TIGER

Journal Articles: 303 results
Magnetized Water: Science or Fraud?  L. Lahuerta Zamora, G. M. Antón-Fos, P. A. Alemán López, and R. V. Martin Algarra
Commercial water magnetizers provide a unique opportunity to help university and secondary students develop appropriate skepticism against extraordinary claims and use testing as the basis for their scientific evaluation.
Lahuerta Zamora, L.; Antón-Fos, G. M.; Alemán López, P. A.; Martin Algarra, R. V. J. Chem. Educ. 2008, 85, 1416.
Aqueous Solution Chemistry |
Magnetic Properties |
pH |
Titration / Volumetric Analysis |
Water / Water Chemistry
On Capillary Rise and Nucleation  R. Prasad
A comparison of capillary rise and nucleation shows that both phenomena result from a balance between two competing energy factors: a volume energy and a surface energy. This comparison may help to introduce nucleation with capillary rise, a topic familiar to students.
Prasad, R. J. Chem. Educ. 2008, 85, 1389.
Liquids |
Materials Science |
Metallurgy |
Solids
Fog Machines, Vapors, and Phase Diagrams  Ed Vitz
This series of demonstrations elucidate the operation of commercial fog machines using common laboratory materials and can be adapted for elementary through tertiary levels. The formation of fogs is discussed in terms of the phase diagram for water and other chemical principles.
Vitz, Ed. J. Chem. Educ. 2008, 85, 1385.
Liquids |
Phases / Phase Transitions / Diagrams |
Physical Properties |
Water / Water Chemistry
Construction of a Polyaniline Nanofiber Gas Sensor  Shabnam Virji, Bruce H. Weiller, Jiaxing Huang, Richard Blair, Heather Shepherd, Tanya Faltens, Philip C. Haussmann, Richard B. Kaner, and Sarah H. Tolbert
The objectives of this lab are to synthesize different diameter polyaniline nanofibers and compare them as sensor materials. Its advantages include simplicity and low cost, making it suitable for both high school and college students, particularly in departments with modest means.
Virji, Shabnam; Weiller, Bruce H.; Huang, Jiaxing; Blair, Richard; Shepherd, Heather; Faltens, Tanya; Haussmann, Philip C.; Kaner, Richard B.; Tolbert, Sarah H. J. Chem. Educ. 2008, 85, 1102.
Acids / Bases |
Aromatic Compounds |
Conductivity |
Hydrogen Bonding |
Oxidation / Reduction |
Oxidation State |
pH |
Polymerization |
Synthesis
Using Molecular Dynamics Simulation To Reinforce Student Understanding of Intermolecular Forces  Phillip R. Burkholder, Gordon H. Purser, and Renee S. Cole
This article presents a series of experiments incorporating molecular dynamics simulations which predict the motion of chemical species based on the application of empirical rules and a physical analysis of the forces that act between the species. These motions can then be shown in vivid graphical form.
Burkholder, Phillip R.; Purser, Gordon H.; Cole, Renee S. J. Chem. Educ. 2008, 85, 1071.
Computational Chemistry |
Hydrogen Bonding |
Molecular Mechanics / Dynamics |
Physical Properties |
Solutions / Solvents
Stilling Waves with Ordered Molecular Monolayers  Ed Vitz
The amazing ability of a film of oil one molecule thick to dissipate the relatively large energy of water waves can be readily demonstrated, but an explanation of the effect has been elusive until recently.
Vitz, Ed. J. Chem. Educ. 2008, 85, 1064.
Lipids |
Molecular Properties / Structure |
Noncovalent Interactions |
Surface Science |
Water / Water Chemistry |
Fatty Acids
Easy-To-Make Cryophoruses  Rubin Battino and Trevor M. Letcher
This article describes some simple and easy-to-make cryophoruses, ideal for demonstrating evaporative cooling to students at all levels.
Battino, Rubin; Letcher, Trevor M. J. Chem. Educ. 2008, 85, 561.
Lipids |
Physical Properties |
Thermodynamics |
Liquids
Yet Another Variation on the Electrolysis of Water at Iron Nails  Mark T. Stauffer and Justin P. Fox
Describes a variation on the electrolysis of water with iron nails in which a sharp contrast in the colors produced effectively demonstrates electrolysis and the diffusion of oxidized and reduced species from the electrodes.
Stauffer, Mark T.; Fox, Justin P. J. Chem. Educ. 2008, 85, 523.
Acids / Bases |
Electrochemistry |
Oxidation / Reduction |
Stoichiometry |
Water / Water Chemistry |
Electrolytic / Galvanic Cells / Potentials
Understanding the Clausius–Clapeyron Equation by Employing an Easily Adaptable Pressure Cooker  Monica Galleano, Alberto Boveris, and Susana Puntarulo
Describes a laboratory exercise to understand the effect of pressure on phase equilibrium as described by the ClausiusClapeyron equation. The equipment required is a pressure cooker adapted with a pressure gauge and a thermometer in the lid, allowing the measurement of the pressure and the temperature of the chamber containing the water heated until vaporization.
Galleano, Monica; Boveris, Alberto; Puntarulo, Susana. J. Chem. Educ. 2008, 85, 276.
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Water / Water Chemistry
The Role of Water Chemistry in Marine Aquarium Design: A Model System for a General Chemistry Class  Jeffrey J. Keaffaber, Ramiro Palma, and Kathryn R. Williams
Water chemistry is central to aquarium design, and it provides many potential applications for discussion in undergraduate chemistry and engineering courses. This article uses a hypothetical tank to house ocean sunfish as a model to show students the calculations and other considerations that are needed when designing a marine aquarium.
Keaffaber, Jeffrey J.; Palma, Ramiro; Williams, Kathryn R. J. Chem. Educ. 2008, 85, 225.
Acids / Bases |
Aqueous Solution Chemistry |
Consumer Chemistry |
Oxidation / Reduction |
Stoichiometry |
Water / Water Chemistry
A Simplified Model To Predict the Effect of Increasing Atmospheric CO2 on Carbonate Chemistry in the Ocean  Brian J. Bozlee, Maria Janebo, and Ginger Jahn
The chemistry of dissolved inorganic carbon in seawater is reviewed and used to predict the potential effect of rising levels of carbon dioxide in the atmosphere. It is found that calcium carbonate may become unsaturated in cold surface seawater by the year 2100, resulting in the destruction of calcifying organisms such as coral.
Bozlee, Brian J.; Janebo, Maria; Jahn, Ginger. J. Chem. Educ. 2008, 85, 213.
Applications of Chemistry |
Aqueous Solution Chemistry |
Atmospheric Chemistry |
Equilibrium |
Green Chemistry |
Water / Water Chemistry
JCE Resources for Chemistry and Water  Erica K. Jacobsen
This annotated bibliography collects the best that past issues of JCE have to offer for use with the 2008 Chemists Celebrate Earth Day theme, "Streaming Chemistry".
Jacobsen, Erica K. J. Chem. Educ. 2008, 85, 188.
Water / Water Chemistry
Streaming Chemistry  John W. Moore
The JCE editorial staff has collected a broad range of articles in support of the topic Water, this years theme for Chemists Celebrate Earth Day.
Moore, John W. J. Chem. Educ. 2008, 85, 171.
Water / Water Chemistry
Colorful Lather Printing  Susan A. S. Hershberger, Matt Nance, Arlyne M. Sarquis, and Lynn M. Hogue
Students explore the chemistry of polar and nonpolar substances and surfactants while marbling paper with shaving cream and food coloring.
Hershberger, Susan A. S.; Nance, Matt; Sarquis, Arlyne M.; Hogue, Lynn M. J. Chem. Educ. 2007, 84, 608A.
Applications of Chemistry |
Consumer Chemistry |
Noncovalent Interactions |
Physical Properties |
Surface Science |
Water / Water Chemistry
Effects of a Cooperative Learning Strategy on Teaching and Learning Phases of Matter and One-Component Phase Diagrams  Kemal Doymus
Describes a study whose objective was to determine the effects of cooperative learning (using the jigsaw method) on students' achievement in a general chemistry course.
Doymus, Kemal. J. Chem. Educ. 2007, 84, 1857.
Gases |
Liquids |
Phases / Phase Transitions / Diagrams |
Solids
New Analytical Method for the Determination of Detergent Concentration in Water by Fabric Dyeing  Set Seng, Masakazu Kita, and Reiko Sugihara
This article describes a high school classroom activity in which an acrylic fabric is used as the extraction medium in the analysis of detergent concentration rather than more harmful organic solvents. An handmade reflection photometer, assembled with inexpensive materials such as LED, PVC tube, and CdS sensor, is used to determine the detergent concentration.
Seng, Set; Kita, Masakazu; Sugihara, Reiko. J. Chem. Educ. 2007, 84, 1803.
Aqueous Solution Chemistry |
Consumer Chemistry |
Dyes / Pigments |
Laboratory Equipment / Apparatus |
Quantitative Analysis |
Solutions / Solvents |
Water / Water Chemistry
Gas Clathrate Hydrates Experiment for High School Projects and Undergraduate Laboratories  Melissa P. Prado, Annie Pham, Robert E. Ferazzi, Kimberly Edwards, and Kenneth C. Janda
Presents a procedure for preparing and studying propane clathrate hydrate. This experiment introduces students to this unusual solid while stimulating a discussion of the interplay of intermolecular forces, thermodynamics, and solid structure.
Prado, Melissa P.; Pham, Annie; Ferazzi, Robert E.; Edwards, Kimberly; Janda, Kenneth C. J. Chem. Educ. 2007, 84, 1790.
Alkanes / Cycloalkanes |
Applications of Chemistry |
Calorimetry / Thermochemistry |
Gases |
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Water / Water Chemistry |
Hydrogen Bonding
Dancing Crystals: A Dramatic Illustration of Intermolecular Forces  Donald W. Mundell
Crystals of naphthalene form on the surface of an acetone solution and dance about in an animated fashion illustrating surface tension, crystallization, and intermolecular forces. Additional experiments reveal the properties of the solution and previous demonstrations of surface motion are explored.
Mundell, Donald W. J. Chem. Educ. 2007, 84, 1773.
Aromatic Compounds |
Liquids |
Molecular Mechanics / Dynamics |
Molecular Properties / Structure |
Physical Properties |
Surface Science |
Noncovalent Interactions
Which Method Is Most Precise; Which Is Most Accurate?  A. D. Jordan
The main objective of this experiment, which involves determining the density of a liquid by several methods, is to familiarize students with the concepts of precision and accuracy using data that can be acquired easily with a variety of apparatus and analyzed by simple statistics and a linear regression.
Jordan, A. D. J. Chem. Educ. 2007, 84, 1459.
Liquids |
Physical Properties |
Quantitative Analysis
The Chemistry of Swimming Pool Maintenance  Carl Salter and David L. Langhus
This paper examines the key ideas behind swimming pool chemistry -- the central importance of pH and its effect on chlorine sanitation and calcium carbonate solubility. The paper also reviews the analytical procedures and common practices used to monitor and control pool chemistry or correct problems.
Salter, Carl; Langhus, David L. J. Chem. Educ. 2007, 84, 1124.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Dyes / Pigments |
pH |
Photochemistry |
Precipitation / Solubility |
Water / Water Chemistry
Enthalpy of Vaporization and Vapor Pressures: An Inexpensive Apparatus  Rubin Battino, David A. Dolson, Michael R. Hall, and Trevor M. Letcher
Describes an inexpensive apparatus for the determination of the vapor pressure of a liquid as a function of temperature for the purpose of calculating enthalpy changes of vaporization. Also described are a simple air thermostat and an inexpensive temperature controller based on an integrated temperature sensor.
Battino, Rubin; Dolson, David A.; Hall, Michael R.; Letcher, Trevor M. J. Chem. Educ. 2007, 84, 822.
Gases |
Laboratory Equipment / Apparatus |
Lipids |
Phenols |
Physical Properties |
Thermodynamics |
Liquids |
Phases / Phase Transitions / Diagrams
Using Dalton's Law of Partial Pressures To Determine the Vapor Pressure of a Volatile Liquid  Fred R. Hilgeman, Gary Bertrand, and Brent Wilson
This experiment, designed for a general chemistry laboratory, illustrates the use of Dalton's law of partial pressures to determine the vapor pressure of a volatile liquid.
Hilgeman, Fred R.; Bertrand, Gary; Wilson, Brent. J. Chem. Educ. 2007, 84, 469.
Gases |
Liquids |
Physical Properties |
Solutions / Solvents
Molecular Model of Zincon  William F. Coleman
The Featured Molecules this month are the tautomeric forms of the colorimetric reagent zincon. The structures could be used as an introduction to the concept of tautomerism, with students being asked to develop a definition of the term based on their observations of the difference(s) in linkage in the two forms.
Coleman, William F. J. Chem. Educ. 2007, 84, 305.
Biological Cells |
Calorimetry / Thermochemistry |
Water / Water Chemistry |
Molecular Mechanics / Dynamics |
Molecular Modeling |
Molecular Properties / Structure
Popcorn—What's in the Bag?  Marissa B. Sherman and Thomas A. Evans
Three independent activities explore microwave popcorn, the nature of the packaging, and the popcorn produced.
Sherman, Marissa B.; Evans, Thomas A. J. Chem. Educ. 2006, 83, 416A.
Carbohydrates |
Nutrition |
Physical Properties |
Solutions / Solvents |
Water / Water Chemistry
Teaching Physical Chemistry Experiments with a Computer Simulation by LabVIEW  A. Belletti, R. Borromei, and G. Ingletto
This article reports on a computer simulation developed with the software LabVIEW of the physical chemistry experiment regarding the vapor pressure measurements of a pure liquid as a function of temperature, as well as a system of data collecting that emphasizes the similarities between the virtual and real experiment.
Belletti, A.; Borromei, R.; Ingletto, G. J. Chem. Educ. 2006, 83, 1353.
Equilibrium |
Laboratory Computing / Interfacing |
Liquids |
Thermodynamics |
Gases |
Student-Centered Learning
Equilibrium Constants and Water Activity Revisited  David Keeports
Subtle arguments based upon the use of chemical potentials show that numerical values of solute molar concentrations can be used as good approximate activities in equilibrium calculations for reactions involving dilute solutions.
Keeports, David. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
Equilibrium Constants and Water Activity Revisited  E. J. Behrman
In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols.
Behrman, E. J. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
Equilibrium Constants and Water Activity Revisited  E. J. Behrman
In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols.
Behrman, E. J. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
Intermolecular and Intramolecular Forces: A General Chemistry Laboratory Comparison of Hydrogen Bonding in Maleic and Fumaric Acids  Frazier W. Nyasulu and John Macklin
This article presents a simple laboratory experiment that is designed to enhance students' understanding of inter- and intramolecular hydrogen bonding by demonstrating the comparative effect of these phenomena on some chemical and physical properties.
Nyasulu, Frazier W.; Macklin, John. J. Chem. Educ. 2006, 83, 770.
Acids / Bases |
Hydrogen Bonding |
Noncovalent Interactions |
Thermodynamics |
Titration / Volumetric Analysis
The Great Wakonse Earthquake of 2003: A Short, Problem-Based Introduction to the Titration Concept  Brian P. Coppola, Amy C. Gottfried, Robyn L. Gdula, Alan L. Kiste, and Nathan W. Ockwig
This activity introduces nonscience adult learners to the concept of titration from real-world instructions about earthquake water safety found in a California phone book.
Coppola, Brian P.; Gottfried, Amy C.; Gdula, Robyn L.; Kiste, Alan L.; Ockwig, Nathan W. J. Chem. Educ. 2006, 83, 600.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Qualitative Analysis |
Titration / Volumetric Analysis |
Water / Water Chemistry
Teaching Chemistry Laboratory Skills in Industrial Contexts  Julianne M. Braun and Carol White
A recently completed project has produced a compilation of 40 laboratory experiments presented within the contexts of five major industries. This article provides a summary of these experiments, along with a discussion of ancillary materials.
