L. J. Chem. Educ. 1981, 58, 564.
Chemometrics |
Mathematics / Symbolic Mathematics
|
How big is Avogadro's number (or how small are atoms, molecules and ions) Fulkrod, John E. Calculating the volume occupied by Avogadro's number of drops of water helps students understand the magnitude of this quantity while giving them practice at using scientific notation and the metric system. Fulkrod, John E. J. Chem. Educ. 1981, 58, 508.
Nomenclature / Units / Symbols |
Chemometrics |
Stoichiometry
|
Pressure and the exploding beverage container Perkins, Robert R. The question in this article is an extension of exploding pop bottles to illustrate the balancing of a chemical equation, enthalpy, stoichiometry, and vapor pressure calculations, and the use of the Ideal Gas Equation. The question is aimed at the first-year level student. Perkins, Robert R. J. Chem. Educ. 1981, 58, 363.
Stoichiometry |
Gases |
Thermodynamics |
Chemometrics
|
A specific heat analogy McCullough, Brother Thomas, CSC An analogy for helping students to understand the concepts of specific heat and heat transfer problems. McCullough, Brother Thomas, CSC J. Chem. Educ. 1980, 57, 896.
Calorimetry / Thermochemistry |
Chemometrics
|
Sweet heat O'Connor, Rod What would be the net enthalpy change for the complete combustion of 5.00 g of glucose at body temperature? O'Connor, Rod J. Chem. Educ. 1980, 57, 889.
Carbohydrates |
Calorimetry / Thermochemistry |
Chemometrics
|
Teaching and learning problem solving in science. Part I: A general strategy Mettes, C. T. C. W.; Pilot, A.; Roossink, H. J.; Kramers-Pals, H. A systematic approach to solving problems and on designing instruction where students learn this approach. Mettes, C. T. C. W.; Pilot, A.; Roossink, H. J.; Kramers-Pals, H. J. Chem. Educ. 1980, 57, 882.
Chemometrics
|
Empirical formulas - A ratio problem Knox, Kerro A problem involving an analogy between ratios of boys to girls given their average weights and percentage composition of the class by weight. Knox, Kerro J. Chem. Educ. 1980, 57, 879.
Chemometrics |
Molecular Properties / Structure
|
Mole fraction analogies DeLorenzo, Ron An analogy to help students solve concentration problems. DeLorenzo, Ron J. Chem. Educ. 1980, 57, 733.
Stoichiometry |
Chemometrics |
Solutions / Solvents
|
Dissociation of a weak acid Ladd, M. F. C. An earlier treatment of the equilibrium of a weak acid in water gives, for certain ranges of concentration, significantly incorrect results. Ladd, M. F. C. J. Chem. Educ. 1980, 57, 669.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Chemometrics
|
A "road map" problem for freshman chemistry students Burness, James H. Question suitable for a take-home type of exam. Burness, James H. J. Chem. Educ. 1980, 57, 647.
Gases |
Solutions / Solvents |
Stoichiometry |
Nomenclature / Units / Symbols |
Chemometrics
|
Significant figures: Removing the zero mystique Treptow, Richard S. Zeros are significant if they appear before a number takes on size or as stand-ins for unknown digits. Treptow, Richard S. J. Chem. Educ. 1980, 57, 646.
Chemometrics
|
Whatever became of significant figures? The trend toward numerical illiteracy Anderlik, Barbara How does one persuade students, when working with physical measurements, to part with excess digits and become numerically literate. Anderlik, Barbara J. Chem. Educ. 1980, 57, 591.
Chemometrics
|
An illustration to demonstrate the smallness of molecules Kingston, David W. An exercise in dimensional analysis. Kingston, David W. J. Chem. Educ. 1980, 57, 506.
Chemometrics
|
Correlating Celsius and Fahrenheit temperatures by the "unit calculus" Gorin, George Deriving the mathematical relationship between Celsius and Fahrenheit temperatures. Gorin, George J. Chem. Educ. 1980, 57, 350.
Nomenclature / Units / Symbols |
Chemometrics
|
Adopting SI units in introductory chemistry Davies, William G.; Moore, John W. Conventions associated with SI units, conversion relationships commonly used in chemistry, and a roadmap method for solving stoichiometry problems. Davies, William G.; Moore, John W. J. Chem. Educ. 1980, 57, 303.
