TIGER

Journal Articles: 87 results
Textbook Deficiencies: Ambiguities in Chemical Kinetics Rates and Rate Constants  Keith T. Quisenberry and Joel Tellinghuisen
Recommends that textbook authors make it clear that (i) the reaction rate and rate constant cannot be defined unambiguously without explicitly stating the reaction for which they apply and therefore (ii) the relation between the half-life, which is a physical property of the reaction system, and the rate constant depends upon how the reaction is written.
Quisenberry, Keith T.; Tellinghuisen, Joel. J. Chem. Educ. 2006, 83, 510.
Kinetics |
Rate Law
The History of Element 43—Technetium  Fathi Habashi
The article From Masurium to Trinacrium: The Troubled Story of Element 43 is the best story so far published about the history of technetium. There is, however, one paragraph on the right column of page 226 that is questionable.
Habashi, Fathi. J. Chem. Educ. 2006, 83, 213.
Isotopes |
Nuclear / Radiochemistry |
Periodicity / Periodic Table
How Radioactive Is Your Banana?  David W. Ball
This exercise uses a banana to illustrate the level of radioactivity (in this case, from K-40) in an everyday object.
Ball, David W. J. Chem. Educ. 2004, 81, 1440.
Food Science |
Nuclear / Radiochemistry |
Isotopes
Don't Be Tricked by Your Integrated Rate Plot  Edward Urbansky
Reply to comments on original article.
Urbansky, Edward. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
Don't Be Tricked by Your Integrated Rate Plot: Reaction order Ambiguity  Sue Le Vent
Integrated rate equations (for constant reaction volume) may be given in terms of relative reactant concentration, C (= concentration/initial concentration) and relative time, T (= time/half-life); in these forms, the equations are independent of rate constants and initial concentrations.
Le Vent, Sue. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
Don't Be Tricked by Your Integrated Rate Plot: Pitfalls of Using Integrated Rate Plots  Gabor Lente
Problems with linearizing the integrated rate law.
Lente, Gabor. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
Don't Be Tricked by Your Integrated Rate Plot: Pitfalls of Using Integrated Rate Plots  Gabor Lente
Problems with linearizing the integrated rate law.
Lente, Gabor. J. Chem. Educ. 2004, 81, 32.
Kinetics |
Mechanisms of Reactions |
Chemometrics
Rate Law Determination of Everyday Processes  Michael J. Sanger, Russell A. Wiley Jr., Erwin W. Richter, and Amy J. Phelps
Laboratory to determine whether burning a candle and flipping pennies follow zero-, first-, or second-order rate laws.
Sanger, Michael J.; Wiley, Russell A., Jr.; Richter, Erwin W.; Phelps, Amy J. J. Chem. Educ. 2002, 79, 989.
Kinetics |
Rate Law
A Serious but Not Ponderous Book about Nuclear Energy (by Walter Scheider)  Peggy Geiger
Nuclear chemistry for the non-scientist.
Geiger, Peggy. J. Chem. Educ. 2002, 79, 314.
Nuclear / Radiochemistry |
Nonmajor Courses
A Discovery-Based Experiment Illustrating How Iron Metal Is Used to Remediate Contaminated Groundwater  Barbara A. Balko and Paul G. Tratnyek
Procedure in which students investigate the chemistry of iron-permeable reactive barriers and their application to the remediation of contaminated groundwater.
Balko, Barbara A.; Tratnyek, Paul G. J. Chem. Educ. 2001, 78, 1661.
Kinetics |
Oxidation / Reduction |
Water / Water Chemistry |
Metals |
Applications of Chemistry |
Aqueous Solution Chemistry
Don't Be Tricked by Your Integrated Rate Plot!  Edward T. Urbansky
Using integrated rate plots to determine reaction order.
Urbansky, Edward T. J. Chem. Educ. 2001, 78, 921.
Kinetics |
Mechanisms of Reactions |
Learning Theories |
Chemometrics |
Rate Law
Ernest Rutherford, Avogadro's Number, and Chemical Kinetics Revisited (about J. Chem. Educ. 1998, 75, 998-1003)  James E. Sturm
Estimation of temperatures in heaven and hell based on biblical information.
Sturm, James E. J. Chem. Educ. 2000, 77, 1278.