Braun, Julianne M.; White, Carol. J. Chem. Educ. 2006, 83, 353.
Applications of Chemistry |
Industrial Chemistry |
Metals |
Polymerization |
Water / Water Chemistry
Linking Laboratory Experiences to the Real World: The Extraction of Octylphenoxyacetic Acid from Water  Jorge E. Loyo-Rosales, Alba Torrents, Georgina C. Rosales-Rivera, and Clifford P. Rice
A known quantity of the sodium salt of octylphenoxyacetic acid is dissolved in water, transformed to the acid (insoluble) form, and extracted using dichloromethane. These changes can be followed visually owing to conspicuous changes in solution turbidity.
Loyo-Rosales, Jorge E.; Torrents, Alba; Rosales-Rivera, Georgina C.; Rice, Clifford P. J. Chem. Educ. 2006, 83, 248.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
pH |
Stoichiometry |
Nonmajor Courses |
Water / Water Chemistry
An Interactive Environmental Science Course for Education Science Majors  Suzanne K. Lunsford and William Slattery
Describes an interactive environmental modular science course for education science majors preparing to become teachers at the primary and secondary levels. The purpose of the course is to give students experience in inquiry, gathering data, the evaluation of data to understand scientific theory, and the application of inquiry, hands-on methods in the classroom.
Lunsford, Suzanne K.; Slattery, William. J. Chem. Educ. 2006, 83, 233.
Applications of Chemistry |
Geochemistry |
Nonmajor Courses |
Water / Water Chemistry |
Student-Centered Learning |
Standards National / State
The Nature of Hydrogen Bonding  Emeric Schultz
Students use toy connecting blocks and Velcro to investigate weak intermolecular interactions, specifically hydrogen bonds.
Schultz, Emeric. J. Chem. Educ. 2005, 82, 400A.
Noncovalent Interactions |
Hydrogen Bonding |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Covalent Bonding |
Molecular Modeling |
Molecular Properties / Structure
Further Analysis of Boiling Points of Small Molecules, CHwFxClyBrz  Guy Beauchamp
Multiple linear regression analysis has proven useful in selecting predictor variables that could significantly clarify the boiling point variation of the CHwFxClyBrz molecules.
Beauchamp, Guy. J. Chem. Educ. 2005, 82, 1842.
Chemometrics |
Physical Properties |
Hydrogen Bonding |
Molecular Properties / Structure |
Alkanes / Cycloalkanes
Using Visible Spectrophotometers and pH Measurements To Study Speciation in a Guided-Inquiry Laboratory   William H. Otto, Cynthia K. Larive, Susan L. Mason, Janet B. Robinson, Joseph A. Heppert, and James D. Ellis
A collective-effort, guided-inquiry laboratory investigation was developed for the second-semester general chemistry laboratory for the purpose of increasing student conceptual understanding of equilibrium and speciation phenomena. This investigation required students to employ the chemical indicator phenol red in phosphate buffer solution, computer interfaced pH probes, and visible spectrophotometers. Through a combination of potentiometric and visible absorption measurements, the students determined the pH conditions that alter equilibrium concentrations of multiple species (colored and transparent) in solution.
Otto, William H.; Larive, Cynthia K.; Mason, Susan L.; Robinson, Janet B.; Heppert, Joseph A.; Ellis, James D. J. Chem. Educ. 2005, 82, 1552.
Acids / Bases |
UV-Vis Spectroscopy |
Equilibrium |
pH |
Water / Water Chemistry |
Dyes / Pigments
Sedimentation Time Measurements of Soil Particles by Light Scattering and Determination of Chromium, Lead, and Iron in Soil Samples via ICP  Patricia Metthe Todebush and Franz M. Geiger
In this two-part general chemistry laboratory activity, students study soil samples from home and from campus. In part one, the samples are placed in water and the suspended colloid fraction is separated using filtration, followed by a determination of colloid sedimentation rates via light scattering. In part two, the solid phase of the soil samples is dissolved in acid and analyzed for chromium, lead, and iron using an inductively coupled plasma spectrometer. The experiment can be expanded to include arsenic. Through these experiments students can draw conclusions about the physical and chemical behavior of solid components in soil, paying particular attention to their propensity for transporting and chemically transforming pollutants in the environment.
Todebush, Patricia Metthe; Geiger, Franz M. J. Chem. Educ. 2005, 82, 1542.
Colloids |
Geochemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solids |
Surface Science |
Metals
Equilibrium Constants and Water Activity  David Keeports
General chemistry instructors are faced with a dilemma when introducing the topic of equilibrium constants: These constants are correctly written in terms of activities, yet activity is a complex topic better treated rigorously in a physical chemistry course than superficially in a general chemistry course. Thus, to introduce equilibrium calculations, it is necessary to use approximate forms for equilibrium constants. However, I find that some commonly used textbooks provide incorrect arguments leading to approximate equilibrium constants for aqueous reactions.
Keeports, David. J. Chem. Educ. 2005, 82, 999.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry
Conceptual Considerations in Molecular Science  Donald T. Sawyer
The undergraduate curriculum and associated textbooks include several significant misconceptions.
Sawyer, Donald T. J. Chem. Educ. 2005, 82, 985.
Catalysis |
Covalent Bonding |
Electrolytic / Galvanic Cells / Potentials |
Oxidation / Reduction |
Reactions |
Reactive Intermediates |
Thermodynamics |
Water / Water Chemistry
Thermal Expansion: Using Calculator-Based Laboratory Technology To Observe the Anomalous Behavior of Water  Mario Branca and Isabella Soletta
This is a simple experiment to observe variations in the density of water and other liquids at different temperatures with CBL technology. Using it students can observe the anomalous behavior of water at temperatures between 0 C and 4 C.
Branca, Mario; Soletta, Isabella. J. Chem. Educ. 2005, 82, 613.
Liquids |
Physical Properties |
Water / Water Chemistry
Simple Dynamic Models for Hydrogen Bonding Using Velcro-Polarized Molecular Models  Emeric Schultz
This article describes the use of models that dynamically illustrate the unique characteristics of weak intermolecular interactions, specifically hydrogen bonds. The models clearly demonstrate that H-bonds can break and reform while covalent bonds stay intact. The manner in which the models form and break H-bonds reflects the geometric and statistical manner in which H-bonding actually occurs and is not contrived. The use of these models addresses a significant area of student misconceptions. The construction of these molecular models is described.
Schultz, Emeric. J. Chem. Educ. 2005, 82, 401.
Molecular Properties / Structure |
Molecular Modeling |
Noncovalent Interactions |
Hydrogen Bonding |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
Intermolecular Forces as a Key to Understanding the Environmental Fate of Organic Xenobiotics  Ryan E. Casey and Faith A. Pittman
We have developed an environmental chemistry module that can be used in high schools or undergraduate nonscience courses to relate chemical structures and properties to the macroscopic behavior of environmentally relevant organic chemicals like pesticides, PCBs, and solvents. The module introduces the concepts of intermolecular forces, polarity, and partitioning to explain complex phenomena such as environmental transport and biomagnification of xenobiotics (human-made chemicals).
Casey, Ryan E.; Pittman, Faith A. J. Chem. Educ. 2005, 82, 260.
Nonmajor Courses |
Hydrogen Bonding |
Noncovalent Interactions
Hard Water and Soft Soap: Dependence of Soap Performance on Water Hardness. A Classroom Demonstration  Viktoria K. L. Osorio, Wanda de Oliveira, and Omar A. El Seoud
We describe a series of classroom demonstrations presented to high school students. The demonstrations were carried out to answer the question: Why does soap not foam in seawater? We generalized the question into: Why does soap performance depend on the hardness of the water used? A sequence of experiments was carried out to compare the performance of soap in soft and hard water and to illustrate the water-softening action of EDTA and zeolites.
Osorio, Viktoria K. L.; de Oliveira, Wanda; El Seoud, Omar A. J. Chem. Educ. 2005, 82, 257.
Water / Water Chemistry |
Consumer Chemistry
Capillary Electrophoresis Analysis of Cations in Water Samples. An Experiment for the Introductory Laboratory  Christopher J. Pursell, Bert Chandler, and Michelle M. Bushey
This experiment can be done in a lab, as a "dry-lab", or as an in-class exercise. Students explore a number of basic separation topics and work with figures of merit for real and meaningful samples. We have adopted a strategy where students encounter various instruments and methods of analyses multiple times throughout the curriculum. The level of sophistication in the exposures increases with the experience level of the students. Through this repeated exposure students will gain a better and fuller understanding of these methods than they would with a single exposure to the technique in the analytical or instrumental laboratory.
Pursell, Christopher J.; Chandler, Bert; Bushey, Michelle M. J. Chem. Educ. 2004, 81, 1783.
Electrophoresis |
Quantitative Analysis |
Separation Science |
Chemometrics |
Water / Water Chemistry
The Effect of Ionic Strength on the Solubility of an Electrolyte  Joan D. Willey
The theory of activity versus concentration is important in industrial, environmental, and biochemistry. The increase in solubility of an electrolyte in a solution of a second electrolyte with no common ions compared with pure water is not an easy concept to grasp because it seems to be counterintuitive. The simple experiment described here illustrates this principle visually and dramatically. Students attempt to dissolve CaSO42H2O (gypsum) in pure water and in 0.25 M NaCl.
Willey, Joan D. J. Chem. Educ. 2004, 81, 1644.
Aqueous Solution Chemistry |
Quantitative Analysis |
Water / Water Chemistry |
Solutions / Solvents
Sink Inserts for Flood Prevention  Fraser F. Fleming, Daniel J. Bodnar, and David L. Hardesty
A simple, inexpensive insert is described for preventing flooding in lab sinks. The insert is essentially a tube with slots cut into the side that fits snugly into the drain outlet, preventing water buildup and providing additional drainage sites to avoid constriction by small lab items and paper towels.
Fleming, Fraser F.; Bodnar, Daniel J.; Hardesty, David L. J. Chem. Educ. 2004, 81, 1344.
Laboratory Management |
Laboratory Equipment / Apparatus |
Water / Water Chemistry
Introduction of Mass Spectrometry in a First-Semester General Chemistry Laboratory Course: Quantification of MTBE or DMSO in Water  Mike Solow
An experiment has been developed to introduce first-semester general chemistry students to mass spectrometry. Students analyze water samples contaminated with a known compound, either DMSO or MTBE. Students are asked to determine the concentration of the compound in the water. In performing this experiment, students should learn (i) how the mass of an atom or molecule is determined, (ii) the effect of the presence of different isotopes on molecular mass, (iii) the role of an internal standard, and (iv) how mass spectrometry is used in answering various scientific questions.
Solow, Mike. J. Chem. Educ. 2004, 81, 1172.
Instrumental Methods |
Mass Spectrometry |
Quantitative Analysis |
Water / Water Chemistry |
Gas Chromatography
Surface Tension Gradients Induced by Temperature: The Thermal Marangoni Effect  Marcos Gugliotti, Mauricio S. Baptista, and Mario J. Politi
This article presents a simple experiment to demonstrate the motion of liquids induced by surface tension gradients generated by local heating.
Gugliotti, Marcos; Baptista, Mauricio S.; Politi, Mario J. J. Chem. Educ. 2004, 81, 824.
Liquids |
Surface Science |
Lasers
Boiling Point versus Mass  Michael Laing
I am very pleased that Ronald Rich has written making these comments, because he is pre-eminent in this field, beginning with his early book, Periodic Correlations.
Laing, Michael. J. Chem. Educ. 2004, 81, 642.
Atomic Properties / Structure |
Molecular Properties / Structure |
Noncovalent Interactions |
Liquids |
Phases / Phase Transitions / Diagrams
Boiling Point versus Mass   Ronald L. Rich
Laing gave a useful examination of the boiling points of small molecules versus molecular mass. However, a molecule escaping from a liquid is not closely analogous to a satellite breaking free from the earths gravitational field with the requirement of a minimum escape velocity, such that the required kinetic energy is proportional to the mass of the satellite at that escape velocity.
Rich, Ronald L. J. Chem. Educ. 2004, 81, 642.
Molecular Properties / Structure |
Atomic Properties / Structure |
Liquids |
Noncovalent Interactions |
Phases / Phase Transitions / Diagrams
Kinetics of the Osmotic Hydration of Chickpeas  Gabriel Pinto and Ali Esin
An experiment examining the swelling of chickpeas as they are soaked in water is presented to introduce students to topics such as osmotic flow, mass transfer, diffusion, kinetics of hydration, modeling, and estimation of activation energy.
Pinto, Gabriel; Esin, Ali. J. Chem. Educ. 2004, 81, 532.
Kinetics |
Water / Water Chemistry |
Food Science |
Transport Properties
Using Science Fiction To Teach Thermodynamics: Vonnegut, Ice-nine, and Global Warming  Charles A. Liberko
When covering the topic of thermodynamics at the introductory level, an example from Kurt Vonnegut, Jr's, fictional novel, Cat's Cradle, is used to take what the students have learned and apply it to a new situation.
Liberko, Charles A. J. Chem. Educ. 2004, 81, 509.
Thermodynamics |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Noncovalent Interactions |
Calorimetry / Thermochemistry
A Modular Laser Apparatus for Polarimetry, Nephelometry, and Fluorimetry in General Chemistry  Scott A. Darveau, Jessica Mueller, April Vaverka, Cheri Barta, Anthony Fitch, Jessica Jurzenski, and Yvonne Gindt
We present an apparatus suitable for multiple uses in the general chemistry laboratory including polarimetry, fluorescence, and nephelometry. The open design of the instrument also decreases the chance that students will contract the "black-box syndrome" that seems to develop when using instruments that only provide the final data in an experiment without showing how the measurements are obtained.
Darveau, Scott A.; Mueller, Jessica; Vaverka, April; Barta, Cheri; Fitch, Anthony; Jurzenski, Jessica; Gindt, Yvonne. J. Chem. Educ. 2004, 81, 401.
Fluorescence Spectroscopy |
Kinetics |
Laboratory Equipment / Apparatus |
Lasers |
Spectroscopy |
Proteins / Peptides |
Water / Water Chemistry
Magnetic Particle Technology. A Simple Preparation of Magnetic Composites for the Adsorption of Water Contaminants  Luiz C. A. Oliveira, Rachel V. R. A. Rios, José D. Fabris, Rochel M. Lago, and Karim Sapag
In this article a simple undergraduate laboratory experiment to produce magnetic adsorbents is described. These magnetic materials efficiently adsorb contaminants from water and can be easily removed from the medium by a simple magnetic separation process.
Oliveira, Luiz C.A.; Rios, Rachel V.R.A.; Fabris, José D.; Lago, Rochel M.; Sapag, Karim. J. Chem. Educ. 2004, 81, 248.
Green Chemistry |
Magnetic Properties |
Materials Science |
Separation Science |
Water / Water Chemistry
Well Wishes. A Case on Septic Systems and Well Water Requiring In-Depth Analysis and Including Optional Laboratory Experiments  Mary M. Walczak and Juliette M. Lantz
This paper describes the use of a case study to teach introductory chemistry students the chemical principles of solution concentration (especially ppm) and dilution, aqueous redox reactions, and stoichiometric conversions between different solution species.
Walczak, Mary M.; Lantz, Juliette M. J. Chem. Educ. 2004, 81, 218.
Consumer Chemistry |
Water / Water Chemistry |
Solutions / Solvents |
Oxidation / Reduction |
Stoichiometry
Three-Dimensional Model for Water: Magnets as Dipoles  Samuel H. Yalkowsky and Jennifer L. H. Johnson
Reply to comments on original article.
Yalkowsky, Samuel H.; Johnson, Jennifer L. H. J. Chem. Educ. 2004, 81, 34.