Nomenclature / Units / Symbols |
Chemometrics
|
Adding another dimension to dimensional analysis DeLorenzo, Ronald Adding words to typical dimensional analysis work to improve understanding and communication. DeLorenzo, Ronald J. Chem. Educ. 1980, 57, 302.
Chemometrics
|
Significant digits: Numbers and their logarithms Clever, H. Lawrence The number of digits to report in a base 10 logarithm is an unresolved problem for many students. Clever, H. Lawrence J. Chem. Educ. 1979, 56, 824.
Chemometrics |
pH
|
The physically meaningful solution of the quadratic equation Levy, Mel; Byers, Larry D. Shows that the potential ambiguity of two unequal but physically meaningful roots never arises. Levy, Mel; Byers, Larry D. J. Chem. Educ. 1979, 56, 526.
Chemometrics
|
Calculators in freshman chemistry - An alternative view Gold, Marvin There is a serious negative aspect to allowing freshmen use of calculators in chemistry. Gold, Marvin J. Chem. Educ. 1979, 56, 526.
Chemometrics
|
Measurement errors: A lecture demonstration Munn, Robert J. A lecture demonstration to realistically discuss precision, accuracy, averaging, data rejection, and significant digits. Munn, Robert J. J. Chem. Educ. 1979, 56, 267.
Chemometrics
|
How many significant digits in 0.05C? Power, James D. Textbooks abound with erroneous examples, such as 33F = 0.56C. Power, James D. J. Chem. Educ. 1979, 56, 239.
Chemometrics |
Nomenclature / Units / Symbols
|
Calculators, slide rules, and significant figures McCullough, Thomas, CSC Using a slide rule to help students understand the concept of significant figures before using a calculator. McCullough, Thomas, CSC J. Chem. Educ. 1979, 56, 238.
Chemometrics
|
Intuitive and general approach to acid-base equilibrium calculations Felty, Wayne L. The purpose of this paper is to show that the usual intuitive approach used in general chemistry can be readily extended without introduction of additional, sophisticated concepts to give the general, exact expression and to point out the pedagogical advantage of its use. Felty, Wayne L. J. Chem. Educ. 1978, 55, 576.
Acids / Bases |
Equilibrium |
Chemometrics
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Pressure calculations Schultz, Charles W. This question requires students to be able to distinguish two kinds of pressure: Boyles law pressure of gas (that depends on volume) from the equilibrium vapor pressure above a liquid (that does not). Schultz, Charles W. J. Chem. Educ. 1978, 55, 515.
Gases |
Chemometrics
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Balancing an atypical redox equation Carrano, S. A. The author presents a particularly tricky redox problem and walks readers through a solution. Carrano, S. A. J. Chem. Educ. 1978, 55, 382.
Chemometrics |
Oxidation / Reduction |
Stoichiometry
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Chemical predictions from pKa values Hassanali, A. The problem presented here develops student understanding of both pKa calculations and organic acids. Hassanali, A. J. Chem. Educ. 1978, 55, 378.
Acids / Bases |
pH |
Chemometrics
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Teaching the method of successive approximations Nassiff, Peter J.; Boyko, E. R. The purpose of this papers is to help the teacher show the student why basic methods of successive approximations work, how they may be applied, and under what conditions it will be successful. Nassiff, Peter J.; Boyko, E. R. J. Chem. Educ. 1978, 55, 376.
Chemometrics |
Acids / Bases |
Gases
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Collision theory Myers, Richard S. The question presented here can be employed in general or physical chemistry courses. Myers, Richard S. J. Chem. Educ. 1978, 55, 243.
Chemometrics |
Thermodynamics |
Kinetics
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The chemical equation. Part I: Simple reactions Kolb, Doris A chemical equation is often misunderstood by students as an "equation" that is used in chemistry. However, a more accurate description is that it is a concise statement describing a chemical reaction expressed in chemical symbolism. Kolb, Doris J. Chem. Educ. 1978, 55, 184.