Nonmajor Courses |
Calorimetry / Thermochemistry |
Thermodynamics |
Atomic Properties / Structure |
Kinetics |
Nuclear / Radiochemistry
Old Rule of Thumb and the Arrhenius Equation  I. A. Leenson
The empirical rule (doubling of the reaction rate upon every 10 increase in temperature) is discussed on the basis of the Arrhenius equation and experimental data. A graph is plotted that shows the applicability limits of the empirical rule in terms of activation energies and temperatures.
Leenson, Ilya A. J. Chem. Educ. 1999, 76, 1459.
Kinetics
A Different Approach to a 3-D Periodic System Including Stable Isotopes  Alexandru T. Balaban
On a Periodic System with the two dimensions represented by Periods and Columns, one may stack each stable nuclide of an element along the third dimension. This "Downtown Area" representation is helpful for interconnecting concepts of: element, isotope or nuclide (stable vs. radioactive), atomic weight, atomic number, mass number.
Balaban, Alexandru T. J. Chem. Educ. 1999, 76, 359.
Periodicity / Periodic Table |
Isotopes |
Nuclear / Radiochemistry
Chemistry of the Heaviest Elements-One Atom at a Time  Darleane C. Hoffman and Diana M. Lee
A 75-year perspective of the chemistry of the heaviest elements, including a 50-year retrospective view of past developments, a summary of current research achievements and applications, and some predictions about exciting, new developments that might be envisioned within the next 25 years.
Hoffman, Darleane C.; Lee, Diana M. J. Chem. Educ. 1999, 76, 331.
Chromatography |
Instrumental Methods |
Isotopes |
Nuclear / Radiochemistry |
Separation Science |
Descriptive Chemistry |
Enrichment / Review Materials |
Atomic Properties / Structure
The Fizz Keeper, a Case Study in Chemical Education, Equilibrium, and Kinetics  Reed Howald
The chemistry of the loss of carbonation from carbonated beverages on storage is considered. Increasing the pressure of CO2(g) will restore carbonation, but an increase in pressure adding air should not affect the equilibria. It can and does, however, affect the kinetics-the rate at which a new equilibrium is established. Thus the Fizz Keeper is effective for storage of resealed pop containers for hours, but not for periods of weeks or months.
Howald, Reed. J. Chem. Educ. 1999, 76, 208.
Transport Properties |
Equilibrium |
Gases |
Kinetics |
Aqueous Solution Chemistry |
Consumer Chemistry |
Applications of Chemistry
Low-Level Radioactive Waste Disposal: An Exercise in Dealing with Pollution  Grant R. Krow and Jessica B. Krow
A problem-based learning exercise based upon the need for society to dispose of low-level radioactive waste is presented. The exercise is structured as a classroom-centered group problem-based learning module, whose exploration will occupy at least two-three weeks of class time. The goals are to increase student understanding of chemistry and its relationship to ethics and political decision-making.
Krow, Grant R.; Krow, Jessica B. J. Chem. Educ. 1998, 75, 1583.
Learning Theories |
Nuclear / Radiochemistry |
Ethics
Limiting Reagent and Kinetics: Social Implications and Malthus' Prediction  L. H. Holmes Jr.
Robert Malthus predicted in the early 1800s that man would outstrip his food supply. The amount of carbon on earth is the ultimate limiting reagent for the number of people the earth can have and in the sense that carbon is our "food", Malthus was right. However, the land area of the earth is a "limiting reagent" that will limit our population before carbon does. These concepts are discussed in the context of limiting reagents and chemical kinetics to show that if the rate of increase of population remains at what it is now, we have less than a thousand years to "solve" the problem.
Holmes, L. H., Jr. J. Chem. Educ. 1998, 75, 1004.
Kinetics
Ernest Rutherford, Avogadro's Number, and Chemical Kinetics  I. A. Leenson
The paper presents a way for students to use data from Rutherford's works (1908 - 1911) in order to determine one of the most precise values of Avogadro Constant available at the beginning of the century.
Leenson, I. A. J. Chem. Educ. 1998, 75, 998.
Learning Theories |
Nuclear / Radiochemistry |
Kinetics
Dice Shaking as an Analogy for Radioactive Decay and First Order Kinetics  Emeric Schultz
An experiment involving the shaking of sets of different sided dice is described. Dice of 4, 6, 8, 10, 12 and 20 sides are readily available. This experiment serves as an easily understood analogy for radioactive decay and for the more general case of first order kinetics.