Aqueous Solution Chemistry |
Noncovalent Interactions |
Hydrogen Bonding |
Lipids |
Liquids |
Molecular Modeling |
Phases / Phase Transitions / Diagrams |
Solutions / Solvents |
Water / Water Chemistry
Three-Dimensional Model for Water: Magnets as Chemical Bonds  Roy W. Clark
Concerns over students confusing electrical and magnetic fields.
Clark, Roy W. J. Chem. Educ. 2004, 81, 34.
Aqueous Solution Chemistry |
Noncovalent Interactions |
Hydrogen Bonding |
Lipids |
Liquids |
Molecular Modeling |
Phases / Phase Transitions / Diagrams |
Solutions / Solvents |
Water / Water Chemistry
Bubble Stripping To Determine Hydrogen Concentrations in Ground Water: A Practical Application of Henry's Law  Daniel M. McInnes and Don Kampbell
Applying Henry's law to determine the concentration of hydrogen in ground water as a means of identifying possible contamination by chlorinated organic compounds.
McInnes, Daniel M.; Kampbell, Don. J. Chem. Educ. 2003, 80, 516.
Water / Water Chemistry |
Gases |
Quantitative Analysis |
Applications of Chemistry
The Analysis of Seawater: A Laboratory-Centered Learning Project in General Chemistry  Jodye I. Selco, Julian L. Roberts, Jr., and Daniel B. Wacks
Experiment designed to introduce students to qualitative and quantitative analysis methods (gravimetric analysis, potentiometric titration, ion-selective electrodes, and atomic absorption and atomic emission spectroscopy) in the context of an overall analysis of an environmental sample.
Selco, Jodye I.; Roberts, Julian L., Jr.; Wacks, Daniel B. J. Chem. Educ. 2003, 80, 54.
Aqueous Solution Chemistry |
Instrumental Methods |
Qualitative Analysis |
Quantitative Analysis |
Water / Water Chemistry |
Gravimetric Analysis |
Titration / Volumetric Analysis |
Ion Selective Electrodes |
Atomic Spectroscopy |
Potentiometry
Use of Chloroisocyanuarates for Disinfection of Water: Application of Miscellaneous General Chemistry Topics  Gabriel Pinto and Brian Rohrig
Using the chlorination of water (using sodium dichloroisocyanurate and trichloroisocyanuric acid) to develop general chemistry concepts; includes question for students and answers.
Pinto, Gabriel; Rohrig, Brian. J. Chem. Educ. 2003, 80, 41.
Stoichiometry |
Water / Water Chemistry |
Applications of Chemistry |
Photochemistry
The Liquid Nitrogen Fountain  Robin McRae, Jeffrey A. Rahn, Timothy W. Beamer, and Norm LeBret
Pouring liquid nitrogen into a one-half liter plastic soda bottle and sealing with a large balloon.
McRae, Robin; Rahn, Jeffrey A.; Beamer, Timothy W.; LeBret, Norm . J. Chem. Educ. 2002, 79, 1220.
Liquids
A Three-Dimensional Model for Water  J. L. H. Johnson and S. H. Yalkowsky
Using Molymod spheres and magnets to simulate the structure and properties of water and aqueous systems.
Johnson, J. L. H.; Yalkowsky, S. H. J. Chem. Educ. 2002, 79, 1088.
Aqueous Solution Chemistry |
Covalent Bonding |
Lipids |
Liquids |
Solutions / Solvents |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
Is Salt Melting When It Dissolves in Water?  Alan Goodwin
Analysis of the chemical meaning of the terms melting and dissolving.
Goodwin, Alan. J. Chem. Educ. 2002, 79, 393.
Liquids |
Solids |
Phases / Phase Transitions / Diagrams
A Discovery-Based Experiment Illustrating How Iron Metal Is Used to Remediate Contaminated Groundwater  Barbara A. Balko and Paul G. Tratnyek
Procedure in which students investigate the chemistry of iron-permeable reactive barriers and their application to the remediation of contaminated groundwater.
Balko, Barbara A.; Tratnyek, Paul G. J. Chem. Educ. 2001, 78, 1661.
Kinetics |
Oxidation / Reduction |
Water / Water Chemistry |
Metals |
Applications of Chemistry |
Aqueous Solution Chemistry
Humic Acids: Marvelous Products of Soil Chemistry  Geoffrey Davies, Elham A. Ghabbour, and Cornelius Steelink
Classification, physical and chemical characteristics, formation, structure and sources of humic substances.
Davies, Geoffrey; Ghabbour, Elham A.; Steelink, Cornelius. J. Chem. Educ. 2001, 78, 1609.
Agricultural Chemistry |
Metals |
Natural Products |
Plant Chemistry |
Water / Water Chemistry |
Applications of Chemistry
Boiling Points of the Family of Small Molecules CHwFxClyBrz: How Are They Related to Molecular Mass?  Michael Laing
Investigating the role of molecular mass in determining boiling points of small molecules.
Laing, Michael. J. Chem. Educ. 2001, 78, 1544.
Atomic Properties / Structure |
Noncovalent Interactions |
Liquids |
Molecular Properties / Structure |
Physical Properties
Teaching Brønsted-Lowry Acid-Base Theory in a Direct Comprehensive Way  Jamie L. Adcock
Unifying all the Bronsted-Lowry acid-base concepts in a quantitative way.
Adcock, Jamie L. J. Chem. Educ. 2001, 78, 1495.
Acids / Bases |
Equilibrium |
Learning Theories |
Water / Water Chemistry |
Brønsted-Lowry Acids / Bases
The Use of an Inexpensive Laser Pointer to Perform Qualitative and Semiquantitative Laser Refractometry  Amarílis de Vicente Finageiv Neder, Edgardo García, and Leonardo N. Viana
A simple, low-cost refractometry experiment designed for inexperienced students or use as a demonstration to estimate the refractive index of various liquids.
Neder, Amarílis de Vicente Finageiv; García, Edgardo; Viana, Leonardo N. J. Chem. Educ. 2001, 78, 1481.
Laboratory Equipment / Apparatus |
Lasers |
Spectroscopy |
Liquids |
Qualitative Analysis |
Physical Properties
The Purification of Water by Freeze-Thaw or Zone Melting  James Oughton, Silas Xu, and Rubin Battino
Quantitative investigation of the purification of slat water solutions through the process of partial freezing.
Oughton, James; Xu, Silas; Battino, Rubin. J. Chem. Educ. 2001, 78, 1373.
Conductivity |
Phases / Phase Transitions / Diagrams |
Separation Science |
Quantitative Analysis |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
A Microscale Spectrophotometric Determination of Water Hardness  James S. Gordon
Measuring water hardness using EDTA as a titrant, calmagite as an indicator, a colorimeter, and a graphing calculator.
Gordon, James S. J. Chem. Educ. 2001, 78, 1089.
UV-Vis Spectroscopy |
Water / Water Chemistry |
Titration / Volumetric Analysis
Chemical Laboratory Information Profile: Water  Jay A. Young
Properties, hazards, and storage requirements for water.
Young, Jay A. J. Chem. Educ. 2001, 78, 874.
Laboratory Management |
Physical Properties |
Water / Water Chemistry
Thermodynamics of Water Superheated in the Microwave Oven  B. H. Erné
Water is conveniently heated above its normal boiling point in a microwave oven in a glass microwave oven teapot. Water stops boiling soon after heating is interrupted, but subsequently added rough particles can still act as nucleation centers for a brief, spectacular burst of steam bubbles. The heat to make those steam bubbles obviously comes from the water itself, so that one can conclude that the boiling water was superheated, which is confirmed with a thermometer.
Erné, B. H. J. Chem. Educ. 2000, 77, 1309.
Thermodynamics |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Liquids
Turbulent Motion in Ethyl Acetate-Water System  Jamil Ahmad
4 mL of ethyl acetate is added to 10 mL of water in a Petri dish. Within a minute or so, an image of turbulent motion appears on the screen, at first at a few centers that eventually organize themselves in a line. The image of the line of turbulence is quite striking and resembles a moving front of dancing flames.
Ahmad, Jamil. J. Chem. Educ. 2000, 77, 1182.
Liquids |
Solutions / Solvents |
Surface Science
Weak vs Strong Acids and Bases: The Football Analogy  Todd P. Silverstein
A football analogy for acids and bases in which acids are compared to quarterbacks, whose job is to get rid of the ball (H+). A strong acid, like an excellent quarterback, delivers the ball effectively; a weak acid, like a poor quarterback, is often left holding the ball. Furthermore, bases may be likened to wide receivers, whose job is to catch and hold onto the ball (H+).
Silverstein, Todd P. J. Chem. Educ. 2000, 77, 849.
Acids / Bases |
Aqueous Solution Chemistry |
Water / Water Chemistry |
Brønsted-Lowry Acids / Bases
Liver and Onions: DNA Extraction from Animal and Plant Tissues  Karen J. Nordell, Anne-Marie L. Jackelen, S. Michael Condren, George C. Lisensky, and Arthur B. Ellis*
This activity, which allows students to extract DNA from plant and animal cells, serves as a spectacular example of the complexity of biochemical structure and function and fits well with a discussion of nucleic acids, hydrogen bonding, genetic coding, and heredity. DNA extraction can also be used in conjunction with a discussion of polymers and their properties.
Nordell, Karen J.; Jackelen, Anne-Marie L.; Condren, S. Michael; Lisensky, George C.; Ellis, Arthur B. J. Chem. Educ. 1999, 76, 400A.
Hydrogen Bonding |
Molecular Properties / Structure |
Nucleic Acids / DNA / RNA
Remediation of Water Contaminated with an Azo Dye: An Undergraduate Laboratory Experiment Utilizing an Inexpensive Photocatalytic Reactor  John A. Bumpus, Jennifer Tricker, Ken Andrzejewski, Heather Rhoads, and Matthew Tatarko
The construction and use of an inexpensive photocatalytic reactor that utilizes titanium dioxide as the photocatalyst for wastewater treatment is described. In these experiments and in supplementary material, students are made aware that a variety of techniques have been developed to treat wastewaters, including those generated by the chemical industry. Water contaminated with the azo dye Congo Red was selected as an example of how one might treat contaminated water from a textile manufacturing facility.
Bumpus, John A.; Tricker, Jennifer; Andrzejewski, Ken; Rhoads, Heather; Tatarko, Matthew. J. Chem. Educ. 1999, 76, 1680.
Photochemistry |
Dyes / Pigments |
Laboratory Equipment / Apparatus |
Applications of Chemistry |
Water / Water Chemistry
Pesticides in Drinking Water: Project-Based Learning within the Introductory Chemistry Curriculum  Patricia B. O'Hara, Jon A. Sanborn, and Meredith Howard
A new introductory chemistry module is described, which has as its central theme the measurement of trace levels of these xenoestrogens in the form of pesticides in the Town of Amherst's public drinking water. After a basic introduction to sample handling and measurement of pH, temperature, and conductivity, the students travel in small groups to several sites to collect water and perform preliminary characterization of their samples.
OHara, Patricia B.; Sanborn, Jon A.; Howard, Meredith. J. Chem. Educ. 1999, 76, 1673.
Mass Spectrometry |
Water / Water Chemistry |
Toxicology |
Applications of Chemistry
Learning Quality Assurance/Quality Control Using U.S. EPA Techniques. An Undergraduate Course for Environmental Chemistry Majors  Susan M. Libes
In the environmental realm, quality control (QC) includes activities associated with sampling, sample preservation and storage, method validation, and analysis involving solids, liquids, and gases. Students should be led to discover the need for QC by first performing analyses with little guidance. This is followed by a class discussion in which they critique their data.
Libes, Susan. J. Chem. Educ. 1999, 76, 1642.
Instrumental Methods |
Quantitative Analysis |
Water / Water Chemistry
Using TOPEX Satellite El Niño Altimetry Data to Introduce Thermal Expansion and Heat Capacity Concepts in Chemistry Courses  Harvey F. Blanck
Warm water is less dense than cool water and will float somewhat like ice, with a portion above the surface of the cooler surrounding water. The height of the bump can be used to estimate the excess thermal energy in the warmer water.
Blanck, Harvey F. J. Chem. Educ. 1999, 76, 1635.
Liquids |
Thermodynamics |
Water / Water Chemistry |
Calorimetry / Thermochemistry
The Solubility of Ionic Solids and Molecular Liquids  C. Baer and Sheila M. Adamus
The solubilities of three ionic salts (NaCl, PbCl2, and KAl(SO4)2.12H2O) in water are measured at four temperatures. The concept of recrystallization is introduced as students cool a high-temperature solution and observe crystal formation. Spreadsheet calculations are performed with the group data, which are then graphed, and students observe the wide variance in solubility behavior for the three salts.
Baer, Carl; Adamus, Sheila M. J. Chem. Educ. 1999, 76, 1540.
Noncovalent Interactions |
Laboratory Computing / Interfacing |
Liquids |
Molecular Properties / Structure |
Solutions / Solvents
The Softening of Hard Water and Complexometric Titrations: An Undergraduate Experiment  Helena Ceretti, Enrique A. Hughes, and Anita Zalts
An experiment in which (i) water hardness is explained and demonstrated; (ii) ion-exchange resin properties are visually demonstrated and then used for softening water; (iii) complexometric titrations are used for evaluating water hardness before and after softening; and (iv) acid-base titration can be used to show that the Ca/Mg ions removed by the ion exchanger are replaced by H ions.
Ceretti, Helena; Hughes, Enrique A.; Zalts, Anita. J. Chem. Educ. 1999, 76, 1420.
Ion Exchange |
Quantitative Analysis |
Titration / Volumetric Analysis |
Water / Water Chemistry |
Acids / Bases
Experiments with Zeolites at the Secondary-School Level: Experience from The Netherlands  Eric N. Coker, Pamela J. Davis, Aonne Kerkstra, and Herman van Bekkum
This article describes a number of experiments that involve zeolites and are suitable for secondary-school chemistry laboratories. Students test the hardness of tap water before and after treatment with some zeolite and perform tests with a range of commercial laundry detergents containing zeolites.
Coker, Eric N.; Davis, Pamela J.; Kerkstra, Aonne; van Bekkum, Herman. J. Chem. Educ. 1999, 76, 1417.
Ion Exchange |
Catalysis |
Quantitative Analysis |
Water / Water Chemistry |
Consumer Chemistry |
Applications of Chemistry
Cleaning Up with Chemistry: Investigating the Action of Zeolite in Laundry Detergent  
In this activity, you will investigate the properties of one ingredient, aluminosilicate. The particular aluminosilicate used in powdered laundry detergent is sodium zeolite A. In this activity, you will extract sodium zeolite A from powdered laundry detergent and examine its properties.
J. Chem. Educ. 1999, 76, 1416A.
Materials Science |
Consumer Chemistry |
Applications of Chemistry |
Separation Science |
Water / Water Chemistry |
Ion Exchange
Relative Humidity  R. Bruce Martin
Daily we hear reports of relative humidity, yet most students remain unfamiliar with its import. This short article defines and describes the concept at several levels. A new, general interest, isobaric plot directly indicates the dependence of relative humidity on temperature.
Martin, R. Bruce. J. Chem. Educ. 1999, 76, 1081.
Consumer Chemistry |
Gases |
Nonmajor Courses |
Water / Water Chemistry |
Atmospheric Chemistry
Predicting Acid-Base Titration Curves without Calculations  Dennis W. Barnum
In this paper a qualitative and systematic method for sketching titration curves is presented. Even the more complex cases such as salts or polyprotic acids and bases are treated just as easily as simple monoprotic acids. Having students predict the shape of titration curves from known equilibrium constants helps to focus attention on the general principles without distraction by the mathematics.
Barnum, Dennis W. J. Chem. Educ. 1999, 76, 938.