Stoichiometry |
Chemometrics |
Nomenclature / Units / Symbols |
Reactions
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A pre-general chemistry course for the underprepared student Krannich, Larry K.; Patick, David; Pevear, Jesse Outline and evaluation of a course in chemical problem solving. Krannich, Larry K.; Patick, David; Pevear, Jesse J. Chem. Educ. 1977, 54, 730.
Enrichment / Review Materials |
Chemometrics
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Chemical equilibrium: Analogies that separate the mathematics from the chemistry DeLorenzo, Ronald A. Demonstrates that the mathematics of chemical equilibria are not difficult, particularly when put in a non-chemical context. DeLorenzo, Ronald A. J. Chem. Educ. 1977, 54, 676.
Equilibrium |
Chemometrics
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On significant figures MacCarthy, Patrick Illustrating the decrease in uncertainty that accompanies an increase in significant figures. MacCarthy, Patrick J. Chem. Educ. 1977, 54, 578.
Chemometrics
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Simple classroom experiment on uncertainty of measurement Sen, B. This activity demonstrates several aspects regarding the statistical treatment of data. Sen, B. J. Chem. Educ. 1977, 54, 468.
Chemometrics
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Calculators and significant figures Satek, Larry C. A demonstration on the topic of significant figures and random errors. Satek, Larry C. J. Chem. Educ. 1977, 54, 177.
Chemometrics
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Cookbook dimensional analysis DeLorenzo, Ronald Frequently, teachers will hear, "...it looks easy when you do it..." when teaching dimensional analysis. This teacher advises others on a way to help students gain self-efficacy with this problem solving-strategy. DeLorenzo, Ronald J. Chem. Educ. 1976, 53, 633.
Stoichiometry |
Chemometrics
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A criterion for the simple approximation in dissociation equilibria Leffler, Amos J. The author demonstrates quantitative criterion for the assumption that permits the neglect of the amount of dissociated species in the denominator of the dissociation equation. Leffler, Amos J. J. Chem. Educ. 1976, 53, 460.
Acids / Bases |
Equilibrium |
Chemometrics
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A logic diagram for teaching stoichiometry Tyndall, John R. Presents a diagram that the author found helpful in teaching the fundamentals of stoichiometry. Tyndall, John R. J. Chem. Educ. 1975, 52, 492.
Stoichiometry |
Chemometrics
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Maximizing profits in equilibrium processes Rish, Ronald J. Provides the student with an example in which both chemical principles and calculus are applied to a realistic industrial situation where profits are a must. Rish, Ronald J. J. Chem. Educ. 1975, 52, 441.
Equilibrium |
Industrial Chemistry |
Chemometrics
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Molar solubility calculations and the control equilibrium Chaston, S. H. H. The Control-Equilibrium method uses as its starting point a precise procedure for obtaining the equilibrium that accounts for the bulk of the decomposition of starting materials. Chaston, S. H. H. J. Chem. Educ. 1975, 52, 206.
Solutions / Solvents |
Chemometrics |
Equilibrium
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Illustrating large and small numbers. A problem for the birds Sattler, Louis A calculation designed to illustrate the relative size of Avogadro's number. The solution from p. 181 is reproduced in this PDF. Sattler, Louis J. Chem. Educ. 1975, 52, 180.
Chemometrics |
Stoichiometry
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FeSCN2+ - A computer aid to the CHEM Study experiment McCall, Arthur J., Jr. A Fortran program assists in making the calculations that accompany investigation of the iron(III)thiocyanate equilibrium system. McCall, Arthur J., Jr. J. Chem. Educ. 1975, 52, 118.
Equilibrium |
Aqueous Solution Chemistry |
Chemometrics
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Discussion: Mathematics in the first-year chemistry course Richter, G. P. Report of the Third Biennial Conference on Chemical Education and the Second Centennial of Chemistry Celebration. Richter, G. P. J. Chem. Educ. 1975, 52, 19.
Conferences |
Professional Development |
Chemometrics
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A computer program for heat of combustion calculations Wilhoit, Randolph C.; Bell, Mary Ellen; Subach, Daniel J.; Chen, Carol A computer program is available for converting raw combustion data to the standard state energy of combustion. Wilhoit, Randolph C.; Bell, Mary Ellen; Subach, Daniel J.; Chen, Carol J. Chem. Educ. 1973, 50, 486.