Schultz, Emeric. J. Chem. Educ. 1997, 74, 505.
Kinetics |
Nuclear / Radiochemistry
Radioactivity in Everyday Life  S. G. Hutchison, F. I. Hutchison
This paper discusses the terminology appropriate to radiation exposure and dose, the three sources of natural background radiation (cosmic radiation, cosmogenic radiation, and terrestrial radiation), and several radioactive isotopes that are significant contributors to the radiation exposure received by individuals.
Hutchison, S. G.; Hutchison, F. I. J. Chem. Educ. 1997, 74, 501.
Learning Theories |
Nuclear / Radiochemistry |
Isotopes |
Consumer Chemistry
Simple Rules for Determining Nuclear Stability and Type of Radioactive Decay  Mark L. Campbell
Simple rules for determining nuclear stability and type of radioactive decay.
Campbell, Mark L. J. Chem. Educ. 1995, 72, 892.
Nuclear / Radiochemistry
Cloud Chamber Activities for the High School Classroom  Perry, John Timothy; Sankey, Mary Ann
Instructions for constructing and using an inexpensive cloud chamber; includes student assignments and sample data.
Perry, John Timothy; Sankey, Mary Ann J. Chem. Educ. 1995, 72, 339.
Nuclear / Radiochemistry |
Laboratory Equipment / Apparatus
Teaching Aids For Nuclear Chemistry  Atwood, Charles H.
Listing of topics and sources related to nuclear chemistry, including bibliographies for the Journal and Scientific American.
Atwood, Charles H. J. Chem. Educ. 1994, 71, 845.
Nuclear / Radiochemistry
Photodegradation of methylene blue: Using solar light and semiconductor (TiO2)  Nogueira, Raquel F. P.; Jardim, Wilson F.
An experiment that can be used to introduce or explore concepts such as photochemistry, semiconductors, and kinetics.
Nogueira, Raquel F. P.; Jardim, Wilson F. J. Chem. Educ. 1993, 70, 861.
Semiconductors |
Photochemistry |
Kinetics |
Catalysis |
MO Theory
On neutron numbers and atomic masses  Heyrovsk, R.
Assigning neutron numbers, correct neutron numbers, and atomic masses and nucleon numbers.
Heyrovsk, R. J. Chem. Educ. 1992, 69, 742.
Nuclear / Radiochemistry
A cumulative count method for determining the half-life of barium-137 and gallium-68 radioactive isotopes: A spreadsheet application   Hughes, Elvin, Jr.
A profile of a spreadsheet application illustrating a cumulative count method for determining the half-life of barium-137 and gallium-68 radioactive isotopes.
Hughes, Elvin, Jr. J. Chem. Educ. 1991, 68, A41.
Nuclear / Radiochemistry |
Laboratory Computing / Interfacing
Advice from Allied Health faculty to chemistry faculty  Dever, David F.
Finding out what the different health professions would like to see from undergraduate chemistry programs.
Dever, David F. J. Chem. Educ. 1991, 68, 763.
Medicinal Chemistry |
Nuclear / Radiochemistry |
Nutrition |
Vitamins |
Gases
Wet labs, computers, and spreadsheets  Durham, Bill
The following is a description of some commonly encountered experiments that have been modified for computerized data acquisition.
Durham, Bill J. Chem. Educ. 1990, 67, 416.
Laboratory Computing / Interfacing |
Nuclear / Radiochemistry |
Titration / Volumetric Analysis |
Calorimetry / Thermochemistry |
Kinetics |
Electrochemistry
A student experiment to demonstrate the energy loss and straggling of electrons in matter  de Bruin, M.; Huijgen, F. W. J.
The experiment described has been applied routinely for several years in introductory courses in the application of radiation and isotopes. The results obtained give direct insight into the characteristics of the phenomena associated with the absorption of energetic electrons in matter.
de Bruin, M.; Huijgen, F. W. J. J. Chem. Educ. 1990, 67, 86.