Acids / Bases |
Quantitative Analysis |
Water / Water Chemistry |
Equilibrium |
Learning Theories |
Titration / Volumetric Analysis |
Chemometrics
Ammonia Can Crush  Ed Vitz
When a 12-oz aluminum soft drink can filled with ammonia or hydrogen chloride gas is inverted and dipped into water, the rapidly dissolving gas evacuates the can and the can is crushed before water can be drawn into it. This demonstrates, among other things, the remarkable strength of hydrogen bonds.
Vitz, Ed. J. Chem. Educ. 1999, 76, 932.
Noncovalent Interactions |
Gases |
Solutions / Solvents |
Hydrogen Bonding
The Chemistry of Water (by Susan E. Kegley and Joy Andrews)  Debra J. McCool
The Chemistry of Water is a super book. It is more than a textbook, more than a lab manual. There is a great amount of good chemistry packed into its 160 pages. This module looks at the purity of water and methods to assess water quality.
McCool, Debra J. J. Chem. Educ. 1999, 76, 326.
Water / Water Chemistry
Spring Shock!: Impact of Spring Snowmelt on Lakes and Streams  Judith A. Halstead
This activity uses frozen vinegar to demonstrate that what melts first forms a liquid more concentrated in acetic acid than normal vinegar. As melting continues, the concentration of acetic acid decreases and the pH goes up.
Judith A. Halstead. J. Chem. Educ. 1998, 75, 400A.
Acids / Bases |
Water / Water Chemistry
On the Surface: Mini-Activities Exploring Surface Phenomena  
Activities listed can be used to introduce surface tension and surface area when discussing liquids and gases.
J. Chem. Educ. 1998, 75, 176A.
Surface Science |
Liquids |
Gases |
Kinetics
Identifying Bottled Water: A Problem-Solving Exercise in Chemical Identification  Richard L. Myers
Students are challenged to identify water samples using the known chemical analyses of bottled waters. Several common water quality measurements such as hardness, alkalinity, and ion analysis can be used by students to identify the unknown water. This exercise develops problem-solving skills as students become familiar with basic lab techniques, quality control, data interpretation, and standard methods.
Myers, Richard L. J. Chem. Educ. 1998, 75, 1585.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Qualitative Analysis |
Consumer Chemistry
How To Learn and Have Fun with Poly(Vinyl Alcohol) and White Glue  V. de Zea Bermudez, P. Passos de Almeida, and J. Féria Seita
The general behavior of Newtonian, shear-thinning, shear-thickening, thixotropic, negative thixotropic, and viscoelastic fluids is characterized and briefly discussed in terms of existing theoretical models. Whenever possible, examples of these types of fluids taken from everyday life are given for better understanding.
de Zea Bermudez, Verónica; de Almeida, P. Passos; Seita, J. Féria. J. Chem. Educ. 1998, 75, 1410.
Alcohols |
Liquids
Intermolecular Forces in Introductory Chemistry Studied by Gas Chromatography, Computer Models, and Viscometry  Jonathan C. Wedvik, Charity McManaman, Janet S. Anderson, and Mary K. Carroll
Students performing gas chromatographic (GC) analyses of mixtures of n-alkanes and samples that simulate crime scene evidence discover that liquid mixtures can be separated rapidly into their components based upon intermolecular forces. Each group of students is given a liquid sample that simulates one collected at an arson scene, and the group is required to determine the identity of the accelerant. Students also examine computer models to better visualize how molecular structure affects intermolecular forces: London forces, dipole-dipole interactions, and hydrogen bonding.
Wedvik, Jonathan C.; McManaman, Charity; Anderson, Janet S.; Carroll, Mary K. J. Chem. Educ. 1998, 75, 885.
Theoretical Chemistry |
Chromatography |
Noncovalent Interactions |
Gas Chromatography |
Molecular Modeling |
Forensic Chemistry |
Alkanes / Cycloalkanes |
Hydrogen Bonding |
Molecular Properties / Structure
Why Do Alcoholic Beverages Have "Legs"?  Todd P. Silverstein
After a sip of wine, "legs" of liquid typically run up and down the inside of the glass for many minutes. This phenomenon stems from the dipole-dipole intermolecular forces that are so important in understanding the physical behavior of aqueous solutions.
Silverstein, Todd P. J. Chem. Educ. 1998, 75, 723.
Noncovalent Interactions |
Aqueous Solution Chemistry |
Learning Theories |
Alcohols |
Hydrogen Bonding
Teaching Distillation Knowledge: A Video Film about Distillation Bridging a Gap Between Theory and Practice  Martin J. Goedhart, Hanno van Keulen, Theo M. Mulder, Adri H. Verdonk, and Wobbe De Vos
The authors observed that first year students hardly used their knowledge of phase theory in the design and performance of distillations. They therefore developed a video in which they confront students with the boiling properties of liquid mixtures.
Goedhart, Martin J.; van Keulen, Hanno; Mulder, Theo M.; Verdonk, Adri H.; De Vos, Wobbe. J. Chem. Educ. 1998, 75, 378.
Learning Theories |
Phases / Phase Transitions / Diagrams |
Separation Science |
Liquids |
Physical Properties
The Real Reason Why Oil and Water Don't Mix  Todd P. Silverstein
Authors should remove from their textbooks the incorrect enthalpic/hydrogen-bond explanation for the hydrophobic effect. Because aspects of the correct entropic/clathrate "cage" explanation lie beyond the scope of introductory or organic chemistry courses, it may be wisest to omit any detailed physical explanation of the "like dissolves like" phenomenon.
Silverstein, Todd P. J. Chem. Educ. 1998, 75, 116.
Theoretical Chemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
The Source of the Cloud Produced upon Adding Dry Ice to Water  Manu Kohli, Rudy L. Luck, and Veka Ohtamaa
Explains why a cloud is produced by adding dry ice to water.
Kohli, Manu; Luck, Rudy L.; Ohtamaa, Veka. J. Chem. Educ. 1998, 75, 60.
Solutions / Solvents |
Water / Water Chemistry
A Simple Demonstration of How Intermolecular Forces Make DNA Helical  Michael F. Bruist
The usage of stacked identical boxes can be used to demonstrate the helical shape of DNA by the effect of intermolecular forces.
Bruist, Michael F. J. Chem. Educ. 1998, 75, 53.
Molecular Properties / Structure |
Hydrogen Bonding |
Noncovalent Interactions |
Molecular Modeling
Acid Rain Demonstration: The Formation of Nitrogen Oxides as a By-Product of High-Temperature Flames in Connection with Internal Combustion Engines  Jerry A. Driscoll
This demonstration illustrates the formation of nitrogen oxides resulting from a high temperature flame.
Driscoll, Jerry A. J. Chem. Educ. 1997, 74, 1424.
Equilibrium |
Learning Theories |
Water / Water Chemistry |
Oxidation / Reduction
Complexometric Titrations: Competition of Complexing Agents in the Determination of Water Hardness with EDTA  M. Cecilia Yappert and Donald B. DuPre
The competition of complexing agents for the same metal ion and the formation of colored metal-ion complexes is demonstrated with the use of an overhead projector. This demonstration can be used to emphasize both the relevance of the relative values of formation constants in the complexation of metal cations and the applicability of complexometric titrations in quantitative chemical analysis.
Yappert, M. Cecilia; DuPre, Donald B. J. Chem. Educ. 1997, 74, 1422.
Equilibrium |
Coordination Compounds |
Qualitative Analysis |
Quantitative Analysis |
Titration / Volumetric Analysis |
Aqueous Solution Chemistry |
Water / Water Chemistry |
Metals
A Discussion of Water Pollution in the United States and Mexico; with High School Laboratory Activities for the Analysis of Lead, Atrazine, and Nitrate  Paul B. Kelter, Julie Grundman, David S. Hage, James D. Carr, and Carlos Mauricio Castro-Acuña
In the first part of this paper we present an overview of water pollution in the United States and Mexico, including sources, federal regulations and standards, and standard methods for the assessment of overall water quality. The second part of the paper focuses on three water pollutants, lead, atrazine, and nitrate.
Kelter, Paul B.; Grundman, Julie; Hage, David S.; Carr, James D.; Mauricio, Carlos. J. Chem. Educ. 1997, 74, 1413.
Water / Water Chemistry
Integrating High School Chemistry with Environmental Studies and Research  Jack Randall
This article is a summary of a presentation made at the 1996 BCCE in Clemson, SC, as part of a symposium detailing the integration of environmental topics into Chemistry curricula. High school chemistry has long used environmental topics to enhance the study of various components of the curriculum. This article illustrates the benefits of incorporating environmental science as an integral part of a high school Chemistry course.
Randall, Jack. J. Chem. Educ. 1997, 74, 1409.
Learning Theories |
Nonmajor Courses |
Water / Water Chemistry
News from Online  Carolyn Sweeney Judd
WWW sites related to water and related environmental issues.
Judd, Carolyn Sweeney. J. Chem. Educ. 1997, 74, 1394.
Water / Water Chemistry
The Disappearing Liquid  H. D. Gesser and Ian Ward
Mixing ethanol and water in a volumetric flask results in a noticeable reduction in the volume of the mixture.
Gesser, H. D.; Ward, Ian. J. Chem. Educ. 1997, 74, 1357.
Liquids |
Solutions / Solvents |
Atomic Properties / Structure
A Quantitative Conductance Apparatus  Danny Burns and Don Lewis
Circuitry, electrode configuration and calibration procedures are described for a conductance device. An alternative construction of the circuit is given allowing computer capture of the instrument response.
Burns, Danny; Lewis, Don. J. Chem. Educ. 1997, 74, 570.
Instrumental Methods |
Conductivity |
Liquids |
Solutions / Solvents |
Laboratory Equipment / Apparatus
Boiling Point and Molecular Weight  Rich, Ronald L.
No relationship between boiling points and molecular weight.
Rich, Ronald L. J. Chem. Educ. 1996, 73, A294.
Physical Properties |
Hydrogen Bonding |
Noncovalent Interactions
Letters  
No relationship between boiling points and molecular weight.
J. Chem. Educ. 1996, 73, A294.
Physical Properties |
Hydrogen Bonding |
Noncovalent Interactions
Micropath Distillation Apparatus  N. K. Hazra and D. Mal
A shortpath distillation apparatus in its inverted position can be used for microscale distillation of a liquid sample. This article describes the process.
Hazra, N. K.; Mal, D. J. Chem. Educ. 1996, 73, A103.
Microscale Lab |
Separation Science |
Laboratory Equipment / Apparatus |
Liquids
How to Offer the Optimal Demonstration of the Electrolysis of Water  Rei E. Zhou
This article proposes the optimal conditions for lecture demonstration to ensure that the generated H2 and O2 in the electrolysis of water are in the ratio of 2:1, satisfying the reaction scheme.
Zhou, Rei E. J. Chem. Educ. 1996, 73, 786.
Water / Water Chemistry
Using Physics Principles in the Teaching of Chemistry  Warren Gulden
Chemistry and physics may be separate subjects, but that should not prohibit the use of physics in a chemistry course. When this is done, students can use traditional physics principles or laws for the purpose of understanding chemistry better.
Gulden, Warren. J. Chem. Educ. 1996, 73, 771.
Ionic Bonding |
Physical Properties |
Electrochemistry |
Hydrogen Bonding
Constant-Current Coulometric Titration of Hydrochloric Acid  James Swim, Edward Earps, Laura M. Reed, and David Paul
In this experiment we have combined the titration of a strong acid with a strong base and the electrolysis of water into one complete laboratory experience.
James Swim, Edward Earps, Laura M. Reed, and David Paul. J. Chem. Educ. 1996, 73, 679.
Titration / Volumetric Analysis |
Acids / Bases |
Water / Water Chemistry |
Electrochemistry |
Oxidation / Reduction
Determination of Polychlorinated Biphenyls (PCBs) in River and Bay Sediments: An Undergraduate Laboratory Experiment in Environmental Chemistry Using Capillary Gas Chromatography with Electron Capture Detection  Susan E. Kegley, Kristen J. Hansen, and Kevin L. Cunningham
This paper briefly discusses the history of PCB use and provides guidelines for finding and evaluating PCB-contaminated sites as a way to interest students by showing them an application of chemistry to the "real world."
Kegley, Susan E.; Hansen, Kristen J.; Cunningham, Kevin L. J. Chem. Educ. 1996, 73, 558.
Water / Water Chemistry |
Gas Chromatography |
Applications of Chemistry |
Separation Science |
Solutions / Solvents
Why Don't Water and Oil Mix?  Katia Pravia and David F. Maynard
To develop an understanding of the molecular interactions of polar and nonpolar molecules, we have developed two simple and extremely useful overhead projection demonstrations that help students conceptualize the solubility rules.
Katia Pravia and David F. Maynard. J. Chem. Educ. 1996, 73, 497.
Hydrogen Bonding |
Covalent Bonding |
Precipitation / Solubility |
Molecular Properties / Structure
The Bobbing (Drinking) Bird  H. D. Gesser
This article answers the question of when the bobbing bird will stop bobbing. It offers two scenarios in which the bird will discontinue its bobbing motion.
Gesser, H. D. J. Chem. Educ. 1996, 73, 355.
Water / Water Chemistry
The Solubility of Gases in Liquids  L. H. Holmes, Jr.
This short article addresses the solubility of gases in liquids. It describes the confusion that appears in some general chemistry textbooks concerning the qualitative dependence of solubility on temperature for gases and offers an opinion on the subject.
Holmes, L. H., Jr. J. Chem. Educ. 1996, 73, 143.
Precipitation / Solubility |
Gases |
Liquids
A No-Cost Model of Liquid Structure  Allikayala Ramachandraiah
This article describes a no-cost and readily available model for visualizing the structure of a liquid.
Ramachandraiah, Allikayala. J. Chem. Educ. 1996, 73, 59.
Liquids |
Kinetic-Molecular Theory
Dynamite Demo?  Dale D. Clyde
Caution for boiling-water-with-ice demonstration.
Clyde, Dale D. J. Chem. Educ. 1995, 72, 1130.
Phases / Phase Transitions / Diagrams |
Liquids |
Gases
Crystallization of Supersaturated Sodium Acetate and the Temperature Dependence of the Autoionization Constant of Water  Joseph A. Pergler, Ronald O. Ragsdale, and Thomas G. Richmond
A procedure to qualitatively demonstrate the variation of the autoionization constant of water with temperature.
Pergler, Joseph A.; Ragsdale, Ronald O.; Richmond, Thomas G. J. Chem. Educ. 1995, 72, 1027.
Crystals / Crystallography |
Aqueous Solution Chemistry |
Solutions / Solvents |
Acids / Bases |
Precipitation / Solubility |
Water / Water Chemistry
A New Low-Cost Apparatus for Electrolysis of Water   Chieko Suzuki
Low-cost alternative to the Hofmann apparatus for the electrolysis of water.
Suzuki, Chieko. J. Chem. Educ. 1995, 72, 912.
Electrochemistry |
Water / Water Chemistry |
Laboratory Equipment / Apparatus
Can London Dispersion Forces Be Stronger than Dipole-Dipole Forces, Including Hydrogen Bonds?  Thomas T. Earles
Using French fries as an example in which London dispersion forces are stronger than dipole-dipole forces.
Earles, Thomas T. J. Chem. Educ. 1995, 72, 727.
Noncovalent Interactions |
Hydrogen Bonding
An Environmental Chemistry Curriculum Using Case Studies  Cheng, Vincent K. W.
Using case studies to make environmental chemistry more interesting and relevant for students.
Cheng, Vincent K. W. J. Chem. Educ. 1995, 72, 525.
Water / Water Chemistry |
Industrial Chemistry
Lake Study for Macintosh  Whisnant, David M.; McCormick, James; Wagner, Paul
Software to simulate determination of the cause of fishkill in a lake.
Whisnant, David M.; McCormick, James; Wagner, Paul J. Chem. Educ. 1995, 72, 492.
Water / Water Chemistry
Proper Waste Disposal Procedures (the author replies)  Sherman, Marie C.