Calorimetry / Thermochemistry |
Chemometrics
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A quick scored item analysis for objective tests Stokes, Jimmy C.; Strickland, James F., Jr. Analyzing test data with students in the classroom. Stokes, Jimmy C.; Strickland, James F., Jr. J. Chem. Educ. 1973, 50, 354.
Chemometrics
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Enthalpy and entropy of evaporation from measured vapor pressure using a programmable desk calculator McEachern, Douglas M. A program for a calculator that calculates the heat of evaporation of a solid or a liquid and the corresponding entropy change. McEachern, Douglas M. J. Chem. Educ. 1973, 50, 190.
Calorimetry / Thermochemistry |
Thermodynamics |
Phases / Phase Transitions / Diagrams |
Chemometrics
|
Problem solving for chemistry (Peters, Edward I.) Fiekers, Bernard A., S. J.
Fiekers, Bernard A., S. J. J. Chem. Educ. 1972, 49, A491.
Chemometrics
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Chemical calculations (Benson, Sidney W.) Melgaard, Kennett G.
Melgaard, Kennett G. J. Chem. Educ. 1972, 49, A98.
Chemometrics
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Significant digits in logarithm-antilogarithm interconversions Jones, Donald E. Most textbooks are in error in the proper use of significant digits when interconverting logarithms and antilogarithms. Jones, Donald E. J. Chem. Educ. 1972, 49, 753.
Nomenclature / Units / Symbols |
Chemometrics
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A "relevant" first experiment for freshman chemistry laboratory Macomber, Roger S. This activity involves popping corn and introduces students to the processes of observation and inference as well as the use of the analytical balance and gravimetric procedure. Macomber, Roger S. J. Chem. Educ. 1972, 49, 714.
Chemometrics
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An interactive program for teaching pH and logarithms Eskinazi, Jak; Macero, Daniel J. A computer program written in APL for teaching students logarithms and pH calculations. Eskinazi, Jak; Macero, Daniel J. J. Chem. Educ. 1972, 49, 571.
pH |
Acids / Bases |
Chemometrics
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The two-place logarithm table. An aid to understanding and use of logarithms Freiser, Henry Presents a two-place logarithm table that serves to aid the understanding and use of logarithms. Freiser, Henry J. Chem. Educ. 1972, 49, 325.
Chemometrics
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Density of a binary mixture. A classroom or laboratory exercise Feinstein, H. I. Provides a hypothetical problem in the density of a binary mixture. Feinstein, H. I. J. Chem. Educ. 1972, 49, 111.
Physical Properties |
Chemometrics
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Using alligation alternate to solve composition problems Mancott, Anatol Problems involving the composition of mixtures may be solved by using the relatively obscure method of "alligation alternate" in lieu of the standard algebraic procedure with no loss in accuracy; includes five examples. Mancott, Anatol J. Chem. Educ. 1972, 49, 57.
Chemometrics |
Solutions / Solvents |
Isotopes
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Audio taped explanations of freshman experimental calculations Harrison, Aline M. The authors have found audio tapes to be effective replacements for live, in-lab explanations of experimental calculations. Harrison, Aline M. J. Chem. Educ. 1971, 48, 826.
Chemometrics |
Laboratory Management
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SI units in physico-chemical calculations Norris, A. C. This article demonstrates how the adoption of SI units affects some of the more important physico-chemical calculations found at the undergraduate level. Norris, A. C. J. Chem. Educ. 1971, 48, 797.
Nomenclature / Units / Symbols |
Chemometrics
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Acid-base reaction parameters Freiser, Henry The author demonstrates how the combined algebraic graphical approach can be extended to acid-base titration curve calculations as well as to buffer and sharpness index formulation. Freiser, Henry J. Chem. Educ. 1970, 47, 809.
Acids / Bases |
pH |
Titration / Volumetric Analysis |
Chemometrics
|
Grading the copper sulfide experiment Novick, Seymour The author recommends a more liberal analysis in grading the copper sulfide experiment. Novick, Seymour J. Chem. Educ. 1970, 47, 785.