Atomic Properties / Structure |
Nuclear / Radiochemistry |
Isotopes
Beta decay diagram   Suder, Robert
Too often instructors believe that students can intuitively understand nuclear decay from balanced equations, but it has been the author's experience that a diagram greatly enhances student knowledge of this process.
Suder, Robert J. Chem. Educ. 1989, 66, 231.
Nuclear / Radiochemistry
Chemical principles for the introductory laboratory, CHM 384 (Johnson, James F.)  Wegner, Carol
A comprehensive review of the title program which overviews basic techniques and concepts presented in introductory laboratory courses. Topics include: titration, equilibrium, Ksp, solubility, Beer's law, coordination complexes and first-order rates of reaction.
Wegner, Carol J. Chem. Educ. 1988, 65, A47.
Acids / Bases |
Titration / Volumetric Analysis |
UV-Vis Spectroscopy |
Equilibrium |
Solutions / Solvents |
Coordination Compounds |
Kinetics
The study of a simple redox reaction as an experimental approach to chemical kinetics  Elias, Horst; Zipp, Arden P.
The authors present a kinetics experiment based on the oxidation of iodide ions that, like the iodine clock, is quick and easy to perform but has the advantage of being followed directly rather than indirectly.
Elias, Horst; Zipp, Arden P. J. Chem. Educ. 1988, 65, 737.
Kinetics |
Reactions |
Rate Law
Determining the solubility of Ca(OH)2 using 45Ca as a tracer  Edmiston, Michael D.; Suter, Robert W.
These authors have developed a simple lab that can be incorporated into freshman chemistry that allows students to understand the power of radiochemistry as an analytical tool as well as gain perspectives about real versus imagined dangers of radioactivity.
Edmiston, Michael D.; Suter, Robert W. J. Chem. Educ. 1988, 65, 279.
Nuclear / Radiochemistry |
Medicinal Chemistry
Windowsill kinetics: A spectrophotometric study of the photochromism of mercury dithizonate  Petersen, Richard L.; Harris, Gaylon L.
Mercury dithizonate undergoes a color change from orange to an intense royal blue upon irradiation with visible light.
Petersen, Richard L.; Harris, Gaylon L. J. Chem. Educ. 1985, 62, 802.
Photochemistry |
Spectroscopy |
Kinetics |
Coordination Compounds |
Raman Spectroscopy
Radioactive dating: A method for geochronology  Rowe, M. W.
The discovery of radioactivity, radioactive dating, and various dating methods.
Rowe, M. W. J. Chem. Educ. 1985, 62, 580.
Geochemistry |
Nuclear / Radiochemistry |
Isotopes |
Mass Spectrometry
Nuclear synthesis and identification of new elements  Seaborg, Glenn T.
Review of descriptive terms, nuclear reactions, radioactive decay modes, and experimental methods in nuclear chemistry.
Seaborg, Glenn T. J. Chem. Educ. 1985, 62, 392.
Nuclear / Radiochemistry |
Nomenclature / Units / Symbols |
Isotopes
Change in concentration with time  Umland, Jean B.
Shows how the rate of a reaction is fast at first and then gradually decreases to zero when one reactant has been used up.
Umland, Jean B. J. Chem. Educ. 1985, 62, 153.
Solutions / Solvents |
Kinetics |
Rate Law
Kinetics and mechanism-a games approach  Harsch, Gunther
Using statistical games to simulate and illustrate a variety of chemical kinetics.
Harsch, Gunther J. Chem. Educ. 1984, 61, 1039.
Kinetics |
Mechanisms of Reactions |
Catalysis |
Rate Law
Natural sources of ionizing radiation  Bodner, George M.; Rhea, Tony A.
Units of radiation measurement, calculations of radiation dose equivalent, sources of ionizing radiation and its biological effects.
Bodner, George M.; Rhea, Tony A. J. Chem. Educ. 1984, 61, 687.
Natural Products |
Nuclear / Radiochemistry |
Nomenclature / Units / Symbols
Computer simulation of elementary chemical kinetics   Nase, Martha L.; Seidman, Kurt
44. Bits and pieces, 16. The authors have developed several computer programs that simulate chemical kinetics for elementary first and second order processes. These programs can be used to generate kinetic data that can then be analyzed by the student in a variety of ways.
Nase, Martha L.; Seidman, Kurt J. Chem. Educ. 1983, 60, 734.