Response to objections regarding improper waste disposal.
Sherman, Marie C. J. Chem. Educ. 1995, 72, 286.
Water / Water Chemistry |
Laboratory Management
Proper Waste Disposal Procedures  Clarke, Karl
Objection to improper recommendation for waste disposal.
Clarke, Karl J. Chem. Educ. 1995, 72, 286.
Water / Water Chemistry |
Laboratory Management
Experiments for Modern Introductory Chemistry: The Temperature Dependence of Vapor Pressure  Kildahl, Nicholas; Berka, Ladislav H.
Gas chromatography experiment that allows the discovery of the temperature dependence of the vapor pressure of a pure liquid; includes sample data and analysis.
Kildahl, Nicholas; Berka, Ladislav H. J. Chem. Educ. 1995, 72, 258.
Gases |
Liquids |
Gas Chromatography
An Environmental Distillation Experiment for Nonscience Majors  Soriano, David S.; Draeger, Jon A.
Comparison of total dissolved solids for several samples of water before and after a single, simple distillation.
Soriano, David S.; Draeger, Jon A. J. Chem. Educ. 1995, 72, 84.
Separation Science |
Water / Water Chemistry
Checking Trace Nitrate in Water and Soil Using an Amateur Scientist's Measurement Guide  Baker, Roger C., Jr.
Procedures and apparatus (photometer) for measuring concentrations of nitrates in water and soil using common equipment and materials; includes data and analysis.
Baker, Roger C., Jr. J. Chem. Educ. 1995, 72, 57.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Agricultural Chemistry
Journey around a Phase Diagram  Kildahl, Nicholas K.
This paper deals in depth with questions that arise from phase diagrams in an introductory level chemistry course.
Kildahl, Nicholas K. J. Chem. Educ. 1994, 71, 1052.
Phases / Phase Transitions / Diagrams |
Gases |
Liquids
A Simple "Back of the Envelope" Method for Estimating the Densities and Molecular Volumes of Liquids and Solids  Girolami, Gregory S.
The method described for the estimation of densities and molecular volumes are surprisingly accurate and very simple.
Girolami, Gregory S. J. Chem. Educ. 1994, 71, 962.
Physical Properties |
Liquids |
Solids
Soda Water, Supercooling or Freezing Point Depression?  Brooker, Murray H.
Composition, preparation, properties, and behavior of soda water.
Brooker, Murray H. J. Chem. Educ. 1994, 71, 903.
Gases |
Water / Water Chemistry |
Precipitation / Solubility |
Solutions / Solvents |
Consumer Chemistry
Experiments for Modern Introductory Chemistry: Intermolecular Forces and Raoult's Law  Berka, Ladislav H.; Kildahl, Nicholas
Procedure that illustrates the liquid-vapor phase equilibrium of ideal and nonideal solutions.
Berka, Ladislav H.; Kildahl, Nicholas J. Chem. Educ. 1994, 71, 613.
Noncovalent Interactions |
Gas Chromatography |
Gases |
Liquids |
Equilibrium |
Solutions / Solvents
Testing the Waters for Chromium  Herrmann, Mary S.
A test for the presence of Cr(IV) in water using a sensitive colorimetric reagent.
Herrmann, Mary S. J. Chem. Educ. 1994, 71, 323.
Water / Water Chemistry |
Metals |
Quantitative Analysis
A small-scale, easy-to-run wastewater-treatment plant: The treatment of an industrial water that contains suspended clays and soluble salts   Alvaro, Mercedes; Espla, Mercedes; Llinares, Jesus; Martinez-Manez, Ramon; Soto, Juan
Chemistry students are often interested in the chemical principles involved in industrial processes, the pollutants and waste products are generated, and their removal. This experiment introduces students to several theoretical concepts as they apply to real physical and chemical waste-treatment processes.
Alvaro, Mercedes; Espla, Mercedes; Llinares, Jesus; Martinez-Manez, Ramon; Soto, Juan J. Chem. Educ. 1993, 70, A129.
Water / Water Chemistry |
Green Chemistry |
Industrial Chemistry |
Colloids |
Separation Science
Pictorial analogies IX: Liquids and their properties   Fortman, John J.
Liquids on the molecular level, surface tension, and vapor pressure are explained through visual analogies of a class reunion and movie patrons.
Fortman, John J. J. Chem. Educ. 1993, 70, 881.
Liquids |
Gases |
Surface Science
A two-dimensional model for water  Yalkowsky, Samuel H.
The tetrahedral arrangement of the two hydrogen atoms and two electron pairs of the water molecule are difficult to represent diagrammatically in two dimensions, resulting in great difficulty to explain the anomalous properties of water. Nonetheless, the author illustrates the great insights that can be gained from two-dimensional analogies.
Yalkowsky, Samuel H. J. Chem. Educ. 1993, 70, 614.
Water / Water Chemistry
Why is water blue?  Braun, Charles L.; Smirnov, Sergei N.
Exploring the problem of why water in a beaker appears to be clear, yet we see large bodies of water as blue in color.
Braun, Charles L.; Smirnov, Sergei N. J. Chem. Educ. 1993, 70, 612.
Atomic Spectroscopy |
Water / Water Chemistry
A water treatment experiment (chemical hardness) for nonscience majors  Soriano, David S.; Draeger, Jon A.
Description of an activity used in a nonmajors course called 'Chemistry and Society'.
Soriano, David S.; Draeger, Jon A. J. Chem. Educ. 1993, 70, 414.
Water / Water Chemistry |
Nonmajor Courses |
Instrumental Methods
Introducing the treatment of waste and wastewater in the general chemistry course: Applying physical and chemical principles to the problems of waste management  Dhawale, S. W.
Students learn simple lab techniques so that they can discuss applications such as cleanup of small-scale oil spills and the processes used to obtain drinkable pure water.
Dhawale, S. W. J. Chem. Educ. 1993, 70, 395.
Water / Water Chemistry |
Green Chemistry |
Applications of Chemistry
Polarity, miscibility, and surface tension of liquids   Silverstein, Todd P.
A very simple overhead projector demonstration using water and ethanol to give a dramatic visual illustration of cohesive and adhesive forces.
Silverstein, Todd P. J. Chem. Educ. 1993, 70, 253.
Water / Water Chemistry |
Solutions / Solvents
Lowering the surface tension of water: An illustration of the scientific method   Jasien, Paul G.; Barnett, Glenn
This demonstration has been effective in simulating a good discussion in class: floating non-wettable substances on the surface of water and touching the surface with a bar of soap.
Jasien, Paul G.; Barnett, Glenn J. Chem. Educ. 1993, 70, 251.
Water / Water Chemistry
Microscale experiments: Dissolved oxygen and chloride determination in water  Crosson, Mary; Gibb, Reen
Determining the dissolved oxygen and chloride content of water samples through titrations.
Crosson, Mary; Gibb, Reen J. Chem. Educ. 1992, 69, 830.
Microscale Lab |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis
Viscosity of polymer solutions  Bertrand, Gary L.
This program contains three components: "Density of Liquids", "Viscosity of Liquids", and "Viscosity of Polymer Solutions".
Bertrand, Gary L. J. Chem. Educ. 1992, 69, 818.
Solutions / Solvents |
Physical Properties |
Liquids
A modern vapor pressure apparatus based on the isoteniscope.  Van Hecke, Gerald R.
Equipment used for vapor pressure measurements that eliminates use of a mercury manometer.
Van Hecke, Gerald R. J. Chem. Educ. 1992, 69, 681.
Laboratory Equipment / Apparatus |
Gases |
Liquids
Capillary radius and surface tensions: Using calculations based on Tate's law.  Worley, John D.
An experiment that can be carried out without the use of a tensiometer or any other complex or expensive apparatus except for a balance.
Worley, John D. J. Chem. Educ. 1992, 69, 678.
Water / Water Chemistry |
Surface Science
The thermodynamics of home-made ice cream.  Gibbon, Donald L.; Kennedy, Keith; Reading, Nathan; Quieroz, Mardsen.
Using the production of ice cream to teach heat capacity, viscosity, and freezing-point reduction.
Gibbon, Donald L.; Kennedy, Keith; Reading, Nathan; Quieroz, Mardsen. J. Chem. Educ. 1992, 69, 658.
Thermodynamics |
Water / Water Chemistry |
Applications of Chemistry
BCTC for Windows.  Whisnant, David M.; McCormick, James.
BCTC is an environmental simulation that is modeled after the dioxin controversy; students are involved in the investigation of a suspected carcinogen called BCTC found in a river and threatening a city's water supply.
Whisnant, David M.; McCormick, James. J. Chem. Educ. 1992, 69, 638.
Water / Water Chemistry |
Toxicology
Simple soda bottle solubility and equilibria  Snyder, Cheryl A.; Snyder, Dudley C.
Using a bottle of selzter water and bromocresol green to demonstrate gas-liquid solubility (carbon dioxide in water).
Snyder, Cheryl A.; Snyder, Dudley C. J. Chem. Educ. 1992, 69, 573.
Solutions / Solvents |
Precipitation / Solubility |
Equilibrium |
Gases |
Liquids |
Aqueous Solution Chemistry |
Water / Water Chemistry
A reasonable alternative to water aspiration  Mulcahy, Francis M.; Robbins, Andrea M.
The authors have designed a manifold system to obtain the greatest possible use of their vacuum pumps.
Mulcahy, Francis M.; Robbins, Andrea M. J. Chem. Educ. 1992, 69, 428.
Laboratory Equipment / Apparatus |
Laboratory Management |
Water / Water Chemistry
Boiling and freezing simultaneously - with a feeble vacuum pump!   Ellison, Mike
The author uses this demonstration of freezing and boiling at reduced pressure to reinforce concepts about energy effects in phase changes.
Ellison, Mike J. Chem. Educ. 1992, 69, 325.
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Thermodynamics
Vapor pressure demonstrations using a butane lighter  Delumyea, R. Del
The concept of the change of state of matter and particularly the volatitlity of liquids is an important concept taught in introductory chemistry courses.
Delumyea, R. Del J. Chem. Educ. 1992, 69, 321.
Gases |
Physical Properties |
Liquids |
Phases / Phase Transitions / Diagrams
Standard states for water equilibrium (author response).  Campbell, Mark L.; Waite, Boyd A.
For the purposes of comparison only the unconventionally derived Ka values should be used to compare equilibrium constants for other acids to determine relative acid strengths.
Campbell, Mark L.; Waite, Boyd A. J. Chem. Educ. 1992, 69, 256.
Water / Water Chemistry |
Equilibrium |
Brønsted-Lowry Acids / Bases
Standard states for water equilibrium.  Baldwin, W. George; Burchill, C. Eugene.
The authors consider that Ka and Kb values for Bronsted acids and bases in aqueous solution represent one data set describing the properties of solutes in dilute aqueous solution.
Baldwin, W. George; Burchill, C. Eugene. J. Chem. Educ. 1992, 69, 255.
Water / Water Chemistry |
Equilibrium |
Brønsted-Lowry Acids / Bases
Freezing point depression in a bottle of soda   Bare, William D.
The "ravenous consumption of soda" by today's students makes an interesting model with which to demonstrate the effect of solute concentration on the freezing point of an aqueous solution.
Bare, William D. J. Chem. Educ. 1991, 68, 1038.
Aqueous Solution Chemistry |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry
Chemical equilibrium: VIII. Precipitates   Gordus, Adon A.
The final article in a series (see previous months this year): This article focuses on ionic precipitates in water and how buffered solutions allow easier calculation of solubilities.
Gordus, Adon A. J. Chem. Educ. 1991, 68, 927.
Acids / Bases |
Equilibrium |
pH |
Precipitation / Solubility |
Aqueous Solution Chemistry |
Water / Water Chemistry
Colorful layers and purple globs   Waye, Les
Colorful demonstration that illustrates concepts of polarity.
Waye, Les J. Chem. Educ. 1991, 68, 666.
Liquids
Densities and miscibilities of liquids and liquid mixtures   Franz, David A.
A sequence of demonstrations that lend themselves to quantitative calculations regarding density.
Franz, David A. J. Chem. Educ. 1991, 68, 594.
Physical Properties |
Liquids
Demonstrations of interfacial phenomena   Prall, Bruce R.
Overhead projector demonstrations that illustrate the interfacial interactions of the following systems: 1) water and carbon tetrachloride, 2) copper wire and water, 3) 1-Octanol and water.
Prall, Bruce R. J. Chem. Educ. 1991, 68, 592.
Surface Science |
Liquids |
Water / Water Chemistry |
Solutions / Solvents
Viscosity races   Hemmerlin, William M.; Abel, Kenton B.
A simple demonstration that illustrates the relationship between molecular size and viscosity.
Hemmerlin, William M.; Abel, Kenton B. J. Chem. Educ. 1991, 68, 417.
Physical Properties |
Liquids
Magnetic models of ions and water molecules for overhead projection   Davies, William G.
This paper describes a set of lecture-demonstration models that are easily made from ceramic magnets like those found in many discount stores and hobby shops.
Davies, William G. J. Chem. Educ. 1991, 68, 245.
Water / Water Chemistry
Bromothymol surprise  Maier, Linda L.
Dropping a tablet of Alka Seltzer into a bromothymol blue solution.
Maier, Linda L. J. Chem. Educ. 1990, 67, 963.
Acids / Bases |
Dyes / Pigments |
Aqueous Solution Chemistry |
Water / Water Chemistry
Ice under pressure  Chang, Raymond; Skinner, James F.
A piece of steel music wire pulled through a block of ice by weights on either side.
Chang, Raymond; Skinner, James F. J. Chem. Educ. 1990, 67, 789.
Water / Water Chemistry |
Physical Properties
Magic sand: Modeling the hydrophobic effect and reversed-phase liquid chromatography  Vitz, Ed
The procedures described here are meant to reveal the important "nonsolvent" properties of water through its interaction with Magic Sand, and other synthetic silica derivatives.
Vitz, Ed J. Chem. Educ. 1990, 67, 512.
Chromatography |
Water / Water Chemistry
An inexpensive device for collection of samples of water for dissolved oxygen determination without air contact   Favaretto, Lelio
This communication describes a simple and inexpensive device that permits the collection of water samples and fixation of dissolved oxygen by the Winkler method.
Favaretto, Lelio J. Chem. Educ. 1990, 67, 509.
Water / Water Chemistry |
Laboratory Equipment / Apparatus
An inexpensive laboratory steam generator  Hagen, James P.; Barton, Kevin L.
The authors have devised an inexpensive, more efficient, safer heat source suitable for laboratories not equipped with house steam.
Hagen, James P.; Barton, Kevin L. J. Chem. Educ. 1990, 67, 448.
Water / Water Chemistry |
Laboratory Equipment / Apparatus |
Laboratory Management
A vapor pressure demonstration   Sears, Jerry A.
The fact that all liquids exert a vapor pressure is an abstract concept that many students have difficulty understanding. The following demonstration offers dramatic, visual evidence of the pressure exerted by the vapor of a liquid.
Sears, Jerry A. J. Chem. Educ. 1990, 67, 427.
Alkanes / Cycloalkanes |
Phases / Phase Transitions / Diagrams |
Liquids
Dramatizing isotopes: Deuterated ice cubes sink   Ellis, Arthur B.; Adler, Edward A.; Juergens, Frederick H.
The authors describe a safe, striking demonstration of the effect of isotopic substitution.
Ellis, Arthur B.; Adler, Edward A.; Juergens, Frederick H. J. Chem. Educ. 1990, 67, 159.
Water / Water Chemistry |
Isotopes
An automatic water trap for steam distillation  Ruekberg, Ben
The unpleasant aspects of the water trap can be avoided with a simple, inexpensive device that renders the water trap automatically selfdraining.
Ruekberg, Ben J. Chem. Educ. 1990, 67, 66.