Stoichiometry |
Chemometrics
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Chemical exponentialism for beginners Larson, G. Olof Presents a method for introducing and reviewing exponential mathematical operations. Larson, G. Olof J. Chem. Educ. 1970, 47, 693.
Chemometrics
|
Hydrolysis of sodium carbonate Nakayama, F. S. Presents a procedure for obtaining the ion concentrations of the various component species produced by the hydrolysis of sodium carbonate. Nakayama, F. S. J. Chem. Educ. 1970, 47, 67.
Aqueous Solution Chemistry |
Chemometrics |
pH
|
Component concentrations in solutions of weak acids Goldish, Dorothy M. presents a new approach to teaching the subject of weak acid equilibria and its associated calculations. Goldish, Dorothy M. J. Chem. Educ. 1970, 47, 65.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Chemometrics |
pH
|
Essential Math for the Sciences: Algebra, Trigonometry, and Vectors (Beiser, Arthur) Reuland, Donald J.
Reuland, Donald J. J. Chem. Educ. 1969, 46, A899.
Chemometrics
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Volkswagen versus the hummingbird Nebbia, Giorgio Questions the cited (046-07-0455) thermodynamic calculations. Nebbia, Giorgio J. Chem. Educ. 1969, 46, 701.
Thermodynamics |
Calorimetry / Thermochemistry |
Chemometrics
|
LTE. Crocker, Roger The author points out that the objections raised to his earlier work are academic. Crocker, Roger J. Chem. Educ. 1969, 46, 699.
Stoichiometry |
Chemometrics
|
LTE. Algebra and chemical equations Copley, George Novello The author questions the mathematic validity of the cited work. Copley, George Novello J. Chem. Educ. 1969, 46, 699.
Stoichiometry |
Chemometrics
|
Fuel conversion in transport phenomena Gerlach, E. R. Calculations comparing the fuel efficiency of a hummingbird with that of a Volkswagen. Gerlach, E. R. J. Chem. Educ. 1969, 46, 455.
Calorimetry / Thermochemistry |
Chemometrics |
Nomenclature / Units / Symbols
|
Circular slide rule conversion of pH to [H+] Grimm, Larry C. This short note discusses the use of a circular slide rule to convert pH to [H+]. Grimm, Larry C. J. Chem. Educ. 1969, 46, 22.
Chemometrics |
Acids / Bases |
pH |
Aqueous Solution Chemistry
|
Hazardous chemicals data National Fire Protection Association Explains aspects of chemical hazard data and presents hazards associated with acetaldehyde. National Fire Protection Association J. Chem. Educ. 1968, 45, A115.
Chemometrics |
Aldehydes / Ketones |
Laboratory Management
|
Chlorine trifluoride. Steere, Norman V. Summarizes the hazards associated with chlorine trifluoride. Steere, Norman V. J. Chem. Educ. 1967, 44, A1057.
Chemometrics |
Laboratory Management
|
The significance of significant figures Pinkerton, Richard C.; Gleit, Chester E. This paper is an attempt to clarify some of our ideas about numerical data, measurements, mathematical operations, and significant figures. Pinkerton, Richard C.; Gleit, Chester E. J. Chem. Educ. 1967, 44, 232.
Nomenclature / Units / Symbols |
Chemometrics
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Statistical analysis of data in the general chemistry laboratory Chapin, Earl C.; Burns, Richard F. Students are asked to analyze data collected with respect to determinations of Dumas molecular weight, equivalent weight of a metal, equivalent weight of an acid, and molecular weight by freezing point depression. Chapin, Earl C.; Burns, Richard F. J. Chem. Educ. 1965, 42, 564.
Chemometrics
|
Computer program for the calculation of acid-base titration curves Emery, Allan R. Describes the development of a computer program for the calculation of acid-base titration curves. Emery, Allan R. J. Chem. Educ. 1965, 42, 131.
Titration / Volumetric Analysis |
Acids / Bases |
Aqueous Solution Chemistry |
Chemometrics
|
Teaching ionic equilibrium: Use of log chart transparencies Freiser, Henry; Fernando, Quintus The use of graphical methods brings the problem of significance of various terms in complicated expressions into proper focus. Furthermore, a pictorial representation permits the student to see at a glance how the concentrations of various species in a system at equilibrium change with conditions. Freiser, Henry; Fernando, Quintus J. Chem. Educ. 1965, 42, 35.
