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Halting the Briggs-Rauscher Oscillating Reaction The Briggs-Rauscher reaction is demonstrated in three different ways. Catalase from a liver extract decomposes the hydrogen peroxide in an Briggs-Rauscher reaction, stopping the oscillations.
Catalysis |
Kinetics |
Enzymes |
Proteins / Peptides
Induction by Iron(II) of the Oxidation of Iodide by Dichromate Acidic aqueous solutions containing dichromate and iodide ions are mixed with no reaction. The addition of a solution of iron(II) ion induces the rapid formation of brown triiodide ion.
Kinetics : Enzyme (7 Variations)
Trypsin assists in digestion by breaking proteins down into smaller peptides. However, this process is not as efficient in the presence of fluorophosphates. Identify the role of each of these components.
Catalytic converters are used in automobiles to convert pollutants in engine emissions to benign products. Catalytic converters in today's automobiles are made of a porous ceramic brick that has been coated with catalysts, additives, stabilizers, and support materials. Corning has developed bricks that have very thin-walled channels with 600 channels per square inch. Which of the following research goals did they target?
J. Chem. Educ. 1999,76, 1578–1583John Andraos Corrections to the article A Streamlined Approach to Solving Simple and Complex Kinetic Systems Analytically. Andraos, John. J. Chem. Educ.2008, 85, 1624.
Kinetics |
Mechanisms of Reactions |
Theoretical Chemistry
Helping Students Make Sense of Logarithms and Logarithmic RelationshipsEd DePierro, Fred Garafalo, and Rick Toomey This paper summarizes difficulties that chemistry students at all levels exhibit when translating, manipulating, and interpreting mathematical expressions containing logarithms, and offers approaches useful in helping students to overcome those difficulties. DePierro, Ed; Garafalo, Fred; Toomey, Rick T. J. Chem. Educ.2008, 85, 1226.
Kinetics |
Mathematics / Symbolic Mathematics |
Constructivism
An Updated Equilibrium MachineEmeric Schultz Describes a device that can demonstrate equilibrium and the Le Châtelier principle, as well as kinetic and thermodynamic concepts. The device consists of a leaf blower attached to a plastic container divided into two chambers by a barrier of variable size and form. Styrofoam balls can be exchanged across the barrier when various air pressures are applied by the blower. Schultz, Emeric. J. Chem. Educ.2008, 85, 1131.
Catalysis in BiologyTim Wendorff A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Catalysis |
Enzymes
ChemPaths 104 M Feb 28John W. Moore Today in Chem 104:
* Lecture: Catalysis
* Reading:
Kotz, Ch. 15, Sec. 6
Moore, Ch. 13, Sec. 8-10
* Homework #6 due by 11:55 pm F Mar 4
* Biomolecules Tutorial: Enzymes (and Enzymes Quiz)
due at 11:55 pm, W Mar 2.
Catalysis |
Enzymes
Increasing the Rate of a ReactionEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.