Separation Science |
Water / Water Chemistry |
Laboratory Equipment / Apparatus
High-efficiency condenser for low-boiling liquids and gases  Ali, Saqib; Mazhar, M.
Constructing a high-efficiency condenser for low-boiling liquids and gases using a 2 L plastic bottle.
Ali, Saqib; Mazhar, M. J. Chem. Educ. 1989, 66, 786.
Laboratory Equipment / Apparatus |
Gases |
Liquids |
Physical Properties
The liquid phase of carbon dioxide: A simple lecture demonstration  Andrews, Lester
Demonstrating that liquid CO2 can exist at higher pressures.
Andrews, Lester J. Chem. Educ. 1989, 66, 597.
Liquids |
Phases / Phase Transitions / Diagrams
An experiment to demonstrate the application of the scientific method  Tannenbaum, Irving R.
Boiling water as a demonstration to lead students to make and interpret careful observations.
Tannenbaum, Irving R. J. Chem. Educ. 1989, 66, 597.
Water / Water Chemistry
Using a Dumas bulb to determine the molecular weight of a volatile liquid   Kawa, Christopher J.
The use of an aspirator improves the filling and emptying process of a Dumas bulb.
Kawa, Christopher J. J. Chem. Educ. 1989, 66, 336.
Laboratory Equipment / Apparatus |
Laboratory Management |
Liquids
Buoyancy measurements for teaching and research  Miller, Bernard
The following examination of the venerable buoyancy principle can serve as a simple but rigorous illustration of a falsification test that not only clears up a possible misconception but also points the way to a number of practical uses of buoyancy measurements that have not generally been recognized.
Miller, Bernard J. Chem. Educ. 1989, 66, 267.
Liquids |
Physical Properties
The interconversion of electrical and chemical energy: The electrolysis of water and the hydrogen-oxygen fuel cell  Roffia, Sergio; Concialini, Vittorio; Paradisi, Carmen
Presentation of a simple apparatus that allows an instructor to perform the electrolysis of water and the back conversion of the products to water while overcoming some typical drawbacks encountered in this process.
Roffia, Sergio; Concialini, Vittorio; Paradisi, Carmen J. Chem. Educ. 1988, 65, 725.
Water / Water Chemistry |
Electrochemistry
Interfacial phenomena   Anwander, Alberto E.; Grant, Richard P. J. S.; Letcher, Trevor M.
The interfaces between liquids, and liquids and gases, have a number of possible permutations that lead to exotic phenomenon such as antibubbles, floating drops, boules, polyaphrons, and hanging air bubbles. The authors give directions for demonstrating these in the classroom or lab.
Anwander, Alberto E.; Grant, Richard P. J. S.; Letcher, Trevor M. J. Chem. Educ. 1988, 65, 608.
Surface Science |
Liquids |
Gases |
Physical Properties |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Phases / Phase Transitions / Diagrams
Correct equilibrium constants for water (the authors reply)  Starkey, Ronald; Norman, Jack; Hinitze, Mark
Water and hydronium ion Ka values are special cases.
Starkey, Ronald; Norman, Jack; Hinitze, Mark J. Chem. Educ. 1987, 64, 1068.
Equilibrium |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Acids / Bases |
Thermodynamics
Correct equilibrium constants for water  Baldwin, W. George; Burchill, C. Eugene
Disagreement with the numerical values assigned to equilibrium constants.
Baldwin, W. George; Burchill, C. Eugene J. Chem. Educ. 1987, 64, 1067.
Equilibrium |
Water / Water Chemistry |
Acids / Bases |
Aqueous Solution Chemistry
When oil and water do not mix  Trammell, Gary L.
An introduction to the physics and chemistry of interfaces and lipids, and reactions in micelles.
Trammell, Gary L. J. Chem. Educ. 1987, 64, 1022.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Solutions / Solvents |
Micelles |
Lipids
A Charles's Law/vapor pressure apparatus  Hall, Philip K.
A simple apparatus to illustrate either Charles's law gas expansion of the vapor pressure created by liquids.
Hall, Philip K. J. Chem. Educ. 1987, 64, 969.
Gases |
Liquids
Demonstration of vapor pressure  Richardson, W. S.
Demonstrating the vapor pressure of several different materials using a water manometer.
Richardson, W. S. J. Chem. Educ. 1987, 64, 968.
Gases |
Phases / Phase Transitions / Diagrams |
Liquids
The chemical bond  DeKock, Roger L.
Overview of the chemical bond; considers ionic bonds, covalent bonds, Lewis electron dot structures, polar molecules and hydrogen bonds, and bonding in solid-state elements.
DeKock, Roger L. J. Chem. Educ. 1987, 64, 934.
Ionic Bonding |
Covalent Bonding |
Hydrogen Bonding |
Solid State Chemistry |
Lewis Structures |
Molecular Properties / Structure
Modifications of some traditional demonstrations with liquids  Stedjee, Brian
Immiscible liquid pairs with similar indexes of refraction.
Stedjee, Brian J. Chem. Educ. 1987, 64, 894.
Liquids |
Solutions / Solvents |
Physical Properties
Physical and chemical properties  Boschmann, Erwin
A series of overhead demonstrations regarding physical and chemical properties.
Boschmann, Erwin J. Chem. Educ. 1987, 64, 891.
Physical Properties |
Liquids |
Precipitation / Solubility |
Magnetic Properties |
Kinetic-Molecular Theory |
Crystals / Crystallography |
Gases
An aqueous problem with an interesting solution  Thomas, Nicholas C.
Flow diagram outlining the steps to calculating the number of water molecules in one drop of water and the length of all these molecules stretched end to end.
Thomas, Nicholas C. J. Chem. Educ. 1987, 64, 611.
Water / Water Chemistry |
Stoichiometry
Which will evaporate first?  Stenmark, Allan
The evaporation rate of various short-chain alcohols and diethyl ether are compared.
Stenmark, Allan J. Chem. Educ. 1987, 64, 351.
Physical Properties |
Noncovalent Interactions |
Hydrogen Bonding |
Molecular Properties / Structure |
Alcohols |
Ethers
A safe cell for viewing the critical point of CO2  Botch, Beatrice; Battino, Rubin
Design, construction, and use of a safe cell for viewing the critical point of CO2.
Botch, Beatrice; Battino, Rubin J. Chem. Educ. 1987, 64, 347.
Laboratory Equipment / Apparatus |
Phases / Phase Transitions / Diagrams |
Gases |
Liquids
Methane pistol  Skinner, James F.
This simple demonstration leaves a lasting impression of the importance of intermolecular forces and hydrogen bonding.
Skinner, James F. J. Chem. Educ. 1987, 64, 171.
Noncovalent Interactions |
Hydrogen Bonding |
Molecular Properties / Structure
The quicker picker upper experiment   Snow, Albert J.
A popular commercial slogan as an in for chemistry instructors to talk about capillary action.
Snow, Albert J. J. Chem. Educ. 1986, 63, 1086.
Applications of Chemistry |
Consumer Chemistry |
Water / Water Chemistry
The electrolysis of water: An improved demonstration procedure   Heideman, Stephen
The usual use of sulfuric acid as the electrolyte in the demonstration of the electrolysis of water does not allow students to observe the accompanying pH changes at the electrodes.
Heideman, Stephen J. Chem. Educ. 1986, 63, 809.
Water / Water Chemistry |
pH |
Electrochemistry
A model for hydrogen bonding  Hill, John W.
Hydrogen bonding is a somewhat abstract and difficult concept for many students, yet it is of enormous importance in chemistry.
Hill, John W. J. Chem. Educ. 1986, 63, 503.
Hydrogen Bonding |
Noncovalent Interactions
The water softener - A relevant, unifying example of many common chemical principles and calculations  Fulkrod, John E.
Determining the amount of sodium chloride needed for a water softener to replace all the hard water ions in a month's water supply for a typical household.
Fulkrod, John E. J. Chem. Educ. 1985, 62, 529.
Applications of Chemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry
Water electrolysis-A surprising experiment  Kelsh, Dennis J.
Using aluminum wire for the cathode will produce "too much" hydrogen.
Kelsh, Dennis J. J. Chem. Educ. 1985, 62, 154.
Water / Water Chemistry |
Electrochemistry
The effect of polarity on solubility  Nordstrom, Brian H.
Students observe that iodine dissolves readily in 1,1,1-trichloroethane but not water.
Nordstrom, Brian H. J. Chem. Educ. 1984, 61, 1009.
Precipitation / Solubility |
Solutions / Solvents |
Molecular Properties / Structure |
Water / Water Chemistry
Modeling hypersaline lake "turn-over"  Sprague, Gary
Modeling saline lake inversions with a saturated salt solution in a beaker.
Sprague, Gary J. Chem. Educ. 1984, 61, 956.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
Scientific exploration with a microcomputer: Simulations for nonscientists  Whisnant, David M.
52. A four week-long exercise aimed at involving students with the scientific method through the use of a computer-simulated lake study.
Whisnant, David M. J. Chem. Educ. 1984, 61, 627.
Nonmajor Courses |
Water / Water Chemistry |
Applications of Chemistry
A quantitative gas chromatographic ethanol determination: a contemporary analytical experiment  Leary, James J.
This note describes a gas chromatographic experiment for the quantitative determination of volume percent ethanol in water ethanol solutions.
Leary, James J. J. Chem. Educ. 1983, 60, 675.
Gas Chromatography |
Quantitative Analysis |
Water / Water Chemistry |
Alcohols
An improvement for chromatography  Chiong, Hung-Cheh; Wang, Pei-Lin
A simpler setup for conducting chromatography experiments with colorless liquids.
Chiong, Hung-Cheh; Wang, Pei-Lin J. Chem. Educ. 1983, 60, 419.
Chromatography |
Liquids |
Laboratory Equipment / Apparatus
Molecular association and structure of hydrogen peroxide  Gigure, Paul A.
The typical textbook treatment of molecular association and structure of hydrogen peroxide, and the implications of these concepts for the physical properties of hydrogen peroxide tend to be oversimplified and inaccurate.
Gigure, Paul A. J. Chem. Educ. 1983, 60, 399.
Molecular Properties / Structure |
Physical Properties |
Phases / Phase Transitions / Diagrams |
Hydrogen Bonding
Le Châtelier's principle: the effect of temperature on the solubility of solids in liquids  Brice, L. K.
The purpose of this article is to provide a rigorous but straightforward thermodynamic treatment of the temperature dependence of solubility of solids in liquids that is suitable for presentation at the undergraduate level. The present discussion may suggest how to approach the qualitative aspects of the subject for freshman.
Brice, L. K. J. Chem. Educ. 1983, 60, 387.
Thermodynamics |
Liquids |
Solids |
Chemometrics |
Equilibrium
The determination of anionic surfactants in natural and waste waters  Crisp, P. T.; Eckert, J. M.; Gibson, N. A.
The experiment described in this paper is suitable for the measurement of subpart per million concentrations of anionic surfactants in natural waters and industrial effluents.
Crisp, P. T.; Eckert, J. M.; Gibson, N. A. J. Chem. Educ. 1983, 60, 236.
Industrial Chemistry |
Water / Water Chemistry |
Surface Science
The chemical oceanographer   Abel, Robert B.
Oceanography holds fascinating subject matter for students learning chemistry.
Abel, Robert B. J. Chem. Educ. 1983, 60, 221.
Water / Water Chemistry |
Food Science |
Geochemistry |
Atmospheric Chemistry |
Drugs / Pharmaceuticals |
Applications of Chemistry
Simple control system for automated, multistage stills  Uphaus, R. A.; Kostka, A. G.
A system that uses LEDs to sense the water level in a still pot and control the rate of heat input to the still heating jackets.
Uphaus, R. A.; Kostka, A. G. J. Chem. Educ. 1982, 59, 674.
Laboratory Equipment / Apparatus |
Water / Water Chemistry
The use of a filmstrip projector to present a critical point demonstration  Nyquist, H. LeRoy
A demonstration to illustrate the concepts of critical temperature and critical pressure.
Nyquist, H. LeRoy J. Chem. Educ. 1982, 59, 522.
Gases |
Liquids
A simple experiment for determining vapor pressure and enthalpy of vaporization of water  Levinson, Gerald S.
It is possible to determine the vapor pressure of water using only a tall beaker, a graduated cylinder, and a thermometer.
Levinson, Gerald S. J. Chem. Educ. 1982, 59, 337.
Water / Water Chemistry |
Gases |
Phases / Phase Transitions / Diagrams
Entropy and its role in introductory chemistry  Bickford, Franklin R.
The concept of entropy as it applies to phase changes.
Bickford, Franklin R. J. Chem. Educ. 1982, 59, 317.
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Solids |
Liquids |
Gases
Lemon meringue pie  Smith, Douglas D.
The chemistry and physics of lemon meringue pie.
Smith, Douglas D. J. Chem. Educ. 1982, 59, 60.
Gases |
Ionic Bonding |
Hydrogen Bonding |
Proteins / Peptides
Red cabbage and the electrolysis of water  Skinner, James F.
The demonstration profiled here has proven effective in bringing together concepts from acid-base chemistry and electrochemistry.
Skinner, James F. J. Chem. Educ. 1981, 58, 1017.
Electrochemistry |
Water / Water Chemistry |
Acids / Bases
Red cabbage and the electrolysis of water  Skinner, James F.
The demonstration profiled here has proven effective in bringing together concepts from acid-base chemistry and electrochemistry.
Skinner, James F. J. Chem. Educ. 1981, 58, 1017.
Electrochemistry |
Water / Water Chemistry |
Acids / Bases
A novel source of distilled water for science laboratories in the humid tropics  Ikediobi, C. O.
One of the most serious infrastructure headaches of developing countries is the acute shortage of potable water. In the face of this difficulty, the author offers some helpful tips for chemistry instructors.
Ikediobi, C. O. J. Chem. Educ. 1981, 58, 788.
Water / Water Chemistry |
Laboratory Management
Stormy weather  Taylor, Thomas E.
Question regarding the formation of rain clouds and the exothermic process of condensation.
Taylor, Thomas E. J. Chem. Educ. 1980, 57, 732.
Thermodynamics |
Atmospheric Chemistry |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
Fluoridated water  Muhler, Joseph C.
Answers to a number of questions regarding the fluoridation of drinking water.
Muhler, Joseph C. J. Chem. Educ. 1980, 57, 496.
Applications of Chemistry |
Aqueous Solution Chemistry |
Water / Water Chemistry
The experimental determination of the heat of vaporization of volatile liquids  Chames, Frances; Farver, Nina; Grieve, Catherine; Lynche, Archie; Mac, Michelle; Rickel, Renee; Sears, Jerry
An experiment whereby the heat of vaporization of a volatile liquid can be determined from an Arrhenius plot.
Chames, Frances; Farver, Nina; Grieve, Catherine; Lynche, Archie; Mac, Michelle; Rickel, Renee; Sears, Jerry J. Chem. Educ. 1980, 57, 362.
Calorimetry / Thermochemistry |
Liquids |
Phases / Phase Transitions / Diagrams
Illustrating chemical concepts through food systems: Introductory chemistry experiments  Chamber, IV, E.; Setser, C. S.
Illustrating the vaporization of liquids, reaction rates, adsorption, properties of solutions, colloidal dispersions, suspensions, and hydrogen ion concentration using foods.
Chamber, IV, E.; Setser, C. S. J. Chem. Educ. 1980, 57, 312.
Food Science |
Applications of Chemistry |
Liquids |
Phases / Phase Transitions / Diagrams |
Solutions / Solvents |
Colloids |
Acids / Bases
Lecture demonstration of vanishing meniscus in vapor liquid transition  Duus, H. C.
Shows how the interface between vapor and liquid propane vanishes.
Duus, H. C. J. Chem. Educ. 1979, 56, 614.
Liquids |
Gases |
Phases / Phase Transitions / Diagrams
Wonder water: Another idea that is hard to work into a conversation  Smith, Douglas D.