Aqueous Solution Chemistry |
Equilibrium |
Acids / Bases |
pH |
Chemometrics |
Brønsted-Lowry Acids / Bases
|
Solubility and pH Calculations (Butler, James N.) Ramette, R. W.
Ramette, R. W. J. Chem. Educ. 1964, 41, A970.
Aqueous Solution Chemistry |
Precipitation / Solubility |
pH |
Acids / Bases |
Chemometrics |
Enrichment / Review Materials
|
Problem solving in chemistry (Tilbury, Glen) Whitney, Richard M.
Whitney, Richard M. J. Chem. Educ. 1964, 41, A532.
Chemometrics |
Enrichment / Review Materials
|
Operator formalism in dimensional analysis Musulin, Boris Describes another approach to dimensional analysis. Musulin, Boris J. Chem. Educ. 1964, 41, 622.
Chemometrics
|
The Carnot cycle and Maxwell's relations Nash, Leonard K. Maxwells equations can be derived from nothing more than the Carnot cycle and the deployment of the simplest plane geometry. Nash, Leonard K. J. Chem. Educ. 1964, 41, 368.
Thermodynamics |
Chemometrics
|
Beer's law without calculus Pinkerton, Richard C. There is no good reason for using calculus in the presentation of Beer's law. Pinkerton, Richard C. J. Chem. Educ. 1964, 41, 366.
Chemometrics
|
A method of visual representation of three dimensional functions Lemlich, Arthur; Zinsser, Hans H. Lego blocks are used to visually represent three-dimensional functions. Lemlich, Arthur; Zinsser, Hans H. J. Chem. Educ. 1964, 41, 165.
Chemometrics |
Mathematics / Symbolic Mathematics
|
An amperometric-kinetic experiment emphasizing the importance of error treatment Young, J. A. Provides suggestions for student research based on an earlier article published in the Journal. Young, J. A. J. Chem. Educ. 1963, 40, A139.
Undergraduate Research |
Kinetics |
Chemometrics
|
Chemical calculations (Benson, Sidney W.) Masterton, William L.
Masterton, William L. J. Chem. Educ. 1963, 40, 499.
Chemometrics |
Enrichment / Review Materials
|
Basic mathematics of science and engineering (Wood, Reuben E.) Rosenberg, Robert M.
Rosenberg, Robert M. J. Chem. Educ. 1962, 39, A60.
Chemometrics |
Mathematics / Symbolic Mathematics |
Enrichment / Review Materials
|
Balancing ionic equations by the method of undetermined coefficients Haas, Rudy; Gayer, Karl H. Describes a mathematical method for balancing chemical equations. Haas, Rudy; Gayer, Karl H. J. Chem. Educ. 1962, 39, 537.
Stoichiometry |
Chemometrics
|
A simple method for finding slopes Hoare, James P. Describes a simple method for determining the tangent at any point on a given curve using a solid glass rod. Hoare, James P. J. Chem. Educ. 1961, 38, 570.
Chemometrics
|
An approach to complex equilibrium problems Butler, James N. Presents an approach to equilibrium problems that sets up enough equations relating the various concentrations present to define the system completely and then makes approximations that simplify the equations. Butler, James N. J. Chem. Educ. 1961, 38, 141.
Equilibrium |
Chemometrics |
Acids / Bases |
Aqueous Solution Chemistry
|
Initial ratio of reactants to give, at equilibrium, a maximum yield of products Haslam, E. Derivation of the initial ratio of reactants to give, at equilibrium, a maximum yield of products. Haslam, E. J. Chem. Educ. 1958, 35, 471.
Stoichiometry |
Chemometrics
|
An exact titration equation Bolie, Victor W. The purpose of this paper is to show the development of a titration equation for a precipitation reaction which is exact in the mathematical sense. Bolie, Victor W. J. Chem. Educ. 1958, 35, 449.
Titration / Volumetric Analysis |
Chemometrics |
Undergraduate Research
|
Radioactive decay calculations without calculus Guenther, William B. Presents a method for half-life calculations that does not rely on the use of calculus. Guenther, William B. J. Chem. Educ. 1958, 35, 414.