Kinetics |
Rate Law
A method for the determination of half-lives of long lived radioisotopes  Muse, Lowell A.; Safter, Warren J.
It is possible to obtain a rather accurate estimate of the half-life of long-lived radioisotopes by absolute counting of a sample of known mass.
Muse, Lowell A.; Safter, Warren J. J. Chem. Educ. 1982, 59, 431.
Isotopes |
Nuclear / Radiochemistry |
Laboratory Management
Radioactive friends (and relatives)  Taylor, Thomas E.
How many nuclear disintegrations are occurring per minute in a typical human body?
Taylor, Thomas E. J. Chem. Educ. 1980, 57, 364.
Nuclear / Radiochemistry
The case of the isotopic artist  O'Connor, Rod
A problem regarding the decay of isotopes in pigments used to determine an art forgery.
O'Connor, Rod J. Chem. Educ. 1980, 57, 271.
Isotopes |
Nuclear / Radiochemistry |
Applications of Chemistry |
Dyes / Pigments
An introductory level kinetics investigation  McGarvey, J. E. B.; Knipe, A. C.
A kinetic study of the hydrolysis of 3-bromo-3-phenylpropanoic acid.
McGarvey, J. E. B.; Knipe, A. C. J. Chem. Educ. 1980, 57, 155.
Kinetics |
Rate Law |
Mechanisms of Reactions
The kinetics of running  Larsen, Russell D.
The consideration of running as a rate process has several advantages for a student studying chemical kinetics for the first time.
Larsen, Russell D. J. Chem. Educ. 1979, 56, 651.
Kinetics |
Rate Law
A passive nuclear debris collector  Griffin, John J.; Stevens, Ronald L.; Pszenny, Alexander A. P.; Russell, Irving J.
A simple collector that takes advantage of the ability of rain to remove trace radioactive substances from the lower atmosphere.
Griffin, John J.; Stevens, Ronald L.; Pszenny, Alexander A. P.; Russell, Irving J. J. Chem. Educ. 1979, 56, 475.
Nuclear / Radiochemistry |
Laboratory Equipment / Apparatus |
Applications of Chemistry
Variation of radioactive decay rates  Wolsey, Wayne C.
133. It is stated frequently in introductory chemistry texts that radioactive decay rates are invariant. Students are led to the impression, implicitly, if not explicitly, that changes in chemical form, temperature, pressure, etc. have no effect upon the half-lives of unstable nuclei. This constancy of decay is perhaps true for some particular modes of decay, but by no means is it true for all.
Wolsey, Wayne C. J. Chem. Educ. 1978, 55, 302.
Nuclear / Radiochemistry |
Thermodynamics
Elemental evolution and isotopic composition  Rydberg, J.; Choppin, G. R.
Reviews elemental abundances and the processes of elemental creation.
Rydberg, J.; Choppin, G. R. J. Chem. Educ. 1977, 54, 742.
Astrochemistry |
Periodicity / Periodic Table |
Atomic Properties / Structure |
Isotopes |
Nuclear / Radiochemistry |
Geochemistry
What is an element?  Kolb, Doris
Reviews the history of the discovery, naming, and representation of the elements; the development of the spectroscope and the periodic table; radioactive elements and isotopes; allotropes; and the synthesis of future elements.
Kolb, Doris J. Chem. Educ. 1977, 54, 696.
Periodicity / Periodic Table |
Nuclear / Radiochemistry |
Nomenclature / Units / Symbols |
Isotopes
Questions [and] Answers  Campbell, J. A.
284-289. Six questions and their answers on practical applications of chemistry.
Campbell, J. A. J. Chem. Educ. 1977, 54, 161.
Medicinal Chemistry |
Enzymes |
Nuclear / Radiochemistry |
Drugs / Pharmaceuticals |
Applications of Chemistry |
Enrichment / Review Materials
Coffee cup kinetics. A general chemistry experiment  Birk, James P.
This laboratory activity attempts to fill the void of a lack of kinetics experiments in general chemistry.
Birk, James P. J. Chem. Educ. 1976, 53, 195.
Kinetics
Questions [and] Answers  Campbell, J. A.
212-215. Four questions requiring applications of chemistry and their solutions.
Campbell, J. A. J. Chem. Educ. 1975, 52, 727.