The many benefits of degassed water.
Smith, Douglas D. J. Chem. Educ. 1979, 56, 338.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Applications of Chemistry
An experiment oriented approach to teaching the kinetic molecular theory  Wiseman, Frank L., Jr.
A series of experiments designed to illustrate the kinetic molecular theory and the differences between solids, liquids, and gases.
Wiseman, Frank L., Jr. J. Chem. Educ. 1979, 56, 233.
Kinetic-Molecular Theory |
Gases |
Solids |
Liquids |
Nonmajor Courses
Development of intellectual skills in the laboratory  Ophardt, Charles E.
This first semester laboratory was designed to give instruction and practice in the intellectual skills of application, analysis, synthesis, and in Piaget's formal operations.
Ophardt, Charles E. J. Chem. Educ. 1978, 55, 485.
Learning Theories |
Qualitative Analysis |
Water / Water Chemistry |
Atmospheric Chemistry |
Acids / Bases |
Titration / Volumetric Analysis
Simple liquid-liquid extraction experiment for freshmen  Jones, Mark M.; Champion, Gwendalyn R.
A procedure can be described here can be carried out with the equipment normally present in a typical freshman laboratory. The experiment turns out to be a very good test of the student' technique and understanding.
Jones, Mark M.; Champion, Gwendalyn R. J. Chem. Educ. 1978, 55, 119.
Separation Science |
Liquids |
Titration / Volumetric Analysis
Emphasis on acids and bases  J. Chem. Educ. Staff
Considers the acidity or basicity in soils and natural waters; the acid-base balance in body chemistry; acidic and basic foods; the approximate pH values of common fluids; examples of acidic, basic, and neutral drugs; and the commercial preparation of nitric acid.
J. Chem. Educ. Staff J. Chem. Educ. 1977, 54, 626.
Acids / Bases |
Water / Water Chemistry |
Food Science |
Applications of Chemistry |
pH |
Drugs / Pharmaceuticals
Questions [and] Answers  Campbell, J. A.
323-329.
Campbell, J. A. J. Chem. Educ. 1977, 54, 622.
Enrichment / Review Materials |
Water / Water Chemistry |
Toxicology |
Applications of Chemistry
Questions [and] Answers  Campbell, J. A.
315-322. Eight questions on subjects related to environmental chemistry and their answers.
Campbell, J. A. J. Chem. Educ. 1977, 54, 498.
Enrichment / Review Materials |
Applications of Chemistry |
Water / Water Chemistry |
Atmospheric Chemistry
Silver ion in water purification: A follow-up  Quane, Denis
Applying a previous idea on the possible use of silver ion in water purification to teaching the concept of Ksp.
Quane, Denis J. Chem. Educ. 1977, 54, 381.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Equilibrium |
Solutions / Solvents
Hydrogen bonding and heat of solution  Friedman, Norman
An experiment that clearly illustrates the role of hydrogen bond formation and its effect on the heat of solution.
Friedman, Norman J. Chem. Educ. 1977, 54, 248.
Hydrogen Bonding |
Calorimetry / Thermochemistry |
Solutions / Solvents
Le Chtelier's principle: A laboratory exercise  Friedman, Frederica
Le Chtelier's principle can be demonstrated by showing that water can boil at temperatures below 100C due to reduced vapor pressure.
Friedman, Frederica J. Chem. Educ. 1977, 54, 236.
Equilibrium |
Phases / Phase Transitions / Diagrams |
Gases |
Water / Water Chemistry
Chemist's view of oceanography  Cutshall, Norman H.
The structure of oceanography, chemists in oceanography, chemical analysis in oceanography, chemical oceanography research, and chemical oceanographers in marine pollution studies.
Cutshall, Norman H. J. Chem. Educ. 1977, 54, 162.
Applications of Chemistry |
Aqueous Solution Chemistry |
Water / Water Chemistry
Marine biochemistry. A new interdisciplinary course for the interim  Goldberg, Arthur S.
A course was implemented entitled "Marine Biochemistry" as a result of both student interest and increasing awareness of scientists of the potential usefulness of substances from the sea. A number of recent books and articles have been published and used as source material for the course.
Goldberg, Arthur S. J. Chem. Educ. 1976, 53, 717.
Water / Water Chemistry
Non-covalent interactions: Key to biological flexibility and specificity  Frieden, Earl
Summarizes the types of non-covalent interactions found among biomolecules and how they facilitate the function of antibodies, hormones, and hemoglobin.
Frieden, Earl J. Chem. Educ. 1975, 52, 754.
Noncovalent Interactions |
Hydrogen Bonding |
Water / Water Chemistry |
Proteins / Peptides |
Amino Acids |
Molecular Properties / Structure |
Hormones
Chlorine in your water  Smith, J. G.
The use, chemistry, and alternatives to chlorine and chlorine compounds in water supplies.
Smith, J. G. J. Chem. Educ. 1975, 52, 656.
Water / Water Chemistry |
Consumer Chemistry
Questions [and] Answers  Campbell, J. A.
206-211. Six questions regarding topics in environmental chemistry and biochemistry.
Campbell, J. A. J. Chem. Educ. 1975, 52, 655.
Enrichment / Review Materials |
Applications of Chemistry |
Water / Water Chemistry
Questions [and] Answers  Campbell, J. A.
193-197. Five biochemical questions and their answers.
Campbell, J. A. J. Chem. Educ. 1975, 52, 457.
Enrichment / Review Materials |
pH |
Isotopes |
Water / Water Chemistry
A study of water pollution. An undergraduate chemistry laboratory experience  Sarkis, Vahak D.
In addition to its environmental relevance, a water pollution study of the inorganic constituents in water as outlined in this article, provides the student with certain important principles of chemistry namely, colorimetric and titrimetric procedures.
Sarkis, Vahak D. J. Chem. Educ. 1974, 51, 745.
Applications of Chemistry |
Metals |
Green Chemistry |
Water / Water Chemistry |
Titration / Volumetric Analysis
Computer simulation of countercurrent distribution experiments  Coleman, George H.
A routine for simulating liquid-liquid countercurrent distribution data.
Coleman, George H. J. Chem. Educ. 1973, 50, 825.
Liquids
Demonstration of solubility of "immiscible" fluids  Koob, R. D.; Tallman, D. E.
Demonstrating that hexane is miscible in water.
Koob, R. D.; Tallman, D. E. J. Chem. Educ. 1973, 50, 724.
Solutions / Solvents |
Precipitation / Solubility |
Water / Water Chemistry |
Alkanes / Cycloalkanes
Nitric acid in rain water  Gleason, Geoffrey I.
This trace analysis experiment is based on the conversion of nitrate to nitrite using a cadmium amalgam reductor column.
Gleason, Geoffrey I. J. Chem. Educ. 1973, 50, 718.
Acids / Bases |
Water / Water Chemistry |
Atmospheric Chemistry
Construction of a self-filling pycnometer in five minutes  McCullough, Thomas, C.S.C.
Procedure for constructing a self-filling pycnometer for precise determinations of the specific gravities of liquids.
McCullough, Thomas, C.S.C. J. Chem. Educ. 1973, 50, 546.
Laboratory Equipment / Apparatus |
Physical Properties |
Liquids
The chemistry of pollution - An experimental course  Frank, David L.
Briefly outlines the goals and topics of a course entitled "Chemistry of Air Pollution."
Frank, David L. J. Chem. Educ. 1973, 50, 209.
Atmospheric Chemistry |
Water / Water Chemistry
Dissolved oxygen determination  Berger, Toby E.
Details regarding the cited procedure.
Berger, Toby E. J. Chem. Educ. 1973, 50, 160.
Water / Water Chemistry |
Solutions / Solvents
Notes on determination of dissolved oxygen  Sommers, Raymond A.
Simplifications in the referenced procedure that make it more suitable for the introductory laboratory.
Sommers, Raymond A. J. Chem. Educ. 1973, 50, 160.
Water / Water Chemistry |
Solutions / Solvents
Special session: Women's caucus  Brownlee, Paula

Brownlee, Paula J. Chem. Educ. 1973, 50, 21.
Conferences |
Professional Development |
Water / Water Chemistry
Beyond the Conventional Classroom. Session II-A: Continuing education  Heikkinen, Henry; Zuehlke, Rick; Alexander, John
Combating technical obsolescence; rent o prof; water, man and chemistry; and an undergraduate-graduate research collaboration program.
Heikkinen, Henry; Zuehlke, Rick; Alexander, John J. Chem. Educ. 1973, 50, 18.
Conferences |
Professional Development |
Industrial Chemistry |
Water / Water Chemistry |
Undergraduate Research
Great affinity of ammonia for water  Chen, Philip S.
Demonstrates the great affinity of ammonia for water.
Chen, Philip S. J. Chem. Educ. 1972, 49, A267.
Noncovalent Interactions |
Hydrogen Bonding
The determination of dissolved oxygen by the Winkler method. A student laboratory experiment  McCormick, Patrick G.
This method is based on the reaction between oxygen and a suspension of manganese(II) hydroxide in a strongly alkaline solution.
McCormick, Patrick G. J. Chem. Educ. 1972, 49, 839.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Gases |
Quantitative Analysis |
Titration / Volumetric Analysis
Radiometric analysis of ammonia in water  Mehra, M. C.
In this experiment, the silver concentration in aqueous solution is determined radiometrically using silver-110 as the radiotracer.
Mehra, M. C. J. Chem. Educ. 1972, 49, 837.
Water / Water Chemistry |
Nuclear / Radiochemistry |
Isotopes |
Aqueous Solution Chemistry |
Quantitative Analysis
Sliding friction and skiing  Plumb, Robert C.; Van Hook, Alexander
What causes the film of water to form under skis and ice skates?
Plumb, Robert C.; Van Hook, Alexander J. Chem. Educ. 1972, 49, 830.
Water / Water Chemistry
Water analysis experiment  Anderlick, Barbara
Analyzing various water samples for the presence of a variety of ions.
Anderlick, Barbara J. Chem. Educ. 1972, 49, 749.
Water / Water Chemistry |
Qualitative Analysis |
Aqueous Solution Chemistry |
Metals
Efficient use of washing solvents. A quantitative treatment  Boschmann, Edwin
A quantitative study of the efficient use of washing solvents (e.g. distilled water) in the laboratory.
Boschmann, Edwin J. Chem. Educ. 1972, 49, 650.
Laboratory Management |
Water / Water Chemistry
Measurement of pH of distilled water  Youmans, Hubert L.
Resolving the problem of pH meters giving readings for the pH of distilled water that differ significantly from 7.
Youmans, Hubert L. J. Chem. Educ. 1972, 49, 429.
Water / Water Chemistry |
pH |
Quantitative Analysis
Dissolved oxygen. A relevant experiment for the introductory laboratory  Stagg, William R.
Students measure the dissolved oxygen content of water from several natural sources as well as the change in solubility with temperature.
Stagg, William R. J. Chem. Educ. 1972, 49, 427.
Water / Water Chemistry |
Oxidation / Reduction |
Quantitative Analysis |
Solutions / Solvents |
Precipitation / Solubility |
Gases
Using silica to demonstrate hydrogen bonding  Most, Clark, Jr.
The efficiency of a multitude of hydrogen bonds can be demonstrated by comparing the fluid character of mineral oil to the more solid character of the same oil to which has been added a small amount of finely divided silica.
Most, Clark, Jr. J. Chem. Educ. 1972, 49, 419.
Hydrogen Bonding |
Noncovalent Interactions
Why is the oxygen in water negative?  Liebman, Joel F.
Oxygen in water is negative because a negative charge, unlike a positive, can be stabilized using ground state ionic resonance structures.
Liebman, Joel F. J. Chem. Educ. 1972, 49, 415.
Water / Water Chemistry |
Molecular Properties / Structure |
Oxidation State
Chemistry laboratories and other ecosystems  Wynn, Charles M.
Suggestions for reducing water pollution from the chemistry laboratory.
Wynn, Charles M. J. Chem. Educ. 1972, 49, 225.
Laboratory Management |
Water / Water Chemistry
Squeak, skid and glide - The unusual properties of snow and ice  Plumb, Robert C.; Fletcher, N. H.
The Clapeyron equation controls the behavior of ice under varying conditions of temperature and pressure.
Plumb, Robert C.; Fletcher, N. H. J. Chem. Educ. 1972, 49, 179.
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Equilibrium
Squeak, skid and glide - The unusual properties of snow and ice  Plumb, Robert C.; Fletcher, N. H.
The Clapeyron equation controls the behavior of ice under varying conditions of temperature and pressure.
Plumb, Robert C.; Fletcher, N. H. J. Chem. Educ. 1972, 49, 179.
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Equilibrium
The effervescence of ocean surf  Plumb, Robert C.; Blanchard, Duncan C.; Bilofsky, Howard S.; Bridgman, Wilbur B.
A pure liquid will not foam, but all true solutions will, as dictated by the fundamental concepts of surface thermodynamics enunciated by Gibbs.
Plumb, Robert C.; Blanchard, Duncan C.; Bilofsky, Howard S.; Bridgman, Wilbur B. J. Chem. Educ. 1972, 49, 29.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Gases |
Solutions / Solvents |
Thermodynamics
An introductory experiment on phosphates in detergents  Mohrig, Jerry R.
Examines the phosphate controversy, the roles of phosphates in detergents, the chemistry of phosphates and their colorimetric determination, and presents an experiment in which the amount of phosphate is measured using two different analytical methods.
Mohrig, Jerry R. J. Chem. Educ. 1972, 49, 15.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Consumer Chemistry |
Quantitative Analysis |
Applications of Chemistry
Polywater. A lesson and opportunity in science  Christian, P. A.; Berka, L. H.
The authors present an intriguing observation and offer outlines of some possible studies that can be undertaken in any adequately equipped high school or college chemistry laboratory.
Christian, P. A.; Berka, L. H. J. Chem. Educ. 1971, 48, 667.
Water / Water Chemistry |
Solutions / Solvents
Analysis of phosphate in detergents  Kriz, George S., Jr.; Kriz, Kay Dian
The experiment described here is a response to the need mentioned above and is specifically concerned with water pollution caused by phosphate detergents. It is ideal for today's students who concerned about the environment.
Kriz, George S., Jr.; Kriz, Kay Dian J. Chem. Educ. 1971, 48, 551.
Surface Science |
Water / Water Chemistry |
Applications of Chemistry
Heat of hydration  Dannhauser, Walter
A commonly published experiment can be expanded so that students may obtain the enthalpy of the reaction between anhydrous salts and water.
Dannhauser, Walter J. Chem. Educ. 1971, 48, 329.
Thermodynamics |
Crystals / Crystallography |
Water / Water Chemistry |
Noncovalent Interactions
The chemical pousse-caf  Worley, John David
Production of a density column with a series of liquids with varying densities.
Worley, John David J. Chem. Educ. 1970, 47, A389.
Liquids |
Physical Properties
Is ammonia like water?  Gill, J. B.
This article sets out to compare some of the properties of the two most widely studied solvents, water and liquid ammonia, and in particular illustrate some comparative aspects that are not normally considered.
Gill, J. B. J. Chem. Educ. 1970, 47, 619.
Water / Water Chemistry |
Molecular Properties / Structure |
Aqueous Solution Chemistry
Sealed tube experiments  Campbell, J. A.
Lists and briefly describes a large set of "sealed tube experiments," each of which requires less than five minutes to set-up and clean-up, requires less than five minutes to run, provides dramatic results observable by a large class, and illustrates important chemical concepts.
Campbell, J. A. J. Chem. Educ. 1970, 47, 273.
Thermodynamics |
Crystals / Crystallography |
Solids |
Liquids |
Gases |
Rate Law |
Equilibrium
A lecture-laboratory experiment in gas-liquid partition chromatography  McKay, Edward S.; Vasers, Alise
After being introduced to the chromatographic process in lecture, each student is given a copy of a chromatogram of an unknown mixture and asked to identify its composition and the concentration of each component.
McKay, Edward S.; Vasers, Alise J. Chem. Educ. 1970, 47, 239.
Gases |
Liquids |
Chromatography |
Gas Chromatography |
Quantitative Analysis |
Qualitative Analysis
Baby bottles and elementary chemistry  Davenport, D. A.
Presents several experiments that rely on baby bottles, including Charles' Law expansion, vapor pressure of volatile liquids, molecular weights of volatile liquids, and closed-atmosphere experiments.
Davenport, D. A. J. Chem. Educ. 1969, 46, 878.
Laboratory Equipment / Apparatus |
Laboratory Management |
Gases |
Liquids |
Oxidation / Reduction
Diffusion of potassium permanganate as a lecture demonstration  Conard, C. R.; Bent, H. E.
Dropping crystals of potassium permanganate into a tall column of water leads to the slow dissolution and diffusion of the potassium permanganate throughout the column over a semester's time.
Conard, C. R.; Bent, H. E. J. Chem. Educ. 1969, 46, 758.
Transport Properties |
Aqueous Solution Chemistry |
Kinetic-Molecular Theory |
Solutions / Solvents |
Liquids
Safe use of flammable liquids in laboratories  Shaw, A. J.
Examines the properties of flammable liquids, as well as their safe handling and proper safety equipment.
Shaw, A. J. J. Chem. Educ. 1968, 45, A821.
Liquids |
Laboratory Management
A simple vacuum apparatus for lecture experiments  Peterson, L. K.; Ruddy, F. H.
Describes a simple vacuum apparatus and examples of its use in lecture situations.
Peterson, L. K.; Ruddy, F. H. J. Chem. Educ. 1968, 45, 742.
Laboratory Equipment / Apparatus |
Gases |
Liquids |
Physical Properties |
Transport Properties |
Stoichiometry |
Calorimetry / Thermochemistry
Calcium carbonate equilibria in the oceans - ion pair formation  Morton, Stephen D.; Lee, G. Fred
Discusses some of the problems encountered in studying the chemistry of lakes and oceans, focussing on the solubility of calcium carbonate in marine environments.
Morton, Stephen D.; Lee, G. Fred J. Chem. Educ. 1968, 45, 513.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Precipitation / Solubility |
Qualitative Analysis
Calcium carbonate equilibria in lakes  Morton, Stephen D.; Lee, G. Fred
Discusses some of the problems encountered in studying the chemistry of lakes and oceans, focussing on the solubility of calcium carbonate in fresh water lakes.
Morton, Stephen D.; Lee, G. Fred J. Chem. Educ. 1968, 45, 511.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Precipitation / Solubility |
Equilibrium
A simple and accurate dilatometer for liquids  Wagner, Robert E.; Meyer, Edwin F.
The density of a liquid as a function of temperature may be readily measured using this dilatometer.
Wagner, Robert E.; Meyer, Edwin F. J. Chem. Educ. 1968, 45, 349.
Laboratory Equipment / Apparatus |
Liquids |
Physical Properties
Structure units: Aids in the interpretation of chemical reactions  Strong, Laurence E.
the proposal to define structure units as generators of the various properties of a substance has a considerable advantage over the usual definition of a structure unit as the endpoint of some prescribed scheme of subdivision.
Strong, Laurence E. J. Chem. Educ. 1968, 45, 51.
Learning Theories |
Molecular Properties / Structure |
Solids |
Liquids |
Gases
Group 1. The Alkali Metals. The Copper Group   Mancuso, Carl J.; Alyea, Hubert N.
Demonstrations include the density and melting point of copper versus sodium, the conductivity of sodium, the reactivity with water of groups IA vs IB, and the stability of CO3--, HCO3-, and hydroxides of groups IA vs IB.
Mancuso, Carl J.; Alyea, Hubert N. J. Chem. Educ. 1967, 44, A919.
Metals |
Reactions |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Physical Properties
Atomic structure. Radioactivity (continued)   Alyea, Hubert N.
Formation of the complex Cu(NH3)4++ as an example of coordinate covalent bonding and hydrogen bonding as evidenced by viscosity.
Alyea, Hubert N. J. Chem. Educ. 1967, 44, A599.
Coordination Compounds |
Covalent Bonding |
Hydrogen Bonding |
Liquids
Liquid-liquid extraction  Joseph-Nathan, P.
Describes how liquid-liquid extraction can be done using commercially available substances and an apparatus of small dimensions that still allows an experiment to be followed visually.
Joseph-Nathan, P. J. Chem. Educ. 1967, 44, 176.
Separation Science |
Liquids |
Laboratory Equipment / Apparatus
Hard sphere simulation of statistical mechanical behavior of molecules  Plumb, Robert C.
Describes the design and use of a demonstration device to illustrate the kinetic behavior of gases, liquids, and solids.
Plumb, Robert C. J. Chem. Educ. 1966, 43, 648.
Statistical Mechanics |
Gases |
Liquids |
Solids |
Kinetic-Molecular Theory |
Equilibrium |
Phases / Phase Transitions / Diagrams
Manometric apparatus for vapor and solution studies  Taha, Ahmed A.; Grigsby, Ronald D.; Johnson, James R.; Christian, Sherril D.; Affsprung, Harold E.
Presents a device that can be sued to obtain vapor density and PVT measurements, vapor pressures of solutions and liquids, dew-point pressures and compositions, solubilities of gases in liquids, solubilities of slightly-miscible liquids, equilibrium constants for association reactions in solutions, interactions of vapors and gases with solids, and gas and vapor viscosities.
Taha, Ahmed A.; Grigsby, Ronald D.; Johnson, James R.; Christian, Sherril D.; Affsprung, Harold E. J. Chem. Educ. 1966, 43, 432.
Laboratory Equipment / Apparatus |
Physical Properties |
Solutions / Solvents |
Gases |
Liquids |
Solids
Simple two-dimensional magnetic disc models of ionic liquids  Angell, C. A.; Gruen, D. M.
Modeling ionic liquids using magnetic, elastomer-bonded materials capable of floating on water.
Angell, C. A.; Gruen, D. M. J. Chem. Educ. 1966, 43, 194.
Molecular Modeling |
Liquids |
Solutions / Solvents
Experiments on metal amine salts  Haight, G. P., Jr.
Tetrammine monaquo copper(II) sulfate is prepared and studied qualitatively and quantitatively.
Haight, G. P., Jr. J. Chem. Educ. 1965, 42, 468.
Metals |
Covalent Bonding |
Hydrogen Bonding |
Qualitative Analysis |
Quantitative Analysis
Letters  Robertson, R. E.
Describes a safe solution to problems with squeeze bottles containing high vapor pressure liquids.
Robertson, R. E. J. Chem. Educ. 1965, 42, 457.
Laboratory Equipment / Apparatus |
Liquids
Electrolysis: H2O and H2O2  Eberhardt, William H.
This demonstration involves the concurrent electrolysis of water and hydrogen peroxide.
Eberhardt, William H. J. Chem. Educ. 1964, 41, A591.
Electrochemistry |
Water / Water Chemistry
A model of the ice structure  Lambert, Jack L.; Seitz, Larry M.
Instructions for constructing a physical model of ice.
Lambert, Jack L.; Seitz, Larry M. J. Chem. Educ. 1964, 41, 504.
Water / Water Chemistry |
Molecular Modeling |
Molecular Properties / Structure
Distilled water purity monitor using an ac polarization electrode  Freedman, R. W.; Radkoff, S.
Presents a circuit diagram for a distilled water purity monitor using an ac polarization electrode.
Freedman, R. W.; Radkoff, S. J. Chem. Educ. 1964, 41, 387.
Water / Water Chemistry |
Laboratory Equipment / Apparatus
Removal of hardness and deionization of water by the ion exchange method  Sangster, A. W.
Demonstrates the removal of calcium and chloride ions through ion exchange.
Sangster, A. W. J. Chem. Educ. 1963, 40, A987.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Ion Exchange
Demonstration notes: Fog formation  Benson, John E.
Suggests a modification to producing a cloud in a jar.
Benson, John E. J. Chem. Educ. 1963, 40, A477.
Gases |
Liquids |
Phases / Phase Transitions / Diagrams
The hydrated hydronium ion  Clever, H. Lawrence
It is the purpose of this brief review to cite and discuss some of the evidence for the existence of the trihydrated hydronium ion.
Clever, H. Lawrence J. Chem. Educ. 1963, 40, 637.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Acids / Bases |
Brønsted-Lowry Acids / Bases
Alkali metal-water reactions  Markowitz, Meyer M.
The typical open-air demonstration of sodium reacting with water does not in reality represent the typical reaction of an alkali metal with liquid water; the article goes on to consider other factors that may influence these reactions.
Markowitz, Meyer M. J. Chem. Educ. 1963, 40, 633.
Reactions |
Metals |
Water / Water Chemistry
Hypodermic syringes in quantitative elementary chemistry experiments. Part 2. General chemistry experiments  Davenport, Derek A.; Saba, Afif N.
Presents a variety of experiments that make use of hypodermic syringes in quantitative elementary chemistry.
Davenport, Derek A.; Saba, Afif N. J. Chem. Educ. 1962, 39, 617.
Laboratory Equipment / Apparatus |
Gases |
Liquids |
Reactions |
Equilibrium |
Stoichiometry
The science study series. Volumes 12 and 18  Kieffer, William F.

Kieffer, William F. J. Chem. Educ. 1961, 38, 588.
Atomic Properties / Structure |
Nuclear / Radiochemistry |
Water / Water Chemistry
Ultra Low Conductivity Water  National Bureau of Standards Summary Technical Report
Describes the production of water with a conductivity approaching the lower theoretical limit.
National Bureau of Standards Summary Technical Report J. Chem. Educ. 1961, 38, 421.
Water / Water Chemistry |
Conductivity |
Aqueous Solution Chemistry
The ionization constant of water  Dirkse, Thedford P.
Some textbooks claim that the ion product constant of water is constant under all conditions at a given temperature.
Dirkse, Thedford P. J. Chem. Educ. 1961, 38, 260.
Water / Water Chemistry |
Aqueous Solution Chemistry
Demonstrating the relative polarity of non-conducting liquids  Siegel, S.
The apparatus described is based on the principle that an increase in the dielectric constant of the medium causes a decrease in the force of attraction between charged particles (in this case, two plastic beads).
Siegel, S. J. Chem. Educ. 1960, 37, 368.
Liquids
Kinetic molecular theory from a jukebox  Easley, W. K.; Powers, Glenn F.
Uses dancers to various styles of music as an analogy for differences between the atomic and molecular motions in solids, liquids, and gases.
Easley, W. K.; Powers, Glenn F. J. Chem. Educ. 1960, 37, 302.
Kinetic-Molecular Theory |
Solids |
Liquids |
Gases
Rapid dispensing of liquids for large laboratory classes  Radin, Norman S.
Describes an automatic syringe that is useful for rapidly dispensing liquids for large laboratory classes.
Radin, Norman S. J. Chem. Educ. 1959, 36, 579.
Laboratory Equipment / Apparatus |
Laboratory Management |
Liquids
Vapor density apparatus for general chemistry laboratory  Masterton, W. L.; Williams, T. R.
Presents the design of an apparatus that eliminates errors due to absorption and evaporation in the determination of molecular weights of volatile liquids.
Masterton, W. L.; Williams, T. R. J. Chem. Educ. 1959, 36, 528.
Laboratory Equipment / Apparatus |
Gases |
Physical Properties |
Liquids
Determination of vapor pressure: A general chemistry laboratory experiment  Wolthuis, Enno; Brummel, Roger; Bout, Paul Vanden
Provides a method for obtaining good vapor pressure measurements using simple equipment.
Wolthuis, Enno; Brummel, Roger; Bout, Paul Vanden J. Chem. Educ. 1959, 36, 494.
Gases |
Liquids |
Phases / Phase Transitions / Diagrams
Textbook errors: XX. Miscellanea No. 2  Mysels, Karol J.
Subjects considered include the meaning of "element," the solubility of phenol in carbonate solutions, and the change of vapor pressure with temperature.
Mysels, Karol J. J. Chem. Educ. 1958, 35, 568.
Precipitation / Solubility |
Phenols |
Gases |
Liquids
Lone pair electrons  Fowles, Gerald W. A.
The lone pair electrons, whether in simple or hybrid orbitals, have profound effects on the properties of the molecule; these effects may be discussed as bond angles, dipole moments, bond energies and lengths, and coordination and hydrogen bonding.
Fowles, Gerald W. A. J. Chem. Educ. 1957, 34, 187.
Atomic Properties / Structure |
Covalent Bonding |
Coordination Compounds |
Noncovalent Interactions |
Hydrogen Bonding |
Molecular Properties / Structure
Some aspects of hydrogen bonding in inorganic chemistry  Gorman, Mel
The purpose of this review is to present some of the research which is illustrative of the methods used and the results obtained with a variety of inorganic compounds in which hydrogen bonding is one of the structural features.
Gorman, Mel J. Chem. Educ. 1956, 33, 468.
Hydrogen Bonding |
Noncovalent Interactions
Calorimeter for determining heat capacities of liquids  Greene, Stanley A.
This paper describes a method for utilizing a constant-power heating device that eliminates the need for a preponderance of equipment yet permits reasonable accuracy in determining the heat capacities of liquids.
Greene, Stanley A. J. Chem. Educ. 1955, 32, 577.
Calorimetry / Thermochemistry |
Laboratory Equipment / Apparatus |
Liquids
A Raoult's law experiment for the general chemistry course: Manometry without a manometer  Harris, Frank E.; Nash, Leonard K.
This paper describes an experiment illustrating Raoult's law that does not require a manometer, vacuum system, or mercury.
Harris, Frank E.; Nash, Leonard K. J. Chem. Educ. 1955, 32, 575.
Liquids
Effect of water on the interaction of aluminum and iodine  Azmatullah, Syed; Viswanathan, Argot
A drop of water added to powdered aluminum and iodine initiates a vigorous reaction.
Azmatullah, Syed; Viswanathan, Argot J. Chem. Educ. 1955, 32, 447.
Water / Water Chemistry |
Reactions
Textbook errors: III. The solubility of gases in liquids  Mysels, Karol J.
Rising temperature is generally said to reduce the solubility of gases in liquids, yet the facts disagree with any such generalization.
Mysels, Karol J. J. Chem. Educ. 1955, 32, 399.
Gases |
Liquids |
Precipitation / Solubility |
Solutions / Solvents
Water, a basic natural resource  Keirstead, Ralph E.
Describes the many uses for water and its importance as a basic natural resource.
Keirstead, Ralph E. J. Chem. Educ. 1955, 32, 99.
Water / Water Chemistry
Ammonia and "ammonium hydroxide"  Davis, John B.
One of several reactions that needs reevaluation in the light of the modern theory of valence is the reaction between ammonia and water and the fiction of the ammonium hydroxide molecule.
Davis, John B. J. Chem. Educ. 1953, 30, 511.
Amines / Ammonium Compounds |
Aqueous Solution Chemistry |
Reactions |
Hydrogen Bonding |
Noncovalent Interactions
Micro bump-rockets: A demonstration of the power of superheated liquids.  Woodbridge, Richard G., III
This demonstration uses the energy stored in a small amount of superheated liquid to propel a small rocket made of a glass melting-point tube.
Woodbridge, Richard G., III J. Chem. Educ. 1952, 29, 623.
Liquids
A method of estimating the boiling points of organic liquids  Pearson, D. E.
Discusses the relationship between the molecular structure of organic liquids and their boiling point.
Pearson, D. E. J. Chem. Educ. 1951, 28, 60.
Liquids |
Phases / Phase Transitions / Diagrams |
Physical Properties |
Molecular Properties / Structure