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Consider a cell composed of the following half-reactions. Determine the
magnitude of E° for the cell and decide whether the reaction will be
product-favored or reactant-favored as written.
The Electrochemical Synthesis of Transition-Metal AcetylacetonatesS. R. Long, S. R. Browning, and J. J. Lagowski The electrochemical synthesis of transition-metal acetylacetonates can assist in the transformation of an entry-level laboratory course into a research-like environment where all members of a class are working on the same problem, but each student has a personal responsibility for the synthesis and characterization of a specific compound. Long, S. R.; Browning, S. R.; Lagowski, J. J. J. Chem. Educ.2008, 85, 1429.
Coordination Compounds |
Electrochemistry |
IR Spectroscopy |
Physical Properties |
Synthesis |
Transition Elements |
UV-Vis Spectroscopy
The Correlation of Binary Acid Strengths with Molecular Properties in First-Year ChemistryTravis D. Fridgen This article replaces contradictory explanations for the strengths of different binary acids in first-year chemistry textbooks with a single explanation that uses a BornHaber cycle involving homolyic bond dissociation energies, electron affinities, and ion solvation enthalpies to rationalize trends in the strengths of all binary acids. Fridgen, Travis D. J. Chem. Educ.2008, 85, 1220.
Acids / Bases |
Atomic Properties / Structure |
Aqueous Solution Chemistry |
Physical Properties |
Thermodynamics
Introducing Undergraduate Students to Electrochemistry: A Two-Week Discovery Chemistry ExperimentKenneth V. Mills, Richard S. Herrick, Louise W. Guilmette, Lisa P. Nestor, Heather Shafer, and Mauri A. Ditzler, Within the framework of a laboratory-focused, guided-inquiry pedagogy, students discover the Nernst equation, the spontaneity of galvanic cells, concentration cells, and the use of electrochemical data to calculate equilibrium constants. Mills, Kenneth V.; Herrick, Richard S.; Guilmette, Louise W.; Nestor, Lisa P.; Shafer, Heather;Ditzler, Mauri A. J. Chem. Educ.2008, 85, 1116.
The Free EnergyEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Thermodynamics
Gibbs Free Energy in BiologyJohn W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Thermodynamics |
Metabolism |
Bioenergetics
Electrochemistry (Netorials)Rachel Bain, Mithra Biekmohamadi, Liana Lamont, Mike Miller, Rebecca Ottosen, John Todd, and David Shaw Electrochemistry: this is a resource in the collection "Netorials". This modules about electrochemistry includes topics such as oxidation-reduction and half reactions, voltaic and electrolytic cells, standard cell potentials and batteries. The Netorials cover selected topics in first-year chemistry including: Chemical Reactions, Stoichiometry, Thermodynamics, Intermolecular Forces, Acids & Bases, Biomolecules, and Electrochemistry.
2 SO3(g)
Cr3+(aq) + 3e- 