Rate Law |
Nuclear / Radiochemistry
Some simple classroom experiments on the Monte Carlo method  Para, A. Foglio; Lazzarini, E.
In this present paper some applications of the Monte Carlo method suggested to freshmen in nuclear physics and chemistry courses are described. These applications are concerned with radioactive decay, statistical fluctuation of the decay, the slowing of fast neutrons, and the calculation of the ratio of partial cross sections of certain nuclear reactions.
Para, A. Foglio; Lazzarini, E. J. Chem. Educ. 1974, 51, 336.
Nuclear / Radiochemistry
Stellar nucleosynthesis. A vehicle for the teaching of nuclear chemistry  Viola, V. E., Jr.
Summarizes the basic properties of matter, stellar evolution and nucleosynthesis, radioactive decay, synthetic and "super-heavy" elements, and radiation in the environment.
Viola, V. E., Jr. J. Chem. Educ. 1973, 50, 311.
Nuclear / Radiochemistry |
Astrochemistry
Radiometric analysis of ammonia in water  Mehra, M. C.
In this experiment, the silver concentration in aqueous solution is determined radiometrically using silver-110 as the radiotracer.
Mehra, M. C. J. Chem. Educ. 1972, 49, 837.
Water / Water Chemistry |
Nuclear / Radiochemistry |
Isotopes |
Aqueous Solution Chemistry |
Quantitative Analysis
A freshman experiment in neutron activation analysis  Pickering, Miles
This experiment uses neutron activation analysis to determine the amount of manganese in "pure" iron wire.
Pickering, Miles J. Chem. Educ. 1972, 49, 430.
Nuclear / Radiochemistry |
Quantitative Analysis
Chemistry in art. Radiochemistry and forgery  Rogers, F. E.
It wasn't until a radiochemical analysis in 1968 that a 1937 forgery of a 17th century Dutch master was confirmed as a fake.
Rogers, F. E. J. Chem. Educ. 1972, 49, 418.
Applications of Chemistry |
Nuclear / Radiochemistry |
Isotopes
Aquation of tris-(1,10-phenanthroline) iron(II) in acid solution. A kinetics experiment  Twigg, Martyn V.
The aquation of tris-(1,10-phenanthroline) iron(II) in acid solution is a reaction for which reliable kinetic data are available and it has an easily measured rate at accessible temperatures.
Twigg, Martyn V. J. Chem. Educ. 1972, 49, 371.
Kinetics |
Rate Law
Hydrolysis of benzenediazonium ion  Sheats, John E.; Harbison, Kenneth G.
Presents a more convenient approach to studying the kinetics of the hydrolysis of benzenediazonium ion.
Sheats, John E.; Harbison, Kenneth G. J. Chem. Educ. 1970, 47, 779.
Aromatic Compounds |
Nucleophilic Substitution |
Kinetics
Chemical queries. Especially for introductory chemistry teachers  Young, J. A.; Malik, J. G.; Parris, Michael
(1) Explains how free radicals differ from species such as NO3- and NH4+. (2) Explains why HI is a stronger acid than HF in aqueous solution. - answer by Parris. (3) Explains that it is possible to alter the half-life of a some radioactive processes through chemical means.
Young, J. A.; Malik, J. G.; Parris, Michael J. Chem. Educ. 1970, 47, 697.
Free Radicals |
Acids / Bases |
Aqueous Solution Chemistry |
Nuclear / Radiochemistry |
Isotopes
The periodic systems of D. I. Mendeleev and problems of nuclear chemistry  Gol'danskii, V. I.; translated by Avakian, Peter
Examines the acquisition and identification of new chemical elements and the structure of the eighth period of the periodic table.
Gol'danskii, V. I.; translated by Avakian, Peter J. Chem. Educ. 1970, 47, 406.
Nuclear / Radiochemistry |
Atomic Properties / Structure |
Periodicity / Periodic Table |
Metals
Chemical queries. Especially for introductory chemistry teachers  Young, J. A.; Malik, J. G.; Choppin, Gregory R.; Young, J. P.
(1) Is there more to nuclear stability than only the neutron to proton ration? - answer by Choppin. (2) What are the products generated by the electrolysis of molten potassium nitrate with stainless steel electrodes? - answer by Young.
Young, J. A.; Malik, J. G.; Choppin, Gregory R.; Young, J. P. J. Chem. Educ. 1970, 47, 73.
Nuclear / Radiochemistry |
Isotopes |
Atomic Properties / Structure |
Electrochemistry
General chemistry demonstrations based on nuclear and radiochemical phenomena  Herber, Rolfe H.
This paper is intended to provide a brief survey of lecture demonstrations, suitable for a general chemistry course, that incorporate some of the ideas, concepts, techniques, and instrumentation of the field of nuclear and radiochemistry.
Herber, Rolfe H. J. Chem. Educ. 1969, 46, 665.
Nuclear / Radiochemistry |
Isotopes
The principle of exponential change: Applications in chemistry, biochemistry, and radioactivity  Green, Frank O.
Examines the nature of exponential change and its applications to chemistry, biochemistry, and radioactivity, including radioactive decay, enzyme kinetics, colorimetry, spectrophotometry, and first order reaction kinetics.
Green, Frank O. J. Chem. Educ. 1969, 46, 451.
Nuclear / Radiochemistry |
Kinetics |
Enzymes |
Spectroscopy
Radioisotope generators for introductory laboratory use  Crater, H. L.; Macchione, J. B.; Gemmill, W. J.; Kramer, H. H.
Describes the use of simple radioisotope generators in 23 different experiments involving nuclear theory.
Crater, H. L.; Macchione, J. B.; Gemmill, W. J.; Kramer, H. H. J. Chem. Educ. 1969, 46, 287.
Nuclear / Radiochemistry |
Isotopes |
Laboratory Equipment / Apparatus
The thermal decomposition of 2,5-dihydrofuran vapor: An experiment in gas kinetics  Rubin, Jay A.; Filseth, Stephen V.
Describes an experiment designed to illustrate manipulations with a vacuum system and the conduct of kinetic measurements.
Rubin, Jay A.; Filseth, Stephen V. J. Chem. Educ. 1969, 46, 57.
Kinetics |
Gases
The disposal of chemical and radioactive waste - Part two  Pearsall, S. G.; Wilshusen, W.
Discusses procedures for the disposal of radioactive wastes.
Pearsall, S. G.; Wilshusen, W. J. Chem. Educ. 1968, 45, A677.
Laboratory Management |
Nuclear / Radiochemistry
Demonstration of a parent-daughter radioactive equilibrium using 137Cs-137mBa  Choppin, Gregory R.; Nealy, Carson L.
Demonstrates the relationship between radioactive half life and both the rate of decay and growth of a radioactive daughter.
Choppin, Gregory R.; Nealy, Carson L. J. Chem. Educ. 1964, 41, 598.
Isotopes |
Nuclear / Radiochemistry |
Equilibrium |
Rate Law
A kinetics experiment for first year chemistry  Shaefer, William P.
The exchange of iodine atoms between organic and inorganic iodides serves as a kinetics experiment for first year chemistry.
Shaefer, William P. J. Chem. Educ. 1964, 41, 558.
Kinetics |
Isotopes |
Rate Law
Dating of uranium minerals by the specific radioactivity of lead  Fairhall, A. W.
This paper discusses a method for estimating the age of a uranium mineral without recourse to elaborate mass-spectrometric techniques and presents an experimental procedure for doing so.
Fairhall, A. W. J. Chem. Educ. 1963, 40, 626.
Nuclear / Radiochemistry |
Isotopes |
Geochemistry
Method for determining order of a reaction  Zimmerman, Howard K.
The method presented here is a substitution process that expresses various rate laws in terms of one initial concentration only.
Zimmerman, Howard K. J. Chem. Educ. 1963, 40, 356.
Kinetics
Radioisotope demonstration of common ion effect on solubility  Roig, E.; Rieckehoff, I. C.; Russo, G. S.; Curet, J. D.
This paper reports a direct demonstration of the effect of common ion concentration on the solubility of a uni-univalent salt, thallium(I) chloride.
Roig, E.; Rieckehoff, I. C.; Russo, G. S.; Curet, J. D. J. Chem. Educ. 1961, 38, 350.
Aqueous Solution Chemistry |
Precipitation / Solubility |
Nuclear / Radiochemistry |
Isotopes
Incorporating radioisotope techniques into the chemistry curriculum  Radin, Norman S.
Presents a list of radioisotope experiments suitable for a wide range of different domains and levels in chemistry.
Radin, Norman S. J. Chem. Educ. 1961, 38, 344.
Nuclear / Radiochemistry |
Isotopes
Nuclear and radiochemistry in the curriculum in general chemistry  Garrett, A. B.
The author summarizes how he integrates nuclear and radiochemistry into the general chemistry curriculum.
Garrett, A. B. J. Chem. Educ. 1960, 37, 384.
Nuclear / Radiochemistry |
Isotopes
Determination of reaction rates with an A.C. conductivity bridge: A student experiment  Chesick, J. P.; Patterson, A., Jr.
Describes a quantitative experiment in chemical kinetics suitable for advanced freshmen or physical chemistry; it involves a study of the solvolysis of tertiary butyl chloride by means of conductance measurements.
Chesick, J. P.; Patterson, A., Jr. J. Chem. Educ. 1960, 37, 242.
Conductivity |
Kinetics |
Rate Law
Letters  Hendricks, B. Clifford
A brief examination of the way in which general chemistry textbooks portray the emission of alpha, beta, and gamma rays.
Hendricks, B. Clifford J. Chem. Educ. 1960, 37, 161.
Nuclear / Radiochemistry
A half-life experiment for general chemistry students  Smith, W. T.; Wood, J. H.
This paper describes the authors' experiences with the measurement of the half-life of bismuth-210.
Smith, W. T.; Wood, J. H. J. Chem. Educ. 1959, 36, 492.
Nuclear / Radiochemistry |
Isotopes
Use of radioisotopes in the college chemistry laboratory  Phillips, David; Maybury, Robert H.
Provides experiments and experiences working with constructed Geiger counters and radioisotopes.
Phillips, David; Maybury, Robert H. J. Chem. Educ. 1959, 36, 133.
Nuclear / Radiochemistry |
Isotopes |
Instrumental Methods |
Qualitative Analysis |
Kinetics
Radioactive decay calculations without calculus  Guenther, William B.
Presents a method for half-life calculations that does not rely on the use of calculus.
Guenther, William B. J. Chem. Educ. 1958, 35, 414.
Chemometrics |
Nuclear / Radiochemistry
Nuclear batteries  Garrett, Alfred B.
Describes the structure, operation, and application of nuclear batteries.
Garrett, Alfred B. J. Chem. Educ. 1956, 33, 446.
Nuclear / Radiochemistry |
Electrochemistry
The relative contributions of various elements to the earth's radioactivity  Asimov, Isaac
Describes relative contributions of various elements to the earth's radioactivity.
Asimov, Isaac J. Chem. Educ. 1954, 31, 24.
Nuclear / Radiochemistry |
Geochemistry |
Isotopes
Dating with carbon 14  Kulp, J. Laurence
Examines the principles, technique, results of and problems with radioactive dating using carbon-14.
Kulp, J. Laurence J. Chem. Educ. 1953, 30, 432.
Nuclear / Radiochemistry |
Isotopes
Naturally occurring radioisotopes  Asimov, Isaac
Examines half-life calculations, long-lived radioactive isotopes, and the formation of short-lived radioactive isotopes.
Asimov, Isaac J. Chem. Educ. 1953, 30, 398.
Nuclear / Radiochemistry |
Isotopes |
Geochemistry
Radiations from radioactive materials  Orban, Edward
Lists many radioactive minerals and ores and their sources and describes some simple demonstrations of radioactivity.
Orban, Edward J. Chem. Educ. 1952, 29, 289.
Nuclear / Radiochemistry |
Isotopes
Experiments on radioactivity in the first course in college chemistry  Brown, Charles A.; Rochow, E. G.
Experiments described include the detection and measurement of radioactivity; comparing the penetrative power of beta and gamma radiation; separating thorium from uranium; and determining the half-life of iodine 128.
Brown, Charles A.; Rochow, E. G. J. Chem. Educ. 1951, 28, 521.
Nuclear / Radiochemistry |
Isotopes |
Separation Science
Autoradiography as a science project  Huber, William S.
Describes several autoradiography techniques in which photographic plates are exposed to radioactive sources.
Huber, William S. J. Chem. Educ. 1951, 28, 226.
Nuclear / Radiochemistry