Chemometrics |
Nuclear / Radiochemistry
|
Solution of problems in chemistry Trousdale, Everett A. Presents a method for analyzing and solving mole calculations. Trousdale, Everett A. J. Chem. Educ. 1958, 35, 299.
Chemometrics |
Stoichiometry
|
Dimensional analysis of chemical laws and theories Benfey, O. Theodore The dimensional analysis of the kinetic theory and organic structural theory. Benfey, O. Theodore J. Chem. Educ. 1957, 34, 286.
Chemometrics |
Kinetic-Molecular Theory
|
On the second order rate equation Said, Abdel S. Presents a derivation of the rate equation of a second order reaction. Said, Abdel S. J. Chem. Educ. 1957, 34, 251.
Kinetics |
Rate Law |
Chemometrics
|
A formula for indirect gravimetry Fiekers, B. A. Derivation of a formula for indirect gravimetry and application to a sample problem. Fiekers, B. A. J. Chem. Educ. 1956, 33, 575.
Gravimetric Analysis |
Chemometrics |
Quantitative Analysis
|
A graphical method for determining the order of homogeneous reactions Wright, J. H.; Black, J. H.; Coull, James Provides a review of classical kinetics, derivation of the reaction order equation, and the determination of reaction order using a graph provided. Wright, J. H.; Black, J. H.; Coull, James J. Chem. Educ. 1956, 33, 542.
Kinetics |
Chemometrics
|
The experimental determination of an error distribution Nelson, Lloyd S. Discusses an experiment in which students are asked to the average deviation and probable errors in their measurements. Nelson, Lloyd S. J. Chem. Educ. 1956, 33, 126.
Chemometrics
|
Pocket slide rule for pH calculations Pitzer, Edgar C. A pocket slide rule may be used for direct conversion from hydrogen-ion activity to pH, or vice versa, without the need for arithmetical computation. Pitzer, Edgar C. J. Chem. Educ. 1955, 32, 300.
pH |
Aqueous Solution Chemistry |
Chemometrics
|
Finding the rest point of an undamped analytical balance Stacy, Irving F. Provides a mathematical analysis for finding the rest point of an undamped analytical balance. Stacy, Irving F. J. Chem. Educ. 1955, 32, 90.
Laboratory Equipment / Apparatus |
Instrumental Methods |
Chemometrics
|
A general equation for approximate hydronium ion calculations Drenan, James W. Presents a general equation for simplifying calculations of the hydronium ion. Drenan, James W. J. Chem. Educ. 1955, 32, 36.
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Chemometrics
|
Proper place problems MacKenzie, Scott A mathematical analysis of evaluating problems in which students are asked to place items in the correct order. MacKenzie, Scott J. Chem. Educ. 1954, 31, 428.
Chemometrics
|
A log table for pH problems Condon, Francis E. Provides a readily remembered log table suitable for computing pH from hydronium-ion concentration and the reverse. Condon, Francis E. J. Chem. Educ. 1954, 31, 323.
pH |
Chemometrics |
Acids / Bases |
Aqueous Solution Chemistry
|
Letters to the editor Weaver, Elbert C. Acknowledges and corrects an error in the referenced article regarding an example of Pearson's square. Weaver, Elbert C. J. Chem. Educ. 1954, 31, 102.
Solutions / Solvents |
Chemometrics
|
Letters to the editor Wescott, Emery N. Points out an error in the referenced article regarding an example of Pearson's square. Wescott, Emery N. J. Chem. Educ. 1954, 31, 101.
Solutions / Solvents |
Chemometrics
|
Mathematical chemistry Swinbourne, Ellice S.; Lark, P. David Examines some of the challenges involved in the design of a course in mathematics suitable for undergraduate chemists. Swinbourne, Ellice S.; Lark, P. David J. Chem. Educ. 1953, 30, 570.
Chemometrics |
Mathematics / Symbolic Mathematics
|
A procedure for solving equilibrium problems Boyd, Robert Neilson A procedure for solving equilibrium problems is illustrated through several sample problems. Boyd, Robert Neilson J. Chem. Educ. 1952, 29, 198.
Equilibrium |
Chemometrics |
Aqueous Solution Chemistry
|